High resolution measurements of partial photoionization cross sections in hollow lithium: a critical comparison with advanced many-body calculations

Photoelectron data for hollow lithium states obtained with unprecedented high spectral resolution and sensitivity are presented. A critical comparison is made with the most recent theoretical results. Partial cross sections are measured providing the first definitive test of advanced ab initio calculations for this highly excited four-body atomic system

Pure and Sb-doped SnO

We describe photoemission results from pure and Sb-doped SnO2 nanoparticles deposited on gold substrates. Photoelectron spectra with synchrotron radiation were recorded for Sn 3d, Sb 3d and O 1s core levels and valence bands in the 500-1200 eV energy range. For pure SnO2 nanoparticles the surface is terminated by an oxygen rich layer with no obvious surface environment for Sn. When doped n-type with 9.1% or 16.7% Sb, dopant atoms are concentrated near the surface of the nanoparticles. The valence state of the dopant atoms is predominantly SbV. Plasmon satellite features are also observed in core level photoemission spectra and their intensity relative to the main peak increases with increasing photon energy