93 research outputs found
Adiabatic optical entanglement between electron spins in separate quantum dots
We present an adiabatic approach to the design of entangling quantum
operations with two electron spins localized in separate InAs/GaAs quantum dots
via the Coulomb interaction between optically-excited localized states.
Slowly-varying optical pulses minimize the pulse noise and the relaxation of
the excited states. An analytic "dressed state" solution gives a clear physical
picture of the entangling process, and a numerical solution is used to
investigate the error dynamics. For two vertically-stacked quantum dots we show
that, for a broad range of dot parameters, a two-spin state with concurrence
can be obtained by four optical pulses with durations
ns.Comment: 7 pages, 5 figure
Anisotropy and controllable band structure in supra-wavelength polaritonic metasurfaces
In this letter we exploit the extended coherence length of mixed
plasmon/exciton states to generate active metasurfaces. For this purpose,
periodic stripes of organic dye are deposited on a continuous silver film.
Typical metasurface effects, such as effective behavior and geometry
sensitivity, are measured for periods exceeding the polaritonic wavelength by
more than one order of magnitude. By adjusting the metasurface geometry,
anisotropy, modified band structure and unidimensional polaritons are
computationally simulated and experimentally observed in reflectometry as well
as in emission.Comment: 4 figures, 1 Supplementary Material
Effect of secondary relaxation transitions on photo-induced anisotropy in glassy azobenzene-functionalized polymers
© The Royal Society of Chemistry 2017. We propose a physical mechanism for the photo-induced orientation alignment of azo-dyes incorporated in polymers at temperatures far below the glass transition temperature. Using polarized FT-IR spectroscopy, we show that optical dichroism undergoes an observable change at the β-relaxation transition of the azo-polymer when the mobility of the short backbone fragments is increased. We explain this effect using temperature-dependent local strains that occur within the polymer backbones in a glassy state. These strains underlie the enhanced thermal relaxation that drives the orientation kinetics
Theoretical studies of nonradiative 4f-4f multiphonon transitions in dielectric crystals containing rare earth ions
Detailed calculations have been performed of multiphonon relaxation rates of optical excitations in Nd-doped LiYF4 and Pr-doped CsCdBr3 crystals in the frameworks of the exchange charge model of the crystal fields and rigid ion harmonic models of lattice dynamics. It is shown that the empirical energy gap low emerges from the exponential diminishing of spectral densities of n-phonon correlation functions with the increase of an order n. Calculated transition probabilities for 2-, 3-phonon processes agree with experimental data. However, for energy gaps exceeding the maximum phonon energy more than twice, the existing theory which neglects the lattice anharmonicity brings about underestimated relaxation rates. © 2007 Elsevier B.V. All rights reserved
Temperature and Carbon Assimilation Regulate the Chlorosome Biogenesis in Green Sulfur Bacteria
Green photosynthetic bacteria adjust the structure and functionality of the chlorosome—the light-absorbing antenna complex—in response to environmental stress factors. The chlorosome is a natural self-assembled aggregate of bacteriochlorophyll (BChl) molecules. In this study, we report the regulation of the biogenesis of the Chlorobaculum tepidum chlorosome by carbon assimilation in conjunction with temperature changes. Our studies indicate that the carbon source and thermal stress culture of C. tepidum grows slower and incorporates fewer BChl c in the chlorosome. Compared with the chlorosome from other cultural conditions we investigated, the chlorosome from the carbon source and thermal stress culture displays (a) smaller cross-sectional radius and overall size, (b) simplified BChl c homologs with smaller side chains, (c) blue-shifted absorption maxima, and (d) a sigmoid-shaped circular dichroism spectra. Using a theoretical model, we analyze how the observed spectral modifications can be associated with structural changes of BChl aggregates inside the chlorosome. Our report suggests a mechanism of metabolic regulation for chlorosome biogenesis.Chemistry and Chemical Biolog
