21 research outputs found

    In-situ TEM Synthesis of WO 2.9

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    Elaboration and mechanical characterization of multi-phase alumina-based ultra-fine composites

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    Al2O3-10 vol.% YAG and Al2O3-10 vol.% ZrO2 bi-phase composites as well as Al2O3-5 vol.% YAG-5 vol.% ZrO2 tri-phase composite were developed by controlled sur- face modi\ufb01cation of an alumina powder with inorganic pre- cursors of the second phases. Green bodies were produced by dry pressing and slip casting and then sintered at 1500 \ub0C. In particular, slip casting led to fully dense, defect-free, and highly homogenous samples, made of a \ufb01ne dispersion of the second phases into the micronic alumina matrix, as observed by SEM. The mechanical characterization proved the pre- dominant role of the \ufb01nal density on the Vickers hardness, while the elastic modulus was affected by the volume fraction of the constituent phases, in fairly good agreement with the rule of mixture prediction. The fracture toughness values of the bi- and tri-phase materials were similar, and their crack paths revealed the importance of the thermal residual stresses at the matrix-reinforcement interfaces, promoting inter- granular propagation
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