40,389 research outputs found
Production and spectroscopy of hadrons containing a b quark at ATLAS
We present studies of the production and spectroscopy of some members of the
B-hadron family. We reconstruct B ground states in their hadronic decay modes
with a J/{\psi} or {\Upsilon} in the final state. These studies are based on
the 2011 7 TeV dataset collected by the ATLAS detector.Comment: Presentation at the DPF 2013 Meeting of the American Physical Society
Division of Particles and Fields, Santa Cruz, California, August 13-17, 2013.
11 pages, 12 figure
Theory of Side-Chain Liquid Crystal Polymers: Bulk Behavior and Chain Conformation
We study the thermodynamics and chain conformation of side-chain liquid crystal polymers (SCLCPs) in the bulk using the self-consistent-field approach and a new model to account for the coupling between the orientation of the side-chain liquid-crystal (LC) groups and that of the backbone segments. The new model accounts for both a global coupling between the polymer backbone and the nematic field and a local coupling between the polymer backbone and its attached LC group. Here, the terms global and local refer to the chemical (backbone) distance between the groups. A phenomenological parameter is introduced to represent the coupling strength and nature of the attachment, i.e., end-on vs side-on. The nematic field is shown to control the chain conformation through both the global and the local coupling effects. For the side-on SCLCPs, these two coupling effects act cooperatively so that the chain conformation is always prolate. For the end-on SCLCPs, these two effects act competitively. The chain conformation can be either oblate or prolate in this case, and depends on the relative strengths of these two couplings. On the other hand, the chain conformation also affects the nematic field, primarily through the global coupling. The prolate conformation enhances the nematic field and increases the phase transition temperature, whereas the oblate conformation frustrates the nematic field and decreases the transition temperature. The nematic order parameter is found to be determined mainly by the reduced temperature, and is not sensitive to the coupling effects. Furthermore, we show that the grafting density of the LC side groups has a significant effect on the chain conformation due to the orientational competition between the LC attached and unattached segments. For the end-on SCLCPs with lower graft density, the conformation of the chain backbone can be oblate at higher temperatures and prolate at lower temperatures, in agreement with the re-entrant nematic phase observed in experiments
Effects of ion solvation on phase equilibrium and interfacial tension of liquid mixtures
We study the bulk thermodynamics and interfacial properties of electrolyte solution mixtures by accounting for electrostatic interaction, ion solvation, and inhomogeneity in the dielectric medium in the mean-field framework. Difference in the solvation energy between the cations and anions is shown to give rise to local charge separation near the interface, and a finite Galvani potential between two coexisting solutions. The ion solvation affects the phase equilibrium of the solvent mixture, depending on the dielectric constants of the solvents, reflecting the competition between the solvation energy and translation entropy of the ions. Miscibility is decreased if both solvents have low dielectric constants and is enhanced if both solvents have high dielectric constant. At the mean-field level, the ion distribution near the interface is determined by two competing effects: accumulation in the electrostatic double layer and depletion in a diffuse interface. The interfacial tension shows a nonmonotonic dependence on the salt concentration: it increases linearly with the salt concentration at higher concentrations and decreases approximately as the square root of the salt concentration for dilute solutions, reaching a minimum near 1 mM. We also find that, for a fixed cation type, the interfacial tension decreases as the size of anion increases. These results offer qualitative explanations within one unified framework for the long-known concentration and ion size effects on the interfacial tension of electrolyte solutions
On the theoretical description of weakly charged surfaces
It is widely accepted that the Poisson-Boltzmann (PB) theory provides a valid
description for charged surfaces in the so-called weak coupling limit. Here, we
show that the image charge repulsion creates a depletion boundary layer that
cannot be captured by a regular perturbation approach. The correct
weak-coupling theory must include the self-energy of the ion due to the image
charge interaction. The image force qualitatively alters the double layer
structure and properties, and gives rise to many non-PB effects, such as
nonmonotonic dependence of the surface energy on concentration and charge
inversion. In the presence of dielectric discontinuity, there is no limiting
condition for which the PB theory is valid
Chromatic number of Euclidean plane
If the chromatic number of Euclidean plane is larger than four, but it is
known that the chromatic number of planar graphs is equal to four, then how
does one explain it? In my opinion, they are contradictory to each other. This
idea leads to confirm the chromatic number of the plane about its exact value
Inhomogeneous screening near a dielectric interface
Screening is one of the most important concepts in the study of charged
systems. Near a dielectric interface, the ion distribution in a salt solution
can be highly nonuniform. Here, we develop a theory that self-consistently
treats the inhomogeneous screening effects. At higher concentrations when the
bulk Debye screening length is comparable to the Bjerrum length, the double
layer structure and interfacial properties are significantly affected by the
inhomogeneous screening. In particular, the depletion zone is considerably
wider than that predicted by the bulk screening approximation or the WKB
approximation. For asymmetric salts, the inhomogeneous screening leads to
enhanced charge separation and surface potential.Comment: 5 figure
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