Theory of interfacial charge-transfer complex photophysics in π\pi-conjugated polymer-fullerene blends

We present a theory of the electronic structure and photophysics of 1:1 blends of derivatives of polyparaphenylenevinylene and fullerenes. Within the same Coulomb-correlated Hamiltonian applied previously to interacting chains of single-component $\pi$-conjugated polymers, we find an exciplex state that occurs below the polymer's optical exciton. Weak absorption from the ground state occurs to the exciplex. We explain transient photoinduced absorptions in the blend, observed for both above-gap and below-gap photoexcitations, within our theory. Photoinduced absorptions for above-gap photoexcitation are from the optical exciton as well as the exciplex, while for below-gap photoexcitation induced absorptions are from the exciplex alone. In neither case are free polarons generated in the time scale of the experiment. Importantly, the photophysics of films of single-component $\pi$-conjugated polymers and blends can both be understood by extending Mulliken's theory of ground-state charge transfer to the case of excited-state charge transfer.Comment: 9 pages, 8 figure

Correlated-electron description of the photophysics of thin films of π\pi-conjugated polymers

We extend Mulliken's theory of ground state charge transfer in a donor-acceptor complex to excited state charge transfer between pairs of identical $\pi$-conjugated oligomers, one of which is in the optically excited state and the other in the ground state, leading to the formation of a charge-transfer exciton. Within our theory, optical absorptions from the charge-transfer exciton should include a low energy intermolecular charge-transfer excitation, as well as distinct intramolecular excitations from both the neutral delocalized exciton component and the Coulombically bound polaron-pair component of the charge-transfer exciton. We report high order configuration-interaction calculations for pairs of oligomers of poly-paraphenylenevinylene (PPV) that go beyond our previous single configuration-interaction calculation and find all five excited state absorptions predicted using heuristic arguments based on the Mulliken concept. Our calculated excited state absorption spectrum exhibits strong qualitative agreement with the complete wavelength-dependent ultrafast photoinduced absorption in films of PPV derivatives, suggesting that a significant fraction of the photoinduced absorption here is from the charge-transfer exciton. We make detailed comparisons to experiments, and a testable experimental prediction

The U.S. Government's automotive safety program : a preliminary examination

Division of Policy Research and Analysis, National Science Foundation under Grant no. OEP 76-0028

MOND rotation curves for spiral galaxies with Cepheid-based distances

Rotation curves for four spiral galaxies with recently determined Cepheid-based distances are reconsidered in terms of modified Newtonian dynamics (MOND). For two of the objects, NGC 2403 and NGC 7331, the rotation curves predicted by MOND are compatible with the observed curves when these galaxies are taken to be at the Cepheid distance. For NGC 3198, the largest distance for which reasonable agreement is obtained is 10% smaller than the Cepheid-based distance; i.e., MOND clearly prefers a smaller distance. This conclusion is unaltered when new near-infrared photometry of NGC 3198 is taken as the tracer of the stellar mass distribution. For the large Sc spiral, NGC 2841, MOND requires a distance which is at least 20% larger than the Cepheid-based distance. However, the discrepancy of the Tully-Fisher and SNIa distances with the Cepheid determination casts some doubt upon the Cepheid method in this case.Comment: Accepted for publication in astronomy and astrophysics 9 pages, 9 figure

Competition between Electromagnetically Induced Transparency and Raman Processes

We present a theoretical formulation of competition among electromagnetically induced transparency (EIT) and Raman processes. The latter become important when the medium can no longer be considered to be dilute. Unlike the standard formulation of EIT, we consider all fields applied and generated as interacting with both the transitions of the $\Lambda$ scheme. We solve Maxwell equations for the net generated field using a fast-Fourier-transform technique and obtain predictions for the probe, control and Raman fields. We show how the intensity of the probe field is depleted at higher atomic number densities due to the build up of multiple Raman fields.Comment: 3.5 pages, 7 figure

In-situ electrochemical fabrication of natural contacts on single nanowires

We report a template-based in-situ electrochemical method for fabricating natural electric contacts on single nanowires using a pair of cross-patterned electrodes. Such electric contacts are highly stable upon thermal cycling between room temperature and milli-Kelvin temperatures. Direct imaging of the single-nanowire contacts using scanning electron microscopy is also demonstrated.Comment: 13 pages, 4 figure

