931 research outputs found
Frustration and sound attenuation in structural glasses
Three classes of harmonic disorder systems (Lennard-Jones like glasses,
percolators above threshold, and spring disordered lattices) have been
numerically investigated in order to clarify the effect of different types of
disorder on the mechanism of high frequency sound attenuation. We introduce the
concept of frustration in structural glasses as a measure of the internal
stress, and find a strong correlation between the degree of frustration and the
exponent alpha that characterizes the momentum dependence of the sound
attenuation . In particular, alpha decreases from
about d+1 in low-frustration systems (where d is the spectral dimension), to
about 2 for high frustration systems like the realistic glasses examined.Comment: Revtex, 4 pages including 4 figure
Competing interactions in arrested states of colloidal clays
Using experiments, theory and simulations, we show that the arrested state
observed in a colloidal clay at intermediate concentrations is stabilized by
the screened Coulomb repulsion (Wigner glass). Dilution experiments allow us to
distinguish this high-concentration disconnected state, which melts upon
addition of water, from a low-concentration gel state, which does not melt.
Theoretical modelling and simulations reproduce the measured Small Angle X-Ray
Scattering static structure factors and confirm the long-range electrostatic
nature of the arrested structure. These findings are attributed to the
different timescales controlling the competing attractive and repulsive
interactions.Comment: Accepted for publication in Physical Review Letter
Arrested state of clay-water suspensions: gel or glass?
The aging of a charged colloidal system has been studied by Small Angle
X-rays Scattering, in the exchanged momentum range Q=0.03 - 5 nm-1, and by
Dynamic Light Scattering, at different clay concentrations (Cw =0.6 % - 2.8 %).
The static structure factor, S(Q), has been determined as a function of both
aging time and concentration. This is the first direct experimental evidence of
the existence and evolution with aging time of two different arrested states in
a single system simply obtained only by changing its volume fraction: an
inhomogeneous state is reached at low concentrations, while a homogenous one is
found at high concentrations.Comment: 5 pages, 2 figure
Non-dynamic origin of the acoustic attenuation at high frequency in glasses
The sound attenuation in the THz region is studied down to T=16 K in glassy
glycerol by inelastic x-ray scattering. At striking variance with the decrease
found below 100 K in the GHz data, the attenuation in the THz range does not
show any T dependence. This result i) indicates the presence of two different
attenuation mechanisms, active respectively in the high and low frequency
limits; ii) demonstrates the non-dynamic origin of the attenuation of THz sound
waves, and confirms a similar conclusion obtained in SiO2 glass by molecular
dynamics; and iii) supports the low frequency attenuation mechanism proposed by
Fabian and Allen (Phys.Rev.Lett. 82, 1478 (1999)).Comment: 3 pages, 5 Figures, To be published in PR
Aging of the Nonlinear Optical Susceptibility of colloidal solutions
Using Z-scan and dynamic light scattering measurements we investigate the
nonlinear optics response of a colloidal solution undergoing dynamics slowing
down with age. We study the high optical nonlinearity of an organic dye
(Rhodamine B) dispersed in a water-clay (Laponite) solution, at different clay
concentrations (2.0 wt% - 2.6 wt%), experiencing the gelation process. We
determine the clay platelets self diffusion coefficient and, by its comparison
with the structural relaxation time, we conclude that the gelation process
proceeds through the structuring of interconnecting clay platelets network
rather than through clusters growth and aggregation.Comment: 4 figures, 4 page
Observation of Umklapp processes in non-crystalline materials
Umklapp processes are known to exist in cristalline materials, where they
control important properties such as thermal conductivity, heat capacity and
electrical conductivity. In this work we report the provocative observation of
Umklapp processes in a non-periodical system, namely liquid Lithium. The lack
of a well defined periodicity seems then not to prevent the existence of these
scattering processes mechanisms provided that the local order of the systems
i.e. the maxima of the static structure factor supply the equivalent of a
reciprocal lattice vector in the case of cristalline materials.Comment: 13 pages P
A spectroscopic cell for fast pressure jumps across the glass transition line
We present a new experimental protocol for the spectroscopic study of the
dynamics of glasses in the aging regime induced by sudden pressure jumps
(crunches) across the glass transition line. The sample, initially in the
liquid state, is suddenly brought in the glassy state, and therefore out of
equilibrium, in a four-window optical crunch cell which is able to perform
pressure jumps of 3 kbar in a time interval of ~10 ms. The main advantages of
this setup with respect to previous pressure-jump systems is that the pressure
jump is induced through a pressure transmitting fluid mechanically coupled to
the sample stage through a deformable membrane, thus avoiding any flow of the
sample itself in the pressure network and allowing to deal with highly viscous
materials. The dynamics of the sample during the aging regime is investigated
by Brillouin Light Scattering (BLS). For this purpose the crunch cell is used
in conjunction with a high resolution double monochromator equipped with a CCD
detector. This system is able to record a full spectrum of a typical glass
forming material in a single 1 s shot. As an example we present the study of
the evolution toward equilibrium of the infinite frequency longitudinal elastic
modulus (M_infinity) of a low molecular weight polymer (Poly(bisphenol
A-co-epichlorohydrin), glycidyl end capped). The observed time evolution of
M_infinity, well represented by a single stretched exponential, is interpreted
within the framework of the Tool-Narayanaswamy theory.Comment: 9 pages, 11 figure
Elastic constant dishomogeneity and dependence of the broadening of the dynamical structure factor in disordered systems
We propose an explanation for the quadratic dependence on the momentum ,
of the broadening of the acoustic excitation peak recently found in the study
of the dynamic structure factor of many real and simulated glasses. We ascribe
the observed law to the spatial fluctuations of the local wavelength of
the collective vibrational modes, in turn produced by the dishomegeneity of the
inter-particle elastic constants. This explanation is analitically shown to
hold for 1-dimensional disordered chains and satisfatorily numerically tested
in both 1 and 3 dimensions.Comment: 4 pages, RevTeX, 5 postscript figure
Relaxation processes in harmonic glasses?
A relaxation process, with the associated phenomenology of sound attenuation
and sound velocity dispersion, is found in a simulated harmonic Lennard-Jones
glass. We propose to identify this process with the so called microscopic (or
instantaneous) relaxation process observed in real glasses and supercooled
liquids. A model based on the memory function approach accounts for the
observation, and allows to relate to each others: 1) the characteristic time
and strength of this process, 2) the low frequency limit of the dynamic
structure factor of the glass, and 3) the high frequency sound attenuation
coefficient, with its observed quadratic dependence on the momentum transfer.Comment: 11 pages, 3 figure
Struttura familiare e comportamenti devianti dei giovani in Italia: uno studio effettuato attraverso il metodo del self-report
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