5 research outputs found
Landscape equivalent of the shoving model
It is shown that the shoving model expression for the average relaxation time
of viscous liquids follows largely from a classical "landscape" estimation of
barrier heights from curvature at energy minima. The activation energy involves
both instantaneous bulk and shear moduli, but the bulk modulus contributes less
than 8% to the temperature dependence of the activation energy. This reflects
the fact that the physics of the two models are closely related.Comment: 4 page