The role of intermolecular coupling in the photophysics of disordered organic semiconductors: Aggregate emission in regioregular polythiophene

We address the role of excitonic coulping on the nature of photoexcitations in the conjugated polymer regioregular poly(3-hexylthiophene). By means of temperature-dependent absorption and photoluminescence spectroscopy, we show that optical emission is overwhelmingly dominated by weakly coupled H-aggregates. The relative absorbance of the 0-0 and 0-1 vibronic peaks provides a powerfully simple means to extract the magnitude of the intermolecular coupling energy, approximately 5 and 30 meV for films spun from isodurene and chloroform solutions respectively.Comment: 10 pages, 4 figures, published in Phys. Rev. Let

Photophysics of charge-transfer excitons in thin films of \pi-conjugated polymers

We develop a theory of the electronic structure and photophysics of interacting chains of \pi- conjugated polymers to understand the differences between solutions and films. While photoexcitation generates only the intrachain exciton in solutions, the optical exciton as well as weakly allowed charge-transfer excitons are generated in films. We extend existing theories of the lowest polaronpair and charge-transfer excitons to obtain descriptions of the excited states of these interchain species, and show that a significant fraction of ultrafast photoinduced absorptions in films originate from the lowest charge-transfer exciton. Our proposed mechanism explains the simultaneous observation of polaronlike induced absorption features peculiar to films in ultrafast spectroscopy and the absence of mobile charge carriers as deduced from other experiments. We also show that there is a 1:1 correspondence between the essential states that describe the photophysics of single chains and of interacting chains that constitute thin films.Comment: 10 pages,4 figures, submitted to Phys Rev

Ultra Low Momentum Neutron Catalyzed Nuclear Reactions on Metallic Hydride Surfaces

Ultra low momentum neutron catalyzed nuclear reactions in metallic hydride system surfaces are discussed. Weak interaction catalysis initially occurs when neutrons (along with neutrinos) are produced from the protons which capture ``heavy'' electrons. Surface electron masses are shifted upwards by localized condensed matter electromagnetic fields. Condensed matter quantum electrodynamic processes may also shift the densities of final states allowing an appreciable production of extremely low momentum neutrons which are thereby efficiently absorbed by nearby nuclei. No Coulomb barriers exist for the weak interaction neutron production or other resulting catalytic processes.Comment: 4 pages, ReVTeX forma

Buried AGNs in Advanced Mergers:Mid-infrared color selection as a dual AGN finder

A direct consequence of hierarchical galaxy formation is the existence of dual supermassive black holes (SMBHs), which may be preferentially triggered as active galactic nuclei (AGN) during galaxy mergers. Despite decades of searching, however, dual AGNs are extremely rare, and most have been discovered serendipitously. Using the all-sky WISE survey, we identified a population of over 100 morphologically identified interacting galaxies or mergers that display red mid-infrared colors often associated in extragalactic sources with powerful AGNs. The vast majority of these advanced mergers are optically classified as star-forming galaxies suggesting that they may represent an obscured population of AGNs that cannot be found through optical studies. In this work, we present Chandra/ACIS observations and near-infrared spectra with the Large Binocular Telescope of six advanced mergers with projected pair separations less than ~ 10 kpc. The combined X-ray, near-infrared, and mid-infrared properties of these mergers provide confirmation that four out of the six mergers host at least one AGN, with four of the mergers possibly hosting dual AGNs with projected separations less than ~10 kpc, despite showing no firm evidence for AGNs based on optical spectroscopic studies. Our results demonstrate that 1) optical studies miss a significant fraction of single and dual AGNs in advanced mergers, and 2) mid-infrared pre-selection is extremely effective in identifying dual AGN candidates in late-stage mergers. Our multi-wavelength observations suggest that the buried AGNs in these mergers are highly absorbed, with intrinsic column densities in excess of N_H >10^24cm^-2, consistent with hydrodynamic simulations.Comment: 23 pages, 11 figures, accepted for publication to Ap