Increase of SERS Signal Upon Heating or Exposure to a High-Intensity Laser Field: Benzenethiol on an AgFON Substrate
The surface-enhanced Raman scattering (SERS) signal from an AgFON plasmonic
substrate, recoated with benzenethiol, was observed to increase by about 100%
upon heating for 3.5 min at 100C and 1.5 min at 125C. The signal intensity was
found to increase further by about 80% upon a 10 sec exposure to a
high-intensity (3.2 kW/cm^2) 785-nm cw laser, corresponding to 40 mW in a
40+/-5-um diameter spot. The observed increase in the SERS signal may be
understood by considering the presence of benzenethiol molecules in an
intermediate or 'precursor' state in addition to conventionally ordered
molecules forming a self-assembled monolayer. The increase in the SERS signal
arises from the conversion of the molecules in the precursor state to the
chemisorbed state due to thermal and photo-thermal effects.Comment: 9 pages, 4 figures; J. Phys. Chem. C, accepte
Control of electron spin decoherence caused by electron-nuclear spin dynamics in a quantum dot
Control of electron spin decoherence in contact with a mesoscopic bath of
many interacting nuclear spins in an InAs quantum dot is studied by solving the
coupled quantum dynamics. The nuclear spin bath, because of its bifurcated
evolution predicated on the electron spin up or down state, measures the
which-state information of the electron spin and hence diminishes its
coherence. The many-body dynamics of nuclear spin bath is solved with a
pair-correlation approximation. In the relevant timescale, nuclear pair-wise
flip-flops, as elementary excitations in the mesoscopic bath, can be mapped
into the precession of non-interacting pseudo-spins. Such mapping provides a
geometrical picture for understanding the decoherence and for devising control
schemes. A close examination of nuclear bath dynamics reveals a wealth of
phenomena and new possibilities of controlling the electron spin decoherence.
For example, when the electron spin is flipped by a -pulse at , its
coherence will partially recover at as a consequence of quantum
disentanglement from the mesoscopic bath. In contrast to the re-focusing of
inhomogeneously broadened phases by conventional spin-echoes, the
disentanglement is realized through shepherding quantum evolution of the bath
state via control of the quantum object. A concatenated construction of pulse
sequences can eliminate the decoherence with arbitrary accuracy, with the
nuclear-nuclear spin interaction strength acting as the controlling small
parameter
Relaxation of Electron Spin during High-Field Transport in GaAs Bulk
A semiclassical Monte Carlo approach is adopted to study the multivalley spin
depolarization of drifting electrons in a doped n-type GaAs bulk semiconductor,
in a wide range of lattice temperature ( K) and doping density
(cm). The decay of the initial non-equilibrium spin
polarization of the conduction electrons is investigated as a function of the
amplitude of the driving static electric field, ranging between 0.1 and 6
kV/cm, by considering the spin dynamics of electrons in both the and
the upper valleys of the semiconductor. Doping density considerably affects
spin relaxation at low temperature and weak intensity of the driving electric
field. At high values of the electric field, the strong spin-orbit coupling of
electrons in the -valleys significantly reduces the average spin
polarization lifetime, but, unexpectedly, for field amplitudes greater than 2.5
kV/cm, the spin lifetime increases with the lattice temperature. Our numerical
findings are validated by a good agreement with the available experimental
results and with calculations recently obtained by a different theoretical
approach.Comment: 14 pages, 6 figure
Single Electron Spin Decoherence by Nuclear Spin Bath: Linked Cluster Expansion Approach
We develop a theoretical model for transverse dynamics of a single electron
spin interacting with a nuclear spin bath. The approach allows a simple
diagrammatic representation and analytical expressions of different nuclear
spin excitation processes contributing to electron spin decoherence and
dynamical phase fluctuations. It accounts for nuclear spin dynamics beyond
conventional pair correlation models. As an illustration of the theory, we
evaluated the coherence dynamics of a P donor electron spin in a Si crystal.Comment: 37 pages, 13 figure
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