394 research outputs found
The deuterium effect on electrochemiluminescence efficiencies of anthracene and phenanthrene
The effect of deuteration on the electrochemiluminescence (ECL) efficiencies of the mixed systems containing anthracene or phenathrene has been examined using the single light pulse in the double potential programme. Deuteration of anthracene or phenanthrene decreases the ECL efficiencies by factors of 1·2-16·0. This decrease appears to arise from the quenching of the triplets by radical ions in solution. The quenching factors are estimated by using Marcus theory of electron transfer reactions
Studies on efficiencies of electrochemiluminescence of rubrene
The electrochemiluminescence efficiencies of rubrene system has been obtained by using the transient method in a variety of solvents. The efficiencies are in the range of 0·11×10-3-4·1×10-2. The mixed system efficiencies are less at least by an order of magnitude in all the solvents except in dimethylsulphoxide. The variation in efficiencies of the pure and mixed systems is explained on the basis of mechanistic differences. In the applied magnetic field, the electrochemiluminescence efficiency of the pure system increases by about 7% and of the mixed system by about 18-25%
Quantum information distributors: Quantum network for symmetric and asymmetric cloning in arbitrary dimension and continuous limit
We show that for any Hilbert-space dimension, the optimal universal quantum
cloner can be constructed from essentially the same quantum circuit, i.e., we
find a universal design for universal cloners. In the case of infinite
dimensions (which includes continuous variable quantum systems) the universal
cloner reduces to an essentially classical device. More generally, we construct
a universal quantum circuit for distributing qudits in any dimension which acts
covariantly under generalized displacements and momentum kicks. The behavior of
this covariant distributor is controlled by its initial state. We show that
suitable choices for this initial state yield both universal cloners and
optimized cloners for limited alphabets of states whose states are related by
generalized phase-space displacements.Comment: 10 revtex pages, no figure
Statistics of Atmospheric Correlations
For a large class of quantum systems the statistical properties of their
spectrum show remarkable agreement with random matrix predictions. Recent
advances show that the scope of random matrix theory is much wider. In this
work, we show that the random matrix approach can be beneficially applied to a
completely different classical domain, namely, to the empirical correlation
matrices obtained from the analysis of the basic atmospheric parameters that
characterise the state of atmosphere. We show that the spectrum of atmospheric
correlation matrices satisfy the random matrix prescription. In particular, the
eigenmodes of the atmospheric empirical correlation matrices that have physical
significance are marked by deviations from the eigenvector distribution.Comment: 8 pages, 9 figs, revtex; To appear in Phys. Rev.
Mesoscopic Ferromagnet/Superconductor Junctions and the Proximity Effect
We have measured the electrical transport of submicron ferromagnets (Ni) in
contact with a mesoscopic superconductor (Al) for a range of interface
resistances. In the geometry measured, the interface and the ferromagnet are
measured separately. The ferromagnet itself shows no appreciable
superconducting proximity effect, but the ferromagnet/superconductor interface
exhibits strong temperature, field and current bias dependences. These effects
are dependent on the local magnetic field distribution near the interface
arising from the ferromagnet. We find that the temperature dependences may be
fit to a modified version of the Blonder-Tinkham-Klapwijk theory for
normal-superconductor transport.Comment: 4 eps fig
Large Scale Cross-Correlations in Internet Traffic
The Internet is a complex network of interconnected routers and the existence
of collective behavior such as congestion suggests that the correlations
between different connections play a crucial role. It is thus critical to
measure and quantify these correlations. We use methods of random matrix theory
(RMT) to analyze the cross-correlation matrix C of information flow changes of
650 connections between 26 routers of the French scientific network `Renater'.
