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    Crystal structure of germanium(II) dichloride solvated by tetrahydrofuran

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    Tian X, Pape T, Mitzel NW. Crystal structure of germanium(II) dichloride solvated by tetrahydrofuran. HETEROATOM CHEMISTRY. 2005;16(5):361-363.The thermally highly unstable tetrahydrofuran solvate of germanium(H) dichloride (GeCl2 - 2THF) was crystallized, and its crystal structure was determined. It consists of a chain of GeCl2 units connected by secondary Cl...Ge contacts [3.846(2) angstrom] in which each Ge atom is coordinated to two molecules of THE Two weak hydrogen bonds of the C-H... Cl-Ge type in GeCl2.2THF were also detected both with lengths of 2.90(3) A. (c) 2005 Wiley Periodicals, Inc
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