Functionalization of carbon nanotubes using phenosafranin

The functionalization of carbon nanotubes by using phenosafranin was discussed. The self-assembly of phenosafranin (PSF) to multiwalled carbon nanotube (MWNT) was shown by using spectroscopic analysis and atomic force microscopy (AFM) phase imaging studies. It was observed that the shift in absorption spectra was associated with charge transfer of valence electrons from PSF to electron accepting sites on the MWNT. The Raman-active disorder modes were used to fingerprint PSF attachment to MWNT via defect states. A molecular topographic visual confirmation of PSF attached to the MWNT was obtained by using AFM phase imaging

Acute Decline in Renal Function, Inflammation, and Cardiovascular Risk after an Acute Coronary Syndrome

Background and objectives: Chronic kidney disease is associated with a higher risk of cardiovascular outcomes. The prognostic significance of worsening renal function has also been shown in various cohorts of cardiac disease; however, the predictors of worsening renal function and the contribution of inflammation remains to be established. Design, setting, participants, & measurements: Worsening renal function was defined as a 25% or more decrease in estimated GFR (eGFR) over a 1-mo period in patients after a non-ST or ST elevation acute coronary syndromes participating in the Aggrastat-to-Zocor Trial; this occurred in 5% of the 3795 participants. Results: A baseline C-reactive protein (CRP) in the fourth quartile was a significant predictor of developing worsening renal function (odds ratio, 2.48; 95% confidence interval, 1.49, 4.14). After adjusting for baseline CRP and eGFR, worsening renal function remained a strong multivariate predictor for the combined cardiovascular composite of CV death, recurrent myocardial infarction (MI), heart failure or stroke (hazard ratio, 1.6; 95% confidence interval, 1.1, 2.3). Conclusions: Patients with an early decline in renal function after an acute coronary syndrome are at a significant increased risk for recurrent cardiovascular events. CRP is an independent predictor for subsequent decline in renal function and reinforces the idea that inflammation may be related to the pathophysiology of progressive renal disease

A method for the reconstruction of unknown non-monotonic growth functions in the chemostat

We propose an adaptive control law that allows one to identify unstable steady states of the open-loop system in the single-species chemostat model without the knowledge of the growth function. We then show how one can use this control law to trace out (reconstruct) the whole graph of the growth function. The process of tracing out the graph can be performed either continuously or step-wise. We present and compare both approaches. Even in the case of two species in competition, which is not directly accessible with our approach due to lack of controllability, feedback control improves identifiability of the non-dominant growth rate.Comment: expansion of ideas from proceedings paper (17 pages, 8 figures), proceedings paper is version v

Quantum Interference Effects in Electronic Transport through Nanotube Contacts

Quantum interference has dramatic effects on electronic transport through nanotube contacts. In optimal configuration the intertube conductance can approach that of a perfect nanotube ($4e^2/h$). The maximum conductance increases rapidly with the contact length up to 10 nm, beyond which it exhibits long wavelength oscillations. This is attributed to the resonant cavity-like interference phenomena in the contact region. For two concentric nanotubes symmetry breaking reduces the maximum intertube conductance from $4e^2/h$ to $2e^2/h$. The phenomena discussed here can serve as a foundation for building nanotube electronic circuits and high speed nanoscale electromechanical devices

Zirconia nanotubes

Hollow nanotubes of zirconia as well as of yttria-stabilized zirconia are successfully prepared by first coating the carbon nanotubes appropriately with the oxidic material and then burning off the carbon of the template

Accident and Alcohol Detection for Two Wheelers Using Node Mcu

This paper gives description of a smart helmet to avoid Accidents on road. If he/she alcohol consumption level is more and did not wear a helmet the ignition will not on.If the rider met with an accident than immediate alert message will sent to the family member using GSM and the entire data is monitored using thingsboa

