Novel mechanism of photoinduced reversible phase transitions in molecule-based magnets

A novel microscopic mechanism of bi-directional structural changes is proposed for the photo-induced magnetic phase transition in Co-Fe Prussian blue analogues on the basis of ab initio quantum chemical cluster calculations. It is shown that the local potential energies of various spin states of Co are sensitive to the number of nearest neighbor Fe vacancies. As a result, the forward and backward structural changes are most readily initiated by excitation of different local regions by different photons. This mechanism suggests an effective strategy to realize photoinduced reversible phase transitions in a general system consisting of two local components.Comment: 4 pages, LaTex, 3 figures, to appear in Phys. Rev. Let

Phenomenological theory of a scalar electronic order: application to skutterudite PrFe4P12

By phenomenological Landau analysis, it is shown that a scalar order parameter with the point-group symmetry $\Gamma_{1g}$ explains most properties associated with the phase transition in PrFe$_4$P$_{12}$ at 6.5 K. The scalar-order model reproduces magnetic and elastic properties in PrFe$_4$P$_{12}$ consistently such as (i) the anomaly of the magnetic susceptibility and elastic constant at the transition temperature, (ii) anisotropy of the magnetic susceptibility in the presence of uniaxial pressure, and (iii) the anomaly in the elastic constant in magnetic field. An Ehrenfest relation is derived which relates the anomaly of the magnetic susceptibility to that of the elastic constant at the transition.Comment: 16 pages, 9 figure

Kondo Effects and Multipolar Order in the cubic PrTr2Al20 (Tr=Ti, V)

Our single crystal study reveals that PrTr2Al20 (Tr = Ti and V) provides the first examples of a cubic {\Gamma}3 nonmagnetic ground doublet system that shows the Kondo effect including a -ln T dependent resistivity. The {\Gamma}3 quadrupolar moments in PrV2Al20 induce anomalous metallic behavior through hybridization with conduction electrons, such as T^{1/2} dependent resistivity and susceptibility below ~ 20 K down to its ordering temperature T_O = 0.6 K. In PrTi2Al20, however, quadrupoles are well-localized and exhibit an order at T_O = 2.0 K. Stronger Kondo coupling in PrV2Al20 than in PrTi2Al20 suppresses quadrupolar ordering, and instead promotes hybridization between the {\Gamma}3 doublet and conduction electrons, leading to most likely the quadrupolar Kondo effect.Comment: 12 pages, 4 figure

Toward Identification of Order Parameters in Skutterudites - a Wonderland of Strong Correlation Physics -

Current status is described toward identifying unconventional order parameters in filled skutterudites with unique ordering phenomena. The order parameters in PrFe$_4$P$_{12}$ and PrRu$_4$P$_{12}$ are discussed in relation to associated crystalline electric field (CEF) states and angular form factors. By phenomenological Landau analysis, it is shown that a scalar order model explains most properties in both PrFe$_4$P$_{12}$ and PrRu$_4$P$_{12}$ with very different magnetic properties. In particular, the highly anisotropic susceptibility induced by uniaxial pressure in PrFe$_4$P$_{12}$ is explained in terms of two types of couplings. In the case of SmRu$_4$P$_{12}$, the main order parameter at low field is identified as magnetic octupoles. A microscopic mechanism is proposed how the dipole and octupole degrees of freedom mix under the point group $T_h$ of skutterudites.Comment: To be published in Proc. International Conference on New Quantum Phenomena in Skutterudite and Related Systems (Suppl. J. Phys. Soc. Jpn 78, 2008

Pump Built-in Hamiltonian Method for Pump-Probe Spectroscopy

We propose a new method of calculating nonlinear optical responses of interacting electronic systems. In this method, the total Hamiltonian (system + system-pump interaction) is transformed into a different form that (apparently) does not have a system-pump interaction. The transformed Hamiltonian, which we call the pump built-in Hamiltonian, has parameters that depend on the strength of the pump beam. Using the pump built-in Hamiltonian, we can calculate nonlinear responses (responses to probe beams as a function of the pump beam) by applying the {\em linear} response theory. We demonstrate the basic idea of this new method by applying it to a one-dimensional, two-band model, in the case the pump excitation is virtual (coherent excitation). We find that the exponent of the Fermi edge singularity varies with the pump intensity.Comment: 6 page

