19 research outputs found
Mechanistic Origin of Chemo- and Regioselectivity of Nickel-Catalyzed [3 + 2 + 2] Cyclization Reaction
Full text linkNickel-Catalyzed [3 + 2 + 2] Cycloaddition of Ethyl Cyclopropylideneacetate and Heteroatom-Substituted Alkynes: Application to Selective Three-Component Reaction with 1,3-Diynes
Full text linkNickel-Catalyzed Formation of Cyclopentenone Derivatives via the Unique Cycloaddition of α,β-Unsaturated Phenyl Esters with Alkynes
Full text linkRhodium-Catalyzed Highly Enantio- and Diastereoselective Cotrimerization of Alkenes and Dialkyl Acetylenedicarboxylates Leading to Furylcyclopropanes
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Intermolecular Rhodium-Catalyzed [3+2+2] Carbocyclization of Alkenylidenecyclopropanes with Activated Alkynes: Regio- and Diastereoselective Construction of cis
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Synthesis of Vinylcycloheptadienes by the Nickel-Catalyzed Three-Component [3 + 2 + 2] Cocyclization. Application to the Synthesis of Polycyclic Compounds
Full text linkRegio- and Stereoselective Synthesis of a Library of Bioactive Dispiro-Oxindolo/Acenaphthoquino Andrographolides via 1,3- Dipolar Cycloaddition Reaction Under Microwave Irradiation
Full text linkDispiro-pyrrolidino/pyrrolizidino fused oxindoles/acenaphthoquinones have
been derived from andrographolide via azomethine ylide cycloaddition to the conjugated
double-bond under microwave (MW) irradiation. The reactions are chemo-, stereo-, and
regioselective in nature. Change in amino acid from sarcosine/N-benzyl glycine to L-proline
changes the regiochemistry. A representative library of 40 compounds along with in vitro
anticancer evaluation is reported
Nickel-Catalyzed Intermolecular [3 + 2 + 2] Cocyclization of Ethyl Cyclopropylideneacetate and Alkynes. Synthesis of Seven-Membered Carbocycles
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