25 research outputs found
Homogeneous catalytic hydrogenation of diethyl- and diphenyl-acetylene and isomerisation of Cis-stilbene in the presence of [(C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>Ru<sub>3</sub>(CO)<sub>3</sub>(μ-CO)(μ<sub>3</sub>-CO)(C<sub>2</sub>Ph<sub>2</sub>)]
No full textSynthesis and reactivity of dimetallacyclopentenone complexes [Ru<sub>2</sub>(CO)(μ-CO){μ-C(O)CR<sup>1</sup>CR<sup>2</sup>}(η-C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>](R<sup>1</sup>=Me or Ph; R<sup>2</sup>=CO<sub>2</sub>Me): X-ray crystal structures of [Ru<sub>2</sub>(CO)<sub>2</sub>{μ-η<sup>2</sup>,η<sup>2</sup>-C(O)C<sub>6</sub>H<sub>4</sub>C=C(H)CO<sub>2</sub>Me}(η-C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>] and[Ru<sub>3</sub>(CO)(μ-CO)<sub>2</sub>{μ<sub>3</sub>-η<sup>2</sup>-C(Ph)CCO<sub>2</sub>Me}(μ-η<sup>1</sup>,η<sup>5</sup>-C<sub>5</sub>H<sub>4</sub>)(η-C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>]
No full textReactivity of allene at phosphine-bridged di-iron centres: X-ray crystal structures of [Fe<sub>2</sub>(CO)<sub>5</sub>{?-?,?<sup>3</sup>-C(O)C(CH<sub>2</sub>)<sub>2</sub>}(?-dppm)] and [Fe<sub>2</sub>(CO)<sub>4</sub>{?-?<sup>3</sup>,?<sup>3</sup>'-(CH<sub>2</sub>)<sub>2</sub>C<sub>2</sub>(CH<sub>2</sub>)<sub>2</sub>}(?-dppm)].Et<sub>2</sub>O
No full textReactivity of Bis(diphenylphosphino)methane at a di-iron centre; thermally induced rearrangements of dimetallacyclopentenone complexes [Fe<sub>2</sub>(CO)<sub>5</sub>{μ-σ,η<sup>3</sup>-C(O)CRCR}(μ-dppm)]
No full textHomogeneous hydrogenation of alkynes and 1,4-cyclohexadiene in the presence of the clusters Ru<sub>3</sub>(CO)<sub>7</sub>(μ-PPh<sub>2</sub>)<sub>2</sub>(C<sub>6</sub>H<sub>4</sub>), Ru<sub>4</sub>(CO)<sub>1</sub><sub>1</sub>(μ<sub>4</sub>-PPh)(C<sub>6</sub>H<sub>4</sub>), Ru<sub>3</sub>(CO)<sub>7</sub>(μ-PPh<sub>2</sub>)(HC<sub>P</sub>h) and Ru<sub>4</sub>(CO)<sub>1</sub><sub>1</sub>(μ<sub>4</sub>-PPh)(C<sub>2</sub>Ph<sub>2</sub>
No full text
