Monte Carlo simulations of interfaces in polymer blends

We review recent simulation studies of interfaces between immiscible homopolymer phases. Special emphasis is given to the presentation of efficient simulation techniques and powerful methods of data analysis, such as the analysis of capillary wave spectra. Possible reasons for polymer incompatibility and ways to relate model dependent interaction parameters to an effective Flory Huggins parameter are discussed. Various interfaces are then considered and characterised with respect to their microscopic structure and thermodynamic properties. In particular, interfaces between homopolymers of equal or disparate stiffness are studied, interfaces containing diblock copolymers, and interfaces confined in thin films. The results are related to the phase behaviour of ternary homopolymer/copolymer systems, and to wetting transitions in thin films.Comment: To appear in Annual Reviews of Computational Physics, edt. D. Stauffe

Spectropolarimetry of the borderline Seyfert 1 galaxy ESO 323-G077

We report the detection of high linear polarization in the bright Seyfert 1 galaxy ESO 323-G077. Based on optical spectropolarimetry with FORS1 at the VLT we find a continuum polarization which ranges from 2.2 % at 8300A to 7.5 % at 3600A. Similar amounts of linear polarization are found for the broad emission lines, while the narrow lines are not polarized. The position angle of the polarization is independent of the wavelength and found to be perpendicular to the orientation of the extended [OIII] emission cone of this galaxy. Within the standard model of Seyfert nuclei the observations can be well understood assuming that this AGN is observed at an inclination angle where the nucleus is partially obscured and seen mainly indirectly in the light scattered by dust clouds within or above the torus and the illuminated inner edge of the dust torus itself. Hence we conclude that ESO 323-G077 is a borderline Seyfert 1 galaxy which can provide important information on the geometric properties of active nuclei

Leadership Structure and Corporate Governance in Switzerland

The question of whether the CEO should also serve as chairman of the board is one of the most hotly debated issues in the recent corporate governance discussion. While agencytheoretic arguments advocate a separation of decision and control functions, the empirical evidence focusing on U.S. companies is not conclusive. In this context evidence from a country with a different practice of CEO succession may provide important new insights with respect to the question of whether one leadership structure should generally be preferred to the other one. This article fills this gap by investigating the valuation effects of leadership structure in Switzerland where – in contrast to the U.S. – a separation of the CEO and chairman functions is common. Consistent with the majority of prior research focusing on the U.S., the authors found no evidence of a systematic and significant difference in valuation between firms with combined and firms with separated functions. They also investigated whether leadership structure is related to firm-level corporate governance characteristics and found a similar curvilinear relationship between leadership structure and managerial shareholdings as is observed between firm value and managerial shareholdings. An implication is that possible agency costs associated with a combined function are mitigated by a higher incentive alignment of the CEO/chairman through an adequate level of managerial shareholdings. Over the last few years corporate governance became an important investment criterion, which is for example reflected in the emergence of various corporate governance ratings. The authors of this article additionally investigated whether firm value is significantly related to firm level corporate governance as measured by a broad survey-based index for a representative sample of Swiss firms. They documented a positive and significant relationship between the corporate governance index and firm valuation. This finding is robust to controlling for a series of additional governance mechanisms related to ownership structure, board characteristics, and leverage as well as a potential endogeneity of these mechanisms.Leadership structure; Firm valuation; Corporate governance; Managerial shareholdings

Organic Farming Research Support and Research Priorities in the European Union

Support for Organic Farming focused research has increased significantly in successive EU research funding frameworks. This is in line with constantly increasing consumer demand for organic foods over the last 20 years, which has accelerated again over the last 2 years in many European countries, including new member states. Under the 7th Framework Programme (FP7), the expected new increase of funds for organic farming could significantly decrease, even below the levels made available under the 5th Framework Programme (FP5). Most of the project topics listed focus on the development of methods for economic analyses of Organic Farming and/or follow a very “reductionist” one problem - one potential solution approach. On the other side, as there is no clear instruments to establish priorities in research programmes at European level. The IFOAM EU Group has developed a consultation process to set organic farming sector priorities, which could be used as a model to set research priorities in the future. This paper also presents a first assessment of the EU support to organic farming research, reviewing main achievements in organic food production systems research and proposing some changes in the current 7th Framework Programme

Disorder Induced Stripes in d-Wave Superconductors

Stripe phases are observed experimentally in several copper-based high-Tc superconductors near 1/8 hole doping. However, the specific characteristics may vary depending on the degree of dopant disorder and the presence or absence of a low- temperature tetragonal phase. On the basis of a Hartree-Fock decoupling scheme for the t-J model we discuss the diverse behavior of stripe phases. In particular the effect of inhomogeneities is investigated in two distinctly different parameter regimes which are characterized by the strength of the interaction. We observe that small concen- trations of impurities or vortices pin the unidirectional density waves, and dopant disorder is capable to stabilize a stripe phase in parameter regimes where homogeneous phases are typically favored in clean systems. The momentum-space results exhibit universal features for all coexisting density-wave solutions, nearly unchanged even in strongly disordered systems. These coexisting solutions feature generically a full energy gap and a particle-hole asymmetry in the density of states.Comment: 28 pages, 8 figure

Monte Carlo simulations of liquid crystals near rough walls

The effect of surface roughness on the structure of liquid crystalline fluids near solid substrates is studied by Monte Carlo simulations. The liquid crystal is modeled as a fluid of soft ellipsoidal molecules and the substrate is modeled as a hard wall that excludes the centers of mass of the fluid molecules. Surface roughness is introduced by embedding a number of molecules with random positions and orientations within the wall. It is found that the density and order near the wall are reduced as the wall becomes rougher, i.e., the number of embedded molecules is increased). Anchoring coefficients are determined from fluctuations in the reciprocal space order tensor. It is found that the anchoring strength decreases with increasing surface roughness

On the Melting of Bosonic Stripes

We use quantum Monte Carlo simulations to determine the finite temperature phase diagram and to investigate the thermal and quantum melting of stripe phases in a two-dimensional hard-core boson model. At half filling and low temperatures the stripes melt at a first order transition. In the doped system, the melting transitions of the smectic phase at high temperatures and the superfluid smectic (supersolid) phase at low temperatures are either very weakly first order, or of second order with no clear indications for an intermediate nematic phase.Comment: 4 pages, 5 figure

Chemical ordering and composition fluctuations at the (001) surface of the Fe-Ni Invar alloy

We report on a study of (001) oriented fcc Fe-Ni alloy surfaces which combines first-principles calculations and low-temperature STM experiments. Density functional theory calculations show that Fe-Ni alloy surfaces are buckled with the Fe atoms slightly shifted outwards and the Ni atoms inwards. This is consistent with the observation that the atoms in the surface layer can be chemically distinguished in the STM image: brighter spots (corrugation maxima with increased apparent height) indicate iron atoms, darker ones nickel atoms. This chemical contrast reveals a c2x2 chemical order (50% Fe) with frequent Fe-rich defects on Invar alloy surface. The calculations also indicate that subsurface composition fluctuations may additionally modulate the apparent height of the surface atoms. The STM images show that this effect is pronounced compared to the surfaces of other disordered alloys, which suggests that some chemical order and corresponding concentration fluctuations exist also in the subsurface layers of Invar alloy. In addition, detailed electronic structure calculations allow us to identify the nature of a distinct peak below the Fermi level observed in the tunneling spectra. This peak corresponds to a surface resonance band which is particularly pronounced in iron-rich surface regions and provides a second type of chemical contrast with less spatial resolution but one that is essentially independent of the subsurface composition.Comment: 7 pages, 5 figure