Soil-Saprolite Profiles Derived from Mafic Rocks in the North Carolina Piedmont: II. Association of Free Iron Oxides with Soils and Clays

The association of free Fe oxides with soils and clays from two Enon sandy loam (Ultic Hapludalfs, fine, mixed, thermic) soilsaprolite profiles was studied. Goethite was the dominant Fe oxide identified. Lepidocrocite was detected in trace amounts in some samples. FeCBD/clay ratios were highest in the epipedons of these soils suggesting the concentrating of Fe oxides as a result of aluminosilicate mineral weathering. External (BET-N2) surface area measurements of non-deferrated and deferrated clays were analyzed in conjunction with electron micrographs of selected clay fractions to determine the association of free Fe oxides with aluminosilicate clays as a function of depth in the profile. Free Fe oxides were found to exist mainly as small, discrete clusters in the A and B horizons of both profiles and specific of the clay surface decreased as a result of treatment for Fe removal. However, external surface areas increased for the saprolite (Cr) horizon clays after deferration. One subfraction identified as having an increase in surface area after deferration was fine clay from the Cr2 horizon, Enon (metagabbro) profile. Chemical data and electron micrographs suggest that either partial dissolution of small, poorly crystalline aluminosilicate clays or removal of some Fe or non-Fe oxide aggregating agent results in breakdown of the fine clays into smaller particles of higher net specific surface

Soil-Saprolite Profiles Derived from Mafic Rocks in the North Carolina Piedmont: I. Chemical, Morphological, and Mineralogical Characteristics and Transformations

The chemical, morphological and mineralogical properties of two Enon sandy loam (fine, mixed, thermic Ultic Hapludalfs) soilsaprolite profiles, one formed on gabbro and the other on metagabbro, are compared. Clay skins are scarce and stress cutans common in the argillic horizons of these soils. Iron-manganese concretions are concentrated in soil horizons immediately above the argillic horizons. The high shrink-swell capacities and slow permeabilities of the argillic horizons result in relatively shallow depths to paralithic contact with saprolite. The parent rock from the Enon profile near Albemarle, Stanly County, North Carolina is a medium-grained metagabbro with chlorite, hornblende, quartz, and calcic plagioclase feldspar as the dominant primary minerals. Chlorite weathers to regularly interstratified chlorite-vermiculite, which alters to randomly interstratified chlorite-vermiculite and smectite. Particle size decreases with each mineral alteration. Hornblende weathers to smectite and goethite. Calcic plagioclase feldspar transforms to kaolinite in the saprolite and soil horizons. Quartz is relatively resistant to chemical weathering. The parent rock of the Enon profile near Concord, Cabarrus County, North Carolina is a coarse-grained gabbro with hornblende and calcic plagioclase feldspar as the dominant primary minerals. Hornblende transforms to smectite and goethite. Calcic plagioclase feldspar alters to kaolinite in the saprolite and soil horizon

Lithosols in Arizona

This item is part of the Arizona Land and People (formerly Progressive Agriculture in Arizona) archive. It was digitized from a physical copy provided by the College of Agriculture and Life Sciences at The University of Arizona. For more information about this periodical, please email CALS Publications at [email protected]

Irrigated Alluvial Soils in Arizona

This item is part of the Arizona Land and People (formerly Progressive Agriculture in Arizona) archive. It was digitized from a physical copy provided by the College of Agriculture and Life Sciences at The University of Arizona. For more information about this periodical, please email CALS Publications at [email protected]