2 research outputs found
Extended sedimentation profiles in charged colloids: the gravitational length, entropy, and electrostatics
We have measured equilibrium sedimentation profiles in a colloidal model
system with confocal microscopy. By tuning the interactions, we have determined
the gravitational length in the limit of hard-sphere-like interactions, and
using the same particles, tested a recent theory [R.van Roij, J. Phys. Cond.
Mat. 15, S3569, (2003)], which predicts a significantly extended sedimentation
profile in the case of charged colloids with long-ranged repulsions, due to a
spontaneously formed macroscopic electric field. For the hard-sphere-like
system we find that the gravitational length matches that expected. By tuning
the buoyancy of the colloidal particles we have shown that a mean field
hydrostatic equilibrium description even appears to hold in the case that the
colloid volume fraction changes significantly on the length scale of the
particle size. The extended sedimentation profiles of the colloids with
long-ranged repulsions are well-described by theory. Surprisingly, the theory
even seems to hold at concentrations where interactions between the colloids,
which are not modeled explicitly, play a considerable role
Sedimentation of binary mixtures of like- and oppositely charged colloids: the primitive model or effective pair potentials?
We study sedimentation equilibrium of low-salt suspensions of binary mixtures
of charged colloids, both by Monte Carlo simulations of an effective
colloids-only system and by Poisson-Boltzmann theory of a colloid-ion mixture.
We show that the theoretically predicted lifting and layering effect, which
involves the entropy of the screening ions and a spontaneous macroscopic
electric field [J. Zwanikken and R. van Roij, Europhys. Lett. {\bf 71}, 480
(2005)], can also be understood on the basis of an effective colloid-only
system with pairwise screened-Coulomb interactions. We consider, by theory and
by simulation, both repelling like-charged colloids and attracting oppositely
charged colloids, and we find a re-entrant lifting and layering phenomenon when
the charge ratio of the colloids varies from large positive through zero to
large negative values