2,643 research outputs found
Glass transition in Ultrathin Polymer Films : A Thermal Expansion Study
Glass transition process gets affected in ultrathin films having thickness
comparable to the size of the molecules. We observe systematic broadening of
glass transition temperature (Tg) as the thickness of the polymer film reduces
below the radius of gyration but the change in the average Tg was found to be
very small. Existence of reversible negative and positive thermal expansion
below and above Tg increased the sensitivity of our thickness measurements
performed using energy dispersive x-ray reflectivity. A simple model of Tg
variation as a function of depth expected from sliding motion could explain the
results. We observe clear glass transition even for 4 nm polystyrene film that
was predicted to be absent from ellipsometry measurements of thicker films.Comment: 11 pages, 5 figure
Fluid-fluid phase separation in hard spheres with a bimodal size distribution
The effect of polydispersity on the phase behaviour of hard spheres is
examined using a moment projection method. It is found that the
Boublik-Mansoori-Carnahan-Starling-Leland equation of state shows a spinodal
instability for a bimodal distribution if the large spheres are sufficiently
polydisperse, and if there is sufficient disparity in mean size between the
small and large spheres. The spinodal instability direction points to the
appearance of a very dense phase of large spheres.Comment: 7 pages, 3 figures, moderately REVISED following referees' comments
(original was 4 pages, 3 postscript figures
Viscous instabilities in flowing foams: A Cellular Potts Model approach
The Cellular Potts Model (CPM) succesfully simulates drainage and shear in
foams. Here we use the CPM to investigate instabilities due to the flow of a
single large bubble in a dry, monodisperse two-dimensional flowing foam. As in
experiments in a Hele-Shaw cell, above a threshold velocity the large bubble
moves faster than the mean flow. Our simulations reproduce analytical and
experimental predictions for the velocity threshold and the relative velocity
of the large bubble, demonstrating the utility of the CPM in foam rheology
studies.Comment: 10 pages, 3 figures. Replaced with revised version accepted for
publication in JSTA
Quantum cosmology with a curvature squared action
The correct quantum description for a curvature squared term in the action
can be obtained by casting the action in the canonical form with the
introduction of a variable which is the negative of the first derivative of the
field variable appearing in the action, only after removing the total
derivative terms from the action. We present the Wheeler-DeWitt equation and
obtain the expression for the probability density and current density from the
equation of continuity. Furthermore, in the weak energy limit we obtain the
classical Einstein equation. Finally we present a solution of the wave
equation.Comment: 8 pages, revte
Dynamics of diluted magnetic semiconductors from atomistic spin dynamics simulations: Mn doped GaAs as a case study
The dynamical behavior of the magnetism of diluted magnetic semiconductors
(DMS) has been investigated by means of atomistic spin dynamics simulations.
The conclusions drawn from the study are argued to be general for DMS systems
in the low concentration limit, although all simulations are done for 5%
Mn-doped GaAs with various concentrations of As antisite defects. The
magnetization curve, , and the Curie temperature have been
calculated, and are found to be in good correspondence to results from Monte
Carlo simulations and experiments. Furthermore, equilibrium and non-equilibrium
behavior of the magnetic pair correlation function have been extracted. The
dynamics of DMS systems reveals a substantial short ranged magnetic order even
at temperatures at or above the ordering temperature, with a non-vanishing pair
correlation function extending up to several atomic shells. For the high As
antisite concentrations the simulations show a short ranged anti-ferromagnetic
coupling, and a weakened long ranged ferromagnetic coupling. For sufficiently
large concentrations we do not observe any long ranged ferromagnetic
correlation. A typical dynamical response shows that starting from a random
orientation of moments, the spin-correlation develops very fast ( 1ps)
extending up to 15 atomic shells. Above 10 ps in the simulations, the
pair correlation is observed to extend over some 40 atomic shells. The
autocorrelation function has been calculated and compared with ferromagnets
like bcc Fe and spin-glass materials. We find no evidence in our simulations
