Effect of the surface-stimulated mode on the kinetics of homogeneous crystal nucleation in droplets

A kinetic theory of homogeneous crystal nucleation in unary droplets is presented taking into account that a crystal nucleus can form not only in the volume-based mode (with all its facets within the droplet) but also in the surface-stimulated one (with one of its facets at the droplet surface). The previously developed thermodynamics of surface-stimulated crystal nucleation rigorously showed that if at least one of the facets of the crystal is only partially wettable by its melt, then it is thermodynamically more favorable for the nucleus to form with that facet at the droplet surface rather than within the droplet. So far, however, the kinetic aspects of this phenomenon had not been studied at all. The theory proposed in the present paper advocates that even in the surface-stimulated mode crystal nuclei initially emerge (as sub-critical clusters) homogeneously in the sub-surface layer, not "pseudo-heterogeneously" at the surface. A homogeneously emerged sub-critical crystal can become a surface-stimulated nucleus due to density and structure fluctuations. This effect contributes to the total rate of crystal nucleation (as the volume-based mode does). An explicit expression for the total per-particle rate of crystal nucleation is derived. Numerical evaluations for water droplets suggest that the surface-stimulated mode can significantly enhance the per-particle rate of crystal nucleation in droplets as large as 10 microns in radius. Possible experimental verification of the proposed theory is discussed.Comment: 33 pages, 3 figure

Broadband light coupling to dielectric slot waveguides with tapered plasmonic nanoantennas

We propose and theoretically verify an efficient mechanism of broadband coupling between incident light and on-chip dielectric slot waveguide by employing a tapered plasmonic nanoantenna. Nanoantenna receives free space radiation and couples it to a dielectric slot waveguide with the efficiency of up to 20% in a broad spectral range, having a small footprint as compared with the currently used narrowband dielectric grating couplers. We argue that the frequency selective properties of such nanoantennas also allow for using them as ultrasmall on-chip multiplexer/demultiplexer devices

Second-harmonic generation in subwavelength graphene waveguides

We suggest a novel approach for generating second-harmonic radiation in subwavelength graphene waveguides. We demonstrate that quadratic phase matching between the plasmonic guided modes of different symmetries can be achieved in a planar double-layer geometry when conductivity of one of the layers becomes spatially modulated. We predict theoretically that, owing to graphene nonlocal conductivity, the second-order nonlinear processes can be actualized for interacting plasmonic modes with an effective grating coupler to allow external pumping of the structure and output of the radiation at the double frequency.Comment: 5 pages, 3 figure

Necklace-ring vector solitons

We introduce novel classes of optical vector solitons that consist of incoherently coupled self-trapped “necklace” beams carrying zero, integer, and even fractional angular momentum. Because of the stabilizing mutual attraction between the components, such stationary localized structures exhibit quasistable propagation for much larger distances than the corresponding scalar vortex solitons and expanding scalar necklace beams