Glass transition in Ultrathin Polymer Films : A Thermal Expansion Study

Glass transition process gets affected in ultrathin films having thickness comparable to the size of the molecules. We observe systematic broadening of glass transition temperature (Tg) as the thickness of the polymer film reduces below the radius of gyration but the change in the average Tg was found to be very small. Existence of reversible negative and positive thermal expansion below and above Tg increased the sensitivity of our thickness measurements performed using energy dispersive x-ray reflectivity. A simple model of Tg variation as a function of depth expected from sliding motion could explain the results. We observe clear glass transition even for 4 nm polystyrene film that was predicted to be absent from ellipsometry measurements of thicker films.Comment: 11 pages, 5 figure

Energy dependent wavelength of the ion induced nanoscale ripple

Wavelength variation of ion beam induced nanoscale ripple structure has received much attention recently due to its possible application in nanotechnology. We present here results of Ar$^+$ bombarded Si in the energy range 50 to 140 keV to demonstrate that with beam scanning the ripple wavelength increases with ion energy and decreases with energy for irradiation without ion beam scanning. An expression for the energy dependence of ripple wavelength is proposed taking into simultaneous effect of thermally activated surface diffusion and ion induced effective surface diffusion.Comment: REVTeX (4 pages), 3 EPS figure

Two-dimensional Induced Ferromagnetism

Magnetic properties of materials confined to nanometer length scales are providing important information regarding low dimensional physics. Using gadolinium based Langmuir-Blodgett films, we demonstrate that two-dimensional ferromagnetic order can be induced by applying magnetic field along the in-plane (perpendicular to growth) direction. Field dependent exchange coupling is evident in the in-plane magnetization data that exhibit absence of hysteresis loop and show reduction in field required to obtain saturation in measured moment with decreasing temperature.Comment: 4 pages, 3 postscript figures, corrected paper forma

Formation of rectifier with gold nanoclusters

Gold nanoclusters encapsulated with organic molecules are of great interest for its possible applications in the fields of molecular electronics, catalysis and medical science. Here we demonstrate that monolayer and bilayer films of thiol-capped gold nanoclusters can exhibit diode-like properties provided controlled spatial asymmetry exist between two tunnel junctions used to connect a thiol capped gold nanoclusters. Current-voltage characteristics of this rectifier were obtained from conducting probe atomic force microscopy measurements and also from conventional two probe resistance measurements. Systematic x-ray reflectivity and atomic force microscopy measurements were carried out to characterize the spatial asymmetry introduced by a monolayer of fatty acid salt gadolinium stearate used to deposit thiol-capped gold nanocluster molecules on hydrophilic SiO2-Si(001) substrate by Langmuir Blodgett technique. This information was used to explain prominent rectification observed in these nano-structured films.Comment: 13 pages, 3 figure

Growth mechanism of Langmuir-Blodgett films

Langmuir-Blodgett (LB) deposition is an astonishingly simple technique to grow well-ordered correlated metal-organic multilayers. To understand this growth mechanism, we have performed X-ray scattering and atomic force microscopic (AFM) studies on cadmium arachidate LB films exhibiting self-affine and logarithmic in-plane correlation at the interfaces. Using linear stochastic theory for interface evolution, it is proposed that a 1D deposition followed by a 2D desorption process is the growth mechanism of LB films. X-ray and AFM measurements confirm the crossover between these two growth regimes

Excited hadrons as a signal for quark-gluon plasma formation

At the quark-hadron transition, when quarks get confined to hadrons, certain orbitally excited states, namely those which have excitation energies above the respective $L = 0$ states of the same order as the transition temperature $T_c$, may form easily because of thermal velocities of quarks at the transition temperature. We propose that the ratio of multiplicities of such excited states to the respective $L = 0$ states can serve as an almost model independent signal for the quark-gluon plasma formation in relativistic heavy-ion collisions. For example, the ratio $R^*$ of multiplicities of $D_{SJ}^{*\pm}(2317)(J^P = 0^+)$ and $D_S^{*\pm}(2112)(J^P = 1^-)$ when plotted with respect to the center of mass energy of the collision $\sqrt{s}$ (or vs. centrality/number of participants), should show a jump at the value of $\sqrt{s}$ beyond which the QGP formation occurs. This should happen irrespective of the shape of the overall plot of $R^*$ vs. $\sqrt{s}$. Recent data from RHIC on $\Lambda^*/\Lambda$ vs. N$_{part}$ for large values of N$_{part}$ may be indicative of such a behavior, though there are large error bars. We give a list of several other such candidate hadronic states.Comment: 19 pages, RevTex, no figures, minor change