5,335 research outputs found
STM Studies of TbTe3: Evidence for a fully Incommensurate Charge Density Wave
We observe unidirectional charge density wave ordering on the cleaved surface
of TbTe3 with a Scanning Tunneling Microscope at ~6 K. The modulation
wave-vector q_{CDW} as determined by Fourier analysis is 0.71 +/- 0.02 * 2
pi/c. (Where c is one edge of the in-plane 3D unit cell.) Images at different
tip-sample voltages show the unit cell doubling effects of dimerization and the
layer below. Our results agree with bulk X-ray measurements, with the addition
of ~(1/3) * 2 pi/a ordering perpendicular to the CDW. Our analysis indicates
that the CDW is incommensurate.Comment: 4 pages, 4 figure
On the Experimental Estimation of Surface Enhanced Raman Scattering (SERS) Cross Sections by Vibrational Pumping
We present an in-depth analysis of the experimental estimation of cross
sections in Surface Enhanced Raman Scattering (SERS) by vibrational pumping.
The paper highlights the advantages and disadvantages of the technique,
pinpoints the main aspects and limitations, and provides the underlying
physical concepts to interpret the experimental results. Examples for several
commonly used SERS probes are given, and a discussion on future possible
developments is also presented.Comment: To be submitted to J. Phys. Chem.
Enhancement factor distribution around a single SERS Hot-spot and its relation to Single Molecule detection
We provide the theoretical framework to understand the phenomenology and
statistics of single-molecule (SM) signals arising in Surface-Enhanced Raman
Scattering (SERS) under the presence of so-called electromagnetic hot-spots
(HS's). We show that most characteristics of the SM-SERS phenomenon can be
tracked down to the presence of tail-like (power law) distribution of
enhancements and we propose a specific model for it. We analyze, in the light
of this, the phenomenology of SM-SERS and show how the different experimental
manifestations of the effect reported in the literature can be analyzed and
understood under a unified ``universal'' framework with a minimum set of
parameters.Comment: 13 pages, 4 figures, submitted to J. Chem. Phy
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