Low temperature structural effects in the (TMTSF)2_2PF6_6 and AsF6_6 Bechgaard salts

We present a detailed low-temperature investigation of the statics and dynamics of the anions and methyl groups in the organic conductors (TMTSF)$_2$PF$_6$ and (TMTSF)$_2$AsF$_6$ (TMTSF : tetramethyl-tetraselenafulvalene). The 4 K neutron scattering structure refinement of the fully deuterated (TMTSF)$_2$PF$_6$-D12 salt allows locating precisely the methyl groups at 4 K. This structure is compared to the one of the fully hydrogenated (TMTSF)$_2$PF$_6$-H12 salt previously determined at the same temperature. Surprisingly it is found that deuteration corresponds to the application of a negative pressure of 5 x 10$^2$ MPa to the H12 salt. Accurate measurements of the Bragg intensity show anomalous thermal variations at low temperature both in the deuterated PF$_6$ and AsF$_6$ salts. Two different thermal behaviors have been distinguished. Low-Bragg-angle measurements reflect the presence of low-frequency modes at characteristic energies {\theta}$_E$ = 8.3 K and {\theta}$_E$ = 6.7 K for the PF$_6$-D12 and AsF$_6$-D12 salts, respectively. These modes correspond to the low-temperature methyl group motion. Large-Bragg-angle measurements evidence an unexpected structural change around 55 K which probably corresponds to the linkage of the anions to the methyl groups via the formation of F...D-CD2 bonds observed in the 4 K structural refinement. Finally we show that the thermal expansion coefficient of (TMTSF)$_2$PF$_6$ is dominated by the librational motion of the PF$_6$ units. We quantitatively analyze the low-temperature variation of the lattice expansion via the contribution of Einstein oscillators, which allows us to determine for the first time the characteristic frequency of the PF6 librations: {\theta}$_E$ = 50 K and {\theta}$_E$ = 76 K for the PF$_6$-D12 and PF$_6$-H12 salts, respectively

Transient Charging and Discharging of Spin-polarized Electrons in a Quantum Dot

We study spin-polarized transient transport in a quantum dot coupled to two ferromagnetic leads subjected to a rectangular bias voltage pulse. Time-dependent spin-resolved currents, occupations, spin accumulation, and tunneling magnetoresistance (TMR) are calculated using both nonequilibrium Green function and master equation techniques. Both parallel and antiparallel leads' magnetization alignments are analyzed. Our main findings are: a dynamical spin accumulation that changes sign in time, a short-lived pulse of spin polarized current in the emitter lead (but not in the collector lead), and a dynamical TMR that develops negative values in the transient regime. We also observe that the intra-dot Coulomb interaction can enhance even further the negative values of the TMR.Comment: 7 pages, 6 figures. Typos corrections corresponding to the published versio

Entanglement and Bell's inequality violation above room temperature in metal carboxylates

In the present work we show that a special family of materials, the metal carboxylates, may have entangled states up to very high temperatures. From magnetic susceptibility measurements, we have estimated the critical temperature below which entanglement exists in the cooper carboxylate \{Cu$_2$(O$_2$CH)$_4$\}\{Cu(O$_2$CH)$_2$(2-methylpyridine)$_2$\}, and we have found this to be above room temperature ($T_e \sim 630$ K). Furthermore, the results show that the system remains maximally entangled until close to $\sim 100$ K and the Bell's inequality is violated up to nearly room temperature ($\sim 290$ K)

Diagnose das principais doenças do cupuaçuzeiro (Theobroma grandiflorum (Willd. ex Spreng.) Schum.) e seu controle.

Cupuaçu: vassoura-de-bruxa, morte progressiva, podridao vermelha, mancha de Phomopsis.bitstream/CPAA-2009-09/2032/1/Doc_9_98.pd

Coherent States for the Non-Linear Harmonic Oscillator

Wave packets for the Quantum Non-Linear Oscillator are considered in the Generalized Coherent State framerwork. To first order in the non-linearity parameter the Coherent State behaves very similarly to its classical counterpart. The position expectation value oscillates in a simple harmonic manner. The energy-momentum uncertainty relation is time independent as in a harmonic oscillator. Various features, (such as the Squeezed State nature), of the Coherent State have been discussed

Polarization and Strong Infra-Red Activity in Compressed Solid Hydrogen

Under a pressure of ~150 GPa solid molecular hydrogen undergoes a phase transition accompanied by a dramatic rise in infra-red absorption in the vibron frequency range. We use the Berry's phase approach to calculate the electric polarization in several candidate structures finding large, anisotropic dynamic charges and strongly IR-active vibron modes. The polarization is shown to be greatly affected by the overlap between the molecules in the crystal, so that the commonly used Clausius-Mossotti description in terms of polarizable, non-overlapping molecular charge densities is inadequate already at low pressures and even more so for the compressed solid.Comment: To appear in Phys. Rev. Let