3 research outputs found
Isotherm and Kinetic Studies on Adsorption of Pb, Zn and Cu by Kaolinite
The feasibility of kaolinite used as a low-cost adsorbent for the removal of Pb(II), Zn(II) and Cu(II) from
aqueous solutions was investigated. During the removal process, batch technique was used, and the
effects of heavy metal concentration and contact time on adsorption efficiency at pH of 4.5, under a
constant temperature of 20±1 °C were studied. The experimental results were analyzed using four
adsorption isotherm models; Freundlich, Langmuir, Temkin and Redlich-Peterson. Evaluating the
correlation coefficients showed that the Redlich-Peterson isotherm described the data appropriable than
others. The adsorption capacities (qm) from the Langmuir isotherm for Pb(II), Zn(II) and Cu(II) are found
as 7.75 mg/g, 4.95 mg/g and 4.42 mg/g respectively. The effectiveness of kaolinite in the sorption of the
three metals from aqueous system was Pb(II) > Zn(II) > Cu(II). Kinetic studies showed that a pseudosecond order model was more suitable than the pseudo first order model. It is concluded that kaolinite can
be used as an effective adsorbent for removing Pb(II), Zn(II) and Cu(II) from aqueous solutions