We find that C has the universal properties of the Gaussian orthogonal ensemble
of random matrices: The distribution of eigenvalues--up to a rescaling which
exhibits a typical correlation time of the order 10 minutes--and the spacing
distribution follow the predictions of RMT. There are some deviations for large
eigenvalues which contain network-specific information and which identify
genuine correlations between connections. The study of the most correlated
connections reveals the existence of `active centers' which are exchanging
information with a large number of routers thereby inducing correlations
between the corresponding connections. These strong correlations could be a
reason for the observed self-similarity in the WWW traffic.Comment: 7 pages, 6 figures, final versio
Entangling power of quantized chaotic systems
We study the quantum entanglement caused by unitary operators that have
classical limits that can range from the near integrable to the completely
chaotic. Entanglement in the eigenstates and time-evolving arbitrary states is
studied through the von Neumann entropy of the reduced density matrices. We
demonstrate that classical chaos can lead to substantially enhanced
entanglement. Conversely, entanglement provides a novel and useful
characterization of quantum states in higher dimensional chaotic or complex
systems. Information about eigenfunction localization is stored in a graded
manner in the Schmidt vectors, and the principal Schmidt vectors can be scarred
by the projections of classical periodic orbits onto subspaces. The eigenvalues
of the reduced density matrices are sensitive to the degree of wavefunction
localization, and are roughly exponentially arranged. We also point out the
analogy with decoherence, as reduced density matrices corresponding to
subsystems of fully chaotic systems are diagonally dominant.Comment: 21 pages including 9 figs. (revtex
Statistical properties of power-law random banded unitary matrices in the delocalization-localization transition regime
Power-law random banded unitary matrices (PRBUM), whose matrix elements decay
in a power-law fashion, were recently proposed to model the critical statistics
of the Floquet eigenstates of periodically driven quantum systems. In this
work, we numerically study in detail the statistical properties of PRBUM
ensembles in the delocalization-localization transition regime. In particular,
implications of the delocalization-localization transition for the fractal
dimension of the eigenvectors, for the distribution function of the eigenvector
components, and for the nearest neighbor spacing statistics of the eigenphases
are examined. On the one hand, our results further indicate that a PRBUM
ensemble can serve as a unitary analog of the power-law random Hermitian matrix
model for Anderson transition. On the other hand, some statistical features
unseen before are found from PRBUM. For example, the dependence of the fractal
dimension of the eigenvectors of PRBUM upon one ensemble parameter displays
features that are quite different from that for the power-law random Hermitian
matrix model. Furthermore, in the time-reversal symmetric case the nearest
neighbor spacing distribution of PRBUM eigenphases is found to obey a
semi-Poisson distribution for a broad range, but display an anomalous level
repulsion in the absence of time-reversal symmetry.Comment: 10 pages + 13 fig
OxPhos defects cause hypermetabolism and reduce lifespan in cells and in patients with mitochondrial diseases
Patients with primary mitochondrial oxidative phosphorylation (OxPhos) defects present with fatigue and multi-system disorders, are often lean, and die prematurely, but the mechanistic basis for this clinical picture remains unclear. By integrating data from 17 cohorts of patients with mitochondrial diseases (n = 690) we find evidence that these disorders increase resting energy expenditure, a state termed hypermetabolism. We examine this phenomenon longitudinally in patient-derived fibroblasts from multiple donors. Genetically or pharmacologically disrupting OxPhos approximately doubles cellular energy expenditure. This cell-autonomous state of hypermetabolism occurs despite near-normal OxPhos coupling efficiency, excluding uncoupling as a general mechanism. Instead, hypermetabolism is associated with mitochondrial DNA instability, activation of the integrated stress response (ISR), and increased extracellular secretion of age-related cytokines and metabokines including GDF15. In parallel, OxPhos defects accelerate telomere erosion and epigenetic aging per cell division, consistent with evidence that excess energy expenditure accelerates biological aging. To explore potential mechanisms for these effects, we generate a longitudinal RNASeq and DNA methylation resource dataset, which reveals conserved, energetically demanding, genome-wide recalibrations. Taken together, these findings highlight the need to understand how OxPhos defects influence the energetic cost of living, and the link between hypermetabolism and aging in cells and patients with mitochondrial diseases
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