Switching dynamics between metastable ordered magnetic state and nonmagnetic ground state - A possible mechanism for photoinduced ferromagnetism -

By studying the dynamics of the metastable magnetization of a statistical mechanical model we propose a switching mechanism of photoinduced magnetization. The equilibrium and nonequilibrium properties of the Blume-Capel (BC) model, which is a typical model exhibiting metastability, are studied by mean field theory and Monte Carlo simulation. We demonstrate reversible changes of magnetization in a sequence of changes of system parameters, which would model the reversible photoinduced magnetization. Implications of the calculated results are discussed in relation to the recent experimental results for prussian blue analogs.Comment: 12 pages, 13 figure

Elastic Properties and Magnetic Phase Diagrams of Dense Kondo Compound Ce0.75La0.25B6

We have investigated the elastic properties of the cubic dense Kondo compound Ce0.75La0.25B6 by means of ultrasonic measurements. We have obtained magnetic fields vs temperatures (H-T) phase diagrams under magnetic fields along the crystallographic [001], [110] and [111] axes. An ordered phase IV showing the elastic softening of c44 locates in low temperature region between 1.6 and 1.1 K below 0.7 T in all field directions. The phase IV shows an isotropic nature with regard to the field directions, while the antiferro-magnetic phase III shows an anisotropic character. A remarkable softening of c44 and a spontaneous trigonal distortion εyz+εzx+εxy recently reported by Akatsu et al. [J. Phys. Soc. Jpn. 72 (2003) 205] in the phase IV favor a ferro-quadrupole (FQ) moment of Oyz+Ozx+Oxy induced by an octupole ordering.Comment: 9 figures, Strongly Correlated Electron

Onset of inflation in inhomogeneous cosmology

We study how the initial inhomogeneities of the universe affect the onset of inflation in the closed universe. We consider the model of a chaotic inflation which is driven by a massive scalar field. In order to construct an inhomogeneous universe model, we use the long wavelength approximation ( the gradient expansion method ). We show the condition of the inhomogeneities for the universe to enter the inflationary phase.Comment: 22 pages including 12 eps figures, RevTe

Intersite coupling effects in a Kondo lattice

The La dilution of the Kondo lattice CeCoIn_5 is studied. The scaling laws found for the magnetic susceptibility and the specific heat reveal two well-separated energy scales, corresponding to the single impurity Kondo temperature T_K and an intersite spin-liquid temperature T^*. The Ce-dilute alloy has the expected Fermi liquid ground state, while the specific heat and resistivity in the dense Kondo regime exhibit non-Fermi-liquid behavior, which scales with T^*. These observations indicate that the screening of the magnetic moments in the lattice involves antiferromagnetic intersite correlations with a larger energy scale in comparison with the Kondo impurity case.Comment: 4 pages, 4 figure

Curvature perturbation in multi-field inflation with non-minimal coupling

In this paper we discuss a multi-field model of inflation in which generally all fields are non-minimally coupled to the Ricci scalar and have non-canonical kinetic terms. The background evolution and first-order perturbations for the model are evaluated in both the Jordan and Einstein frames, and the respective curvature perturbations compared. We confirm that they are indeed not the same - unlike in the single-field case - and also that the difference is a direct consequence of the isocurvature perturbations inherent to multi-field models. This result leads us to conclude that the notion of adiabaticity is not invariant under conformal transformations. Using a two-field example we show that even if in one frame the evolution is adiabatic, meaning that the curvature perturbation is conserved on super-horizon scales, in general in the other frame isocurvature perturbations continue to source the curvature perturbation. We also find that it is possible to realise a particular model in which curvature perturbations in both frames are conserved but with each being of different magnitude. These examples highlight that the curvature perturbation itself, despite being gauge-invariant, does not correspond directly to an observable. The non-equivalence of the two curvature perturbations would also be important when considering the addition of Standard Model matter into the system.Comment: 21 pages, 2 figures, references added, typos corrected, version to appear in JCA