Electrocatalytic overall water splitting based on (ZnNiCoFeY)xOy high-entropy oxide supported on MoS2

Hydrogen energy is a sustainable and clean source that can meet global energy demands without adverse environmental impacts. High-entropy oxides (HEOs), multielement (5 or more) oxides with an equiatomic or near-equatomic elemental composition, offer a novel approach to designing bifunctional electrocatalysts. This work explores (ZnNiCoFeY)xOy over MoS2 as a bifunctional electrocatalyst (HEO–MoS2) in an alkaline medium. The HEO was synthesized using a combustion process and loaded over MoS2 using an ultrasonic method. The synthesized HEO over MoS2 exhibits excellent performance, including long-term stability for over 24 h, an overpotential of 214 mV vs the reversible hydrogen electrode (RHE) for the hydrogen evolution reaction (HER), and 308 mV for the oxygen evolution reaction (OER) at 10 mA cm−2. This bifunctional electrocatalyst exhibits low overpotential for both the HER and the OER at high current densities. Additionally, HEO–MoS2 demonstrates smaller solution and charge transfer resistance values. The electrolyzer was assembled using bifunctional HEO–MoS2 electrodes for overall water splitting. These electrodes exhibited a low cell voltage of 1.65 V at 10 mA cm−2. The novel electrocatalyst was fabricated using a facile and scalable method that appeals to industrial applications

Intranet Mediators: A Prototype

We describe a mediator designed specifically for an intranet rather than an internet. Our intranet mediator allows data reconciliation and integration to be completed long before the query is executed. This is because information about the data sources is known and a combined schema can be defined prior to the query. On the internet, source schemas are not available so integration cannot occur before the query. In our approach, a data warehouse is used for reconciliation of structured data. We propose a new architecture and describe an initial prototype built to test the architecture. 1

Intranet Mediators (Spring 2001) EnPRO 307

Current web search engines only search unstructured data (web documents). A lot of data is available that is structured (weather, census, sports, etc.). A search engine that could search both structured data and text would be able to answer questions such as "show me the top three restaurants in Chicago" without simply looking for the word "three." The team has been building a Java-based metasearch engine in IPRO 334 duringFall 2000. Numerous issues have arisen. How do we identify which data source will be best for the query? What is the best user interface for the system? For Spring 2001, the team will extend the search engine to include more sources. The team could really use the talents of non-computer science students to help test the system and improve the user interface. Students should plan to work on this at least ten hours a week - anything less will resultin a poor grade for the IPRO. Students for this IPRO are graded heavily based on the success of the team, not just individual performance. Weekly progress reports are required. Note that graduate students in Computer Science are not able to use IPRO classes for credit toward a graduate degree.Sponsorship: IIT Internal R&DProject Plan for EnPRO 307: Intranet Mediators for the Spring 2001 semeste

Experimental and first-principles insights into an enhanced performance of Ru-doped copper phosphate electrocatalyst during oxygen evolution reaction

The oxygen evolution reaction (OER) is a vital half-reaction in many applications, such as the electrochemical H2O splitting, CO2, and N2 conversion processes. The OER involves a four-electron transfer and is a kinetically sluggish reaction that requires additional potential to drive. To enhance the electrochemical performance of the above-mentioned applications, highly efficient, corrosion-resistant, earth-abundant, and eco-friendly electrocatalysts are required. Here, we report a highly porous, minimally Ru-doped copper phosphate electrocatalyst obtained through co-precipitation. The optimized electrocatalyst (5% Ru-doped copper phosphate) exhibits a low overpotential of 340 mV to achieve 10 mA cm−2 compared to copper-based materials, and it remains stable over 20 h. The high performance is attributed to a high electrochemically effective surface area (ECSA) of 30.25 cm2, facilitating effective ion transportation at the electrode/electrolyte interface and excellent electrical conductivity. This result is supported by density functional theory calculations, which demonstrate that ruthenium enhances the electrochemical properties by increasing electronic conductivity, reducing the theoretical overpotential, and influencing the rate-determining step of the oxygen evolution reaction. Herein, the electrocatalyst is attractive for commercialization due to its utilization of minimal ruthenium in earth-abundant electrocatalysts, which offer competitive performance

Dibromopinocembrin and Dibromopinostrobin Are Potential Anti-Dengue Leads with Mild Animal Toxicity

10.3390/molecules25184154Molecules2518415

Electrocatalytic overall water splitting based on (ZnNiCoFeY)xOy high-entropy oxide supported on MoS2

Hydrogen energy is a sustainable and clean source that can meet global energy demands without adverse environmental impacts. High-entropy oxides (HEOs), multielement (5 or more) oxides with an equiatomic or near-equatomic elemental composition, offer a novel approach to designing bifunctional electrocatalysts. This work explores (ZnNiCoFeY)xOy over MoS2 as a bifunctional electrocatalyst (HEO–MoS2) in an alkaline medium. The HEO was synthesized using a combustion process and loaded over MoS2 using an ultrasonic method. The synthesized HEO over MoS2 exhibits excellent performance, including long-term stability for over 24 h, an overpotential of 214 mV vs the reversible hydrogen electrode (RHE) for the hydrogen evolution reaction (HER), and 308 mV for the oxygen evolution reaction (OER) at 10 mA cm−2. This bifunctional electrocatalyst exhibits low overpotential for both the HER and the OER at high current densities. Additionally, HEO–MoS2 demonstrates smaller solution and charge transfer resistance values. The electrolyzer was assembled using bifunctional HEO–MoS2 electrodes for overall water splitting. These electrodes exhibited a low cell voltage of 1.65 V at 10 mA cm−2. The novel electrocatalyst was fabricated using a facile and scalable method that appeals to industrial applications