105 research outputs found
Magnetodielectric effect of Graphene-PVA Nanocomposites
Graphene-Polyvinyl alcohol (PVA) nanocomposite films with thickness were synthesized by solidification of PVA in a solution with dispersed
graphene nanosheets. Electrical conductivity data were explained as arising due
to hopping of carriers between localized states formed at the graphene-PVA
interface. Dielectric permittivity data as a function of frequency indicated
the occurrence of Debye-type relaxation mechanism. The nanocomposites showed a
magnetodielectric effect with the dielectric constant changing by 1.8% as the
magnetic field was increased to 1 Tesla. The effect was explained as arising
due to Maxwell-Wagner polarization as applied to an inhomogeneous
two-dimensional,two-component composite model. This type of nanocomposite may
be suitable for applications involving nanogenerators.Comment: 13 pages, 11 figure
Simple approach for high-contrast optical imaging and characterization of graphene-based sheets
A simple optical method is presented for identifying and measuring the effective optical properties of nanometer-thick, graphene-based materials, based on the use of substrates consisting of a thin dielectric layer on silicon. High contrast between the graphene-based materials and the substrate is obtained by choosing appropriate optical properties and thickness of the dielectric layer. The effective refractive index and optical absorption coefficient of graphene oxide, thermally reduced graphene oxide, and graphene are obtained by comparing the predicted and measured contrasts
Graphene-Based Ultracapacitors
The surface area of a single graphene sheet is 2630 m(2)/g, substantially higher than values derived from BET surface area measurements of activated carbons used in current electrochemical double layer capacitors. Our group has pioneered a new carbon material that we call chemically modified graphene (CMG). CMG materials are made from 1-atom thick sheets of carbon, functionalized as needed, and here we demonstrate in an ultracapacitor cell their performance, Specific capacitances of 135 and 99 F/g in aqueous and organic electrolytes, respectively, have been measured. In addition, high electrical conductivity gives these materials consistently good performance over a wide range of voltage scan rates. These encouraging results illustrate the exciting potential for high performance, electrical energy storage devices based on this new class of carbon material
Calling all chemists
Graphene has potentially useful electronic properties but it is difficult to produce and process on large scales. Working with chemically modified forms of graphene-such as graphene oxide-may provide an alternative
Graphene-silica composite thin films as transparent conductors
Transparent and electrically conductive composite silica films were fabricated on glass and hydrophilic SiOx/silicon substrates by incorporation of individual graphene oxide sheets into silica sols followed by spin-coating, chemical reduction, and thermal curing. The resulting films were characterized by SEM, AFM, TEM, low-angle X-ray reflectivity, XPS, UV-vis spectroscopy, and electrical conductivity measurements. The electrical conductivity of the films compared favorably to those of composite thin films of carbon nanotubes in silica
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