13,588 research outputs found
Rod-like Polyelectrolytes in Presence of Monovalent Salt
We investigate the properties of rigid polyelectrolyte solutions in presence
of monovalent salt. The free energy within the Debye-H\"uckel-Bjerrum (DHBj)
theory [M. E.
Fisher and Y. Levin, {\it Phys. Rev. Lett.} 71, 3826 (1993)] is constructed.
It is found that at thermodynamic equilibrium the polyelectrolyte solution
consists of clusters composed of one polyion and various counterions. The
distribution of the cluster densities is determined by finding the minimum of
the Helmholtz free energy. The osmotic pressure and the average charge of the
cluster are found and their dependence on Manning parameter is
elucidated. A good agreement with the experimental results is obtained.Comment: 11 pages, Revtex (using twocolumn style), 15 figures and postscript
file. Submitted to Macromomelecule
Modeling the input history of programs for improved instruction-memory performance
When a program is loaded into memory for execution, the relative position of
its basic blocks is crucial, since loading basic blocks that are unlikely to be
executed first places them high in the instruction-memory hierarchy only to be
dislodged as the execution goes on. In this paper we study the use of Bayesian
networks as models of the input history of a program. The main point is the
creation of a probabilistic model that persists as the program is run on
different inputs and at each new input refines its own parameters in order to
reflect the program's input history more accurately. As the model is thus
tuned, it causes basic blocks to be reordered so that, upon arrival of the next
input for execution, loading the basic blocks into memory automatically takes
into account the input history of the program. We report on extensive
experiments, whose results demonstrate the efficacy of the overall approach in
progressively lowering the execution times of a program on identical inputs
placed randomly in a sequence of varied inputs. We provide results on selected
SPEC CINT2000 programs and also evaluate our approach as compared to the gcc
level-3 optimization and to Pettis-Hansen reordering
Crystallization, data collection and data processing of maltose-binding protein (MalE) from the phytopathogen Xanthomonas axonopodis pv. citri
Maltose-binding protein is the periplasmic component of the ABC transporter
responsible for the uptake of maltose/maltodextrins. The Xanthomonas axonopodis
pv. citri maltose-binding protein MalE has been crystallized at 293 Kusing
the hanging-drop vapour-diffusion method. The crystal belonged to the
primitive hexagonal space group P6_122, with unit-cell parameters a = 123.59,
b = 123.59, c = 304.20 Ã…, and contained two molecules in the asymetric unit. It
diffracted to 2.24 Ã… resolution
Liquid Polymorphism and Density Anomaly in a Lattice Gas Model
We present a simple model for an associating liquid in which polymorphism and
density anomaly are connected. Our model combines a two dimensional lattice gas
with particles interacting through a soft core potential and orientational
degrees of freedom represented through thermal \char`\"{}ice
variables\char`\"{} . The competition between the directional attractive forces
and the soft core potential leads to a phase diagram in which two liquid phases
and a density anomaly are present. The coexistence line between the low density
liquid and the high density liquid has a positive slope contradicting the
surmise that the presence of a density anomaly implies that the high density
liquid is more entropic than the low density liquid
Amphiphile Adsorption on Rigid Polyelectrolytes
A theory is presented which quantitatively accounts for the cooperative
adsorption of cationic surfactants to anionic polyelectrolytes. For high salt
concentration we find that the critical adsorption concentration (CAC) is a
bilinear function of the polyion monomer and salt concentrations, with the
coefficients dependent only on the type of surfactant used. The results
presented in the paper might be useful for designing more efficient gene
delivery systems
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