for a spin-glass behaviour, for any concentration of As antisites. Instead the
magnetic response is better described as slow dynamics, at least when compared
to that of a regular ferromagnet like bcc Fe.Comment: 24 pages, 15 figure
Extraction of density profile for near perfect multilayers
A simple inversion scheme, based on Born approximation, to determine the electron density profile of near perfect multilayers from specular X-ray reflectivity data has been presented. This scheme is useful for semiconductor multilayers and other thin films, which are grown almost according to the designed parameters. We also indicate the possibility of separating out the contribution of interdiffusion and roughness in electron density profiles of interfaces by utilizing information obtained from the analysis of diffuse scattering data. The extracted compositional profile was used to calculate structural details of epitaxial films along the growth direction. Simulated and metal organic vapor phase epitaxy grown InP/InxGa1−xAs/InP quantum-well systems have been used to demonstrate this scheme
Magnetic properties of 3d-impurities substituted in GaAs
We have calculated the magnetic properties of substituted 3d-impurities
(Cr-Ni) in a GaAs host by means of first principles electronic structure
calculations. We provide a novel model explaining the ferromagnetic long rang
order of III-V dilute magnetic semiconductors. The origin of the ferromagnetism
is shown to be due to delocalized spin-uncompensated As dangling bond
electrons. Besides the quantitative prediction of the magnetic moments, our
model provides an understanding of the halfmetallicity, and the raise of the
critical temperature with the impurity concentration
The evolution of rotating very massive stars with LMC composition
We present a dense model grid with tailored input chemical composition
appropriate for the Large Magellanic Cloud. We use a one-dimensional
hydrodynamic stellar evolution code, which accounts for rotation, transport of
angular momentum by magnetic fields, and stellar wind mass loss to compute our
detailed models. We calculate stellar evolution models with initial masses of
70-500 Msun and with initial surface rotational velocities of 0-550 km/s,
covering the core-hydrogen burning phase of evolution. We find our rapid
rotators to be strongly influenced by rotationally induced mixing of helium,
with quasi-chemically homogeneous evolution occurring for the fastest rotating
models. Above 160 Msun, homogeneous evolution is also established through mass
loss, producing pure helium stars at core hydrogen exhaustion independent of
the initial rotation rate. Surface nitrogen enrichment is also found for slower
rotators, even for stars that lose only a small fraction of their initial mass.
For models above 150 MZAMS, and for models in the whole considered mass range
later on, we find a considerable envelope inflation due to the proximity of
these models to their Eddington limit. This leads to a maximum zero-age main
sequence surface temperature of 56000 K, at 180 Msun, and to an evolution of
stars in the mass range 50-100 Msun to the regime of luminous blue variables in
the HR diagram with high internal Eddington factors. Inflation also leads to
decreasing surface temperatures during the chemically homogeneous evolution of
stars above 180 Msun. The cool surface temperatures due to the envelope
inflation in our models lead to an enhanced mass loss, which prevents stars at
LMC metallicity from evolving into pair-instability supernovae. The
corresponding spin-down will also prevent very massive LMC stars to produce
long-duration gamma-ray bursts, which might, however, originate from lower
masses.Comment: 21 pages, 25 figure
Stability and Stabilization of Relative Equilibria of Dumbbell Bodies in Central Gravity
Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/77368/1/AIAA-10546-792.pd
Evidence for Hysteretic Substrate Channeling in the Proline Dehydrogenaseand ∆\u3csup\u3e1\u3c/sup\u3e-Pyrroline-5-carboxylate Dehydrogenase Coupled Reaction of Proline UtilizationA(PutA)
Background: PutA from Escherichia coli is a bifunctional enzyme and transcriptional repressor in proline catabolism.
Results: Steady-state and transient kinetic data revealed a mechanism in which the two enzymatic reactions are coupled by an activation step.
Conclusion: Substrate channeling in PutA exhibits hysteretic behavior.
Significance: This is the first kinetic model of bi-enzyme activity in PutA and reveals a novel mechanism of channeling activation
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