Nitrogen-containing carbon nanotubes

Carbon nanotubes containing small amounts of nitrogen are produced by the pyrolysis of aza-aromatics such as pyridine, methylpyrimidine and triazine over cobalt nanoparticles in an Ar atmosphere; good yields of such nanotubes are obtained by carrying out the pyrolysis of a mixture of pyridine and Fe(CO)5 in flowing Ar+H2

Physical characterisation of an alginate/lysozyme nano-laminate coating and its evaluation on ‘coalho’ cheese shelf life

This work aimed at the characterisation of a nanolaminate coating produced by the layer-by-layer methodology and its evaluation on the preservation of ‘Coalho’ cheese. Initially, five alternate layers of alginate and lysozyme were assembled in an aminolysed/charged polyethylene terephthalate (A/C PET) and physically characterised by UV/VIS spectroscopy, contact angle, water vapour (WVTR) and oxygen (OTR) transmission rates and scanning electron microscopy. Afterwards, the same methodology was used to apply the nano-laminate coating in ‘Coalho’ cheese and its shelf life was evaluated during 20 days in terms of mass loss, pH, lipid peroxidation, titratable acidity and microbial count. UV/VIS spectroscopy and contact angle analyses confirmed the layers’ deposition and the successful assembly of nano-laminate coating on A/C PET surface. The coating presented WVTR and OTR values of 1.03×10−3 and 1.28× 10−4 g m−2 s−1, respectively. After 20 days, coated cheese showed lower values of mass loss, pH, lipidic peroxidation, microorganisms’ proliferation and higher titratable acidity in comparison with uncoated cheese. These results suggest that gas barrier and antibacterial properties of alginate/lysozyme nanocoating can be used to extend the shelf life of ‘Coalho’ cheese.The author Bartolomeu G. de S. Medeiros is recipient of a scholarship from Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior (CAPES-Brazil). The author Marthyna P. Souza is recipient of a scholarship from Fundacao de Amparo a Ciencia e Tecnologia do Estado de Pernambuco (FACEPE, Brazil) and was recipient of a scholarship from Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior (CAPES/PDEE-Brazil). The authors Ana C. Pinheiro, Ana I. Bourbon and Miguel A. Cerqueira are recipients of a fellowship (SFRH/BD/48120/2008, SFRH/BD/73178/2010 and SFRH/BPD/72753/2010, respectively), supported by Fundacao para a Ciencia e Tecnologia, POPH-QREN and FSE (FCT, Portugal). Maria G. Carneiro-da-Cunha express is gratitude to the Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq) for research grant. The present work was supported by CAPES/PROCAD/NF/1415/2007. The support of EU Cost Action FA0904 is gratefully acknowledged

Understanding the population parameters for unicorn leatherjacket, Aluterus monoceros (Linnaeus, 1758) exploited along the Western Bay of Bengal

Information on age and growth for monocanthid species globally is limited. Aluterus monoceros forms an important fishery in the northern Indian Ocean; however, information on its population dynamics is sparse, as the species has not been explicitly studied. This study elucidates the population parameters from 1031 individuals landed in the multi-day trawl fishery along the western Bay of Bengal from January 2017 to December 2019. Total length ranged from 21.5 to 64.4 cm with a mean of 47.54 cm. Von Bertalanffy growth equation was Lt = 67.67 [1 – e –0.32 (t + 0.0592)]. The fishery was dominated by 3 and 4-year-old age classes and the estimated lifespan was 9.32 years. Recruitment was observed throughout the year and was bimodal, with the major pulse from October – February and the minor pulse from April – June producing 52.44 % and 36.24 %, respectively of the annual recruits. Natural mortality, fishing mortality and total mortality per year were 0.66, 0.55 and 1.21, respectively. Exploitation ratio was 0.45 and exploitation rate was 0.32. Though the species is currently underexploited, considering their lower capture sizes and their occurrence as by-catch in the trawl fishery, precautionary approach is suggested with management measures targeted at protecting their early life history stages