17 research outputs found

    Surface Structure of √3x√3R 30 Cl/Ni(111) Determined Using Low-temperature Angle-Resolved-Photoemission Extended Fine Structure

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    A surface structural study of the √3 × √3 R30° Cl/Ni(111) adsorbate system was made using low-temperature angle-resolved photoemission extended fine structure. The experiments were performed along two emission directions, [111] and [110], and at two temperatures, 120 and 300 K. The multiple-scattering spherical-wave analysis determined that the Cl atom adsorbs in the fcc threefold hollow site, 1.837(8) Å above the first nickel layer, with a Cl-Ni bond length of 2.332(6) Å, and an approximate 5% contraction between the first and the second nickel layers (the errors in parentheses are statistical standard deviations only)

    Threshold Photoelectron Spectrum of the Argon 3s Satellites

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    Lately a variety of techniques have studied the electron correlation satellites with binding energies between the Ar 3s ionization potential (29.24 eV) and the lowest 2p−2 ionization potential (43.38 eV). One of these techniques, threshold photoelectron spectroscopy, with ≈90 meV electron resolution, revealed at least 25 Individual electronic states. All of these could contribute to any other satellite spectrum, and this observation helped explain some discrepancies between previous measurements. This technique has been applied here to the same region (30 eV ⩽ Hv ⩽ 45 eV) with higher resolution (3s−1 peak). In this higher resolution spectrum at least 29 Individual electronic states are present. In some cases multiplet splitting Is observed
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