Observation of Ag Nanoparticles in/on Ag@MIL-100(Fe) Prepared Through Different Procedures

Loading of active metals, metal clusters, and/or metal nanoparticles in Metal Organic Frameworks (MOFs) is an emergent field with applications in sensors, catalysis, medicine, and even in the polymeric industry. In the present work, MIL-100(Fe) has been synthesized and reacted with AgNO3 through liquid and incipient wetness, and also through solid-state reaction or solid grinding. The aim of this study is to evaluate whether the MIL-100 would uptake metal particles using a similar principle as that of the ion exchange in zeolites, or else, their inherent humidity would favor the “dissolution” of the metal salt, thus yielding very small metal particles. The immobilization of Ag nanoparticles inside the MOF pores was identified by Cs-corrected scanning transmission electron microscopy (Cs-corrected STEM) techniques

Renormalization Group and Grand Unification with 331 Models

By making a renormalization group analysis we explore the possibility of having a 331 model as the only intermediate gauge group between the standard model and the scale of unification of the three coupling constants. We shall assume that there is no necessarily a group of grand unification at the scale of convergence of the couplings. With this scenario, different 331 models and their corresponding supersymmetric versions are considered, and we find the versions that allow the symmetry breaking described above. Besides, the allowed interval for the 331 symmetry breaking scale, and the behavior of the running coupling constants are obtained. It worths saying that some of the supersymmetric scenarios could be natural frameworks for split supersymmetry. Finally, we look for possible 331 models with a simple group at the grand unification scale, that could fit the symmetry breaking scheme described above.Comment: 18 pages. 3 figures. Some results reinterpreted, a new section and references added. Version to appear in International Journal of Modern Physics

Anderson Localization Phenomenon in One-dimensional Elastic Systems

The phenomenon of Anderson localization of waves in elastic systems is studied. We analyze this phenomenon in two different set of systems: disordered linear chains of harmonic oscillators and disordered rods which oscillate with torsional waves. The first set is analyzed numerically whereas the second one is studied both experimentally and theoretically. In particular, we discuss the localization properties of the waves as a function of the frequency. In doing that we have used the inverse participation ratio, which is related to the localization length. We find that the normal modes localize exponentially according to Anderson theory. In the elastic systems, the localization length decreases with frequency. This behavior is in contrast with what happens in analogous quantum mechanical systems, for which the localization length grows with energy. This difference is explained by means of the properties of the re ection coefficient of a single scatterer in each case.Comment: 15 pages, 10 figure

High spatial resolution and high contrast optical speckle imaging with FASTCAM at the ORM

In this paper, we present an original observational approach, which combines, for the first time, traditional speckle imaging with image post-processing to obtain in the optical domain diffraction-limited images with high contrast (1e-5) within 0.5 to 2 arcseconds around a bright star. The post-processing step is based on wavelet filtering an has analogy with edge enhancement and high-pass filtering. Our I-band on-sky results with the 2.5-m Nordic Telescope (NOT) and the lucky imaging instrument FASTCAM show that we are able to detect L-type brown dwarf companions around a solar-type star with a contrast DI~12 at 2" and with no use of any coronographic capability, which greatly simplifies the instrumental and hardware approach. This object has been detected from the ground in J and H bands so far only with AO-assisted 8-10 m class telescopes (Gemini, Keck), although more recently detected with small-class telescopes in the K band. Discussing the advantage and disadvantage of the optical regime for the detection of faint intrinsic fluxes close to bright stars, we develop some perspectives for other fields, including the study of dense cores in globular clusters. To the best of our knowledge this is the first time that high contrast considerations are included in optical speckle imaging approach.Comment: Proceedings of SPIE conference - Ground-based and Airborne Instrumentation for Astronomy III (Conference 7735), San Diego 201

Major requirements for building Smart Homes in Smart Cities based on Internet of Things technologies

The recent boom in the Internet of Things (IoT) will turn Smart Cities and Smart Homes (SH) from hype to reality. SH is the major building block for Smart Cities and have long been a dream for decades, hobbyists in the late 1970s made Home Automation (HA) possible when personal computers started invading home spaces. While SH can share most of the IoT technologies, there are unique characteristics that make SH special. From the result of a recent research survey on SH and IoT technologies, this paper defines the major requirements for building SH. Seven unique requirement recommendations are defined and classified according to the specific quality of the SH building blocks

The role of gas infall in the evolution of disc galaxies

Spiral galaxies are thought to acquire their gas through a protracted infall phase resulting in the inside-out growth of their associated discs. For field spirals, this infall occurs in the lower density environments of the cosmic web. The overall infall rate, as well as the galactocentric radius at which this infall is incorporated into the star-forming disc, plays a pivotal role in shaping the characteristics observed today. Indeed, characterising the functional form of this spatio-temporal infall in-situ is exceedingly difficult, and one is forced to constrain these forms using the present day state of galaxies with model or simulation predictions. We present the infall rates used as input to a grid of chemical evolution models spanning the mass spectrum of discs observed today. We provide a systematic comparison with alternate analytical infall schemes in the literature, including a first comparison with cosmological simulations. Identifying the degeneracies associated with the adopted infall rate prescriptions in galaxy models is an important step in the development of a consistent picture of disc galaxy formation and evolution