The key role of interband transitions in hot-electron-modulated TiN films

Titanium nitride (TiN) is an emerging new material in the field of plasmonics, both for its linear and nonlinear optical properties. Similarly to noble metals, like, e.g., gold (Au), the giant third-order optical nonlinearity of TiN following excitation with fs-laser pulses has been attributed to the generation of hot electrons. Here we provide a numerical study of the Fermi smearing mechanism associated with photogenerated hot carriers and subsequent interband transitions modulation in TiN films. A detailed comparison with Au films is also provided, and saturation effects of the permittivity modulation for increasing pump fluence are discussed

Design and testing of ultrafast plasmonic lens nanoemitters

Nanoscale electron pulses are increasingly in demand, including as probes of nanoscale ultrafast dynamics and for emerging light source and lithography applications. Using electromagnetic simulations, we show that gold plasmonic lenses as multiphoton photoemitters provide unique advantages, including emission from an atomically at surface, nanoscale pulse diameter regardless of laser spot size, and femtosecond-scale response time. We then present fabrication of prototypes with sub-nm roughness via e-beam lithography, as well as electro-optical characterization using cathodoluminescence spectromicroscopy. Finally, we introduce a DC photogun at LBNL built for testing ultrafast photoemitters. We discuss measurement considerations for ultrafast nanoemitters and predict that we can extract tens of pA photocurrent from a single plasmonic lens using a Ti:Sa oscillator. Altogether, this lays the groundwork to develop and test a broad class of plasmon-enhanced ultrafast nanoemitters

The key role of interband transitions in hot-electron–modulated TiN films

Titanium nitride (TiN) is an emerging new material in the field of plasmonics, both for its linear and nonlinear optical properties. Similarly to noble metals, like, e.g., gold (Au), the giant third-order optical nonlinearity of TiN following excitation with fs-laser pulses has been attributed to the generation of hot electrons. Here we provide a numerical study of the Fermi smearing mechanism associated with photogenerated hot carriers and subsequent interband transitions modulation in TiN films. A detailed comparison with Au films is also provided, and saturation effects of the permittivity modulation for increasing pump fluence are discussed

Experimental and numerical investigation of the thermo-mechanical behaviour of an energy sheet pile wall

One-of-a-kind experimental and numerical investigation is provided in this paper about energy sheet pile walls: earth retaining structures that embed heat exchanger probes within piles for the exploitation of shallow geothermal energy. The study resorts to the results of full-scale in situ tests and coupled three-dimensional thermo-mechanical finite element analyses of an energy sheet pile wall constructed in an underground station. In this context, an investigation about the influence of thermal boundary and initial conditions on thermo-mechanical behaviour of the energy sheet pile wall is performed. The addressed thermal boundary conditions are associated with the thermal load imposed on the considered foundation by the field environment and the geothermal operation of some energy piles constituting the wall. The addressed thermal initial conditions are associated with the undisturbed ground temperature field of the considered site. Based on a comparison between the experimental and numerical results, and the development of numerical sensitivity analyses, criticalities associated with the analysis and modelling of the thermo-mechanical behaviour of energy sheet pile walls are denoted. The results highlight that: a marked non-uniformity of the temperature field can characterise real applications of energy sheet pile walls, representing a significant challenge to capture numerically at all spatial locations; a comparable influence denotes thermal loads that derive from the field environment and the geothermal operation of energy sheet pile walls, deserving attention when modelling the behaviour of such geostructures; and a critical role of the initial thermal conditions is connected to the satisfactory understanding and prediction of the thermo-mechanical behaviour of energy sheet pile walls, requiring careful consideration for analysis and design purposes

Optical and Magneto-Optical Properties of Donor-Bound Excitons in Vacancy-Engineered Colloidal Nanocrystals

Controlled insertion of electronic states within the band gap of semiconductor nanocrystals (NCs) is a powerful tool for tuning their physical properties. One compelling example is II-VI NCs incorporating heterovalent coinage metals in which hole capture produces acceptor-bound excitons. To date, the opposite donor-bound exciton scheme has not been realized because of the unavailability of suitable donor dopants. Here, we produce a model system for donor-bound excitons in CdSeS NCs engineered with sulfur vacancies (VS) that introduce a donor state below the conduction band (CB), resulting in long-lived intragap luminescence. VS-localized electrons are almost unaffected by trapping, and suppression of thermal quenching boosts the emission efficiency to 85%. Magneto-optical measurements indicate that the VS are not magnetically coupled to the NC bands and that the polarization properties are determined by the spin of the valence-band photohole, whose spin flip is massively slowed down due to suppressed exchange interaction with the donor-localized electron

Tunable physics through coordination chemistry: formation on oxide surface of Ti and Al chelates with 3-hydroxyflavone capable of electron injection and light emission

The optoelectronic features of 3-hydroxyflavone (3HF) self-assembled on the surface of an n-type semiconducting metal oxide (TiO2) and an insulator (Al2O3) are herein investigated. 3HF molecules use the coordinatively unsaturated metal ions present on the oxide surface to form metal complexes, which exhibit different behaviors upon light irradiation, depending on the nature of the metal ion. Specifically, we show that the photoluminescence of the surface species can be modulated according to the chemical properties of the complex (i.e. the binding metal ion), resulting in solid-state emitters in a high quantum yield (about 15%). Furthermore, photoinduced charge injection can be promoted or inhibited, providing a multifunctional hybrid system

Disentangling the ultrafast optical response of Titanium Nitride

In the last decade, Titanium Nitride has emerged as an alternative plasmonic material to noble metals, thanks to its refractory properties and a carrier-lattice thermalization time much faster ( 100 fs), with respect to e.g. gold (~ 1 ps). In this work, we provide a numerical model to unfold TiN ultrafast nonlinear optical response, on a broad spectral range. The calculations are validated on a 200 nm-thick TiN film on glas