38 research outputs found

    Neel probability and spin correlations in some nonmagnetic and nondegenerate states of hexanuclear antiferromagnetic ring Fe6: Application of algebraic combinatorics to finite Heisenberg spin systems

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    The spin correlations \omega^z_r, r=1,2,3, and the probability p_N$ of finding a system in the Neel state for the antiferromagnetic ring Fe(III)6 (the so-called `small ferric wheel') are calculated. States with magnetization M=0, total spin 0<=S<=15 and labeled by two (out of four) one-dimensional irreducible representations (irreps) of the point symmetry group D_6 are taken into account. This choice follows from importance of these irreps in analyzing low-lying states in each S-multiplet. Taking into account the Clebsch--Gordan coefficients for coupling total spins of sublattices (SA=SB=15/2) the global Neel probability p*_N can be determined. Dependencies of these quantities on state energy (per bond and in the units of exchange integral J) and the total spin S are analyzed. Providing we have determined p_N(S) etc. for other antiferromagnetic rings (Fe10, for instance) we could try to approximate results for the largest synthesized ferric wheel Fe18. Since thermodynamic properties of Fe6 have been investigated recently, in the present considerations they are not discussed, but only used to verify obtained values of eigenenergies. Numerical results re calculated with high precision using two main tools: (i) thorough analysis of symmetry properties including methods of algebraic combinatorics and (ii) multiple precision arithmetic library GMP. The system considered yields more than 45 thousands basic states (the so-called Ising configurations), but application of the method proposed reduces this problem to 20-dimensional eigenproblem for the ground state (S=0). The largest eigenproblem has to be solved for S=4; its dimension is 60. These two facts (high precision and small resultant eigenproblems) confirm efficiency and usefulness of such an approach, so it is briefly discussed here.Comment: 13 pages, 7 figs, 5 tabs, revtex

    Quantum fluctuations of the magnetization in high spin molecules - a mu SR study

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    Using zero field (ZF) and longitudinal field (LF) mu SR we study the magnetic properties of high spin molecules (HSM) with spin S = 15/2 and 27/2. The LF-mu SR at very low temperatures suggests that in both our samples dynamical field fluctuations are responsible for the muon relaxation. The relaxation rate lambda increases as the temperature decreases and then saturates below T &lt; T-c indicating that the dynamics is of quantum nature. The fluctuation rate at T --&gt; 0 of the different samples is compared. (C) 2000 Elsevier Science B.V. All rights reserved

    Cyanide-Bridged Bimetallic High Spin Molecules

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    Flux-weakening operation of open-end winding drive integrating a cost effective high-power charger

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    In this paper, a three-phase drive with a six-leg Voltage Source Inverter (VSI) and an open-end winding Interior Permanent Magnet Synchronous Machine (IPMSM) designed for the traction of an electric vehicle is studied in flux-weakening operation. The topology allows the functionality of a high power charger to be obtained, without adding any other supplementary power devices. On the other hand, since there are three independent currents, the control structure has to handle not only the two dq current components but also a zero-sequence current. If neglected, in comparison with wye-coupled three-phase drive, this zero-sequence component can cause a higher maximum peak value of the phase currents, additional stator Joule losses, torque ripple, inverter voltage saturation and IGBT oversizing. The proposed control strategy consists in adapting a conventional method used for wye-connected machines particularly in flux-weakening operation. This strategy allows the closed-loop control of the zero-sequence current to be maintained in the whole speed range and therefore inverter saturation is avoided. Simulations and experimental results are presented and analyzed.FUI SOFRAC
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