Phase transition in a super superspin glass

We here confirm the occurrence of spin glass phase transition and extract estimates of associated critical exponents of a highly monodisperse and densely compacted system of bare maghemite nanoparticles. This system has earlier been found to behave like an archetypal spin glass, with e.g. a sharp transition from paramagnetic to non-equilibrium behavior, suggesting that this system undergoes a spin-glass phase transition at a relatively high temperature, $T_g$ $\sim$ 140 K.Comment: 4 pages, 3 figure

Maximizing Polypropylene Recovery from Waste Carpet Feedstock: A Solvent-Driven Pathway Towards Circular Economy

Here we propose a novel approach for the efficient recovery of polypropylene from waste carpet feedstock utilising a solvent based method operating at 160 °C. The findings contribute to advancing sustainable recycling practices for waste carpet materials and offer valuable insight into the recovery of PP which can also be utilised for other complex waste streams

Fluid flow hydrodynamic modeling in the passage of an oil artificial lift pumping unit

The study of the two-phase flow through the standing and traveling valves used in an oil artificial-lift pumping unit is presented. The investigation aimed to determine the effects the gaseous phase may cause on the pump volumetric efficiency. Data obtained on a specially designed test facility is presented and analyzed as a first step before developing a semi-empirical model to predict the performance of the pump under two-phase flow conditions. Preliminary results, based on one-phase and two-phase runs, demonstrate important features introduced on the pump performance once the gas-phase is included in the proces

The Comparability of Men Who Have Sex With Men Recruited From Venue-Time-Space Sampling and Facebook: A Cohort Study

Background: Recruiting valid samples of men who have sex with men (MSM) is a key component of the US human immunodeficiency virus (HIV) surveillance and of research studies seeking to improve HIV prevention for MSM. Social media, such as Facebook, may present an opportunity to reach broad samples of MSM, but the extent to which those samples are comparable with men recruited from venue-based, time-space sampling (VBTS) is unknown. Objective: The objective of this study was to assess the comparability of MSM recruited via VBTS and Facebook. Methods: HIV-negative and HIV-positive black and white MSM were recruited from June 2010 to December 2012 using VBTS and Facebook in Atlanta, GA. We compared the self-reported venue attendance, demographic characteristics, sexual and risk behaviors, history of HIV-testing, and HIV and sexually transmitted infection (STI) prevalence between Facebook- and VTBS-recruited MSM overall and by race. Multivariate logistic and negative binomial models estimated age/race adjusted ratios. The Kaplan-Meier method was used to assess 24-month retention. Results: We recruited 803 MSM, of whom 110 (34/110, 30.9% black MSM, 76/110, 69.1% white MSM) were recruited via Facebook and 693 (420/693, 60.6% black MSM, 273/693, 39.4% white MSM) were recruited through VTBS. Facebook recruits had high rates of venue attendance in the previous month (26/34, 77% among black and 71/76, 93% among white MSM; between-race P=.01). MSM recruited on Facebook were generally older, with significant age differences among black MSM (P=.02), but not white MSM (P=.14). … See full text for complete abstract

In-Situ Growth of Metal Oxide Nanoparticles on Cellulose Nanofibrils for Dye Removal and Antimicrobial Applications

Nanocellulose is known to act as a platform for the in-situ formation of metal oxide nanoparticles, where the multiple components of the resultant hybrids act synergistically toward specific applications. However, typical mineralization reactions require hydrothermal conditions or addition of further reducing agents. Herein, we demonstrate that carboxylated cellulose nanofibril-based films can spontaneously grow functional metal oxide nanoparticles during the adsorption of heavy metal ions from water, without the need of any further chemicals or temperature. Despite the apparent universality of this behavior with different metal ions, this work focuses on studying the in-situ formation of copper oxide nanoparticles on TOCNF films as well as the resultant hybrid films with improved functionality toward dye removal from water and antimicrobial activity. Using a combination of cutting-edge techniques (e.g., in-situ SAXS and QCMD) to systematically follow the nanoparticle formation on the nanocellulosic films in real time, we suggest a plausible mechanism of assembly. Our results confirm that carboxylated cellulose nanofibril films act as universal substrate for the formation of metal oxide nanoparticles, and thus hybrid nanomaterials, during metal ion adsorption processes. This phenomenon enables the upcycling of nanocellulosic materials through multistage applications, thus increasing its sustainability and efficiency in terms of an optimal use of resources