9 research outputs found

    Tripyrrolidinophosphoric acid triamide as an activator in samarium diiodide reductions

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    The electrochemical and spectrophotometric characterization of the complex formed from samarium diiodide and 4 equiv of tripyrrolidinophosphoric acid triamide (TPPA) is presented. Kinetic studies indicate that the SmI(2)/TPPA complex possesses reactivity greater than the complex formed between samarium diiodide and 4 equiv of HMPA. Examples of the use of SmI(2)/TPPA in synthesis are presented

    Bibliography: longevity, ageing and parental age effects in Drosophila (1907–86)

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