2 research outputs found
Charge Ordering in Organic ET Compounds
The charge ordering phenomena in quasi two-dimensional 1/4-filled organic
compounds (ET)_2X (ET=BEDT-TTF) are investigated theoretically for the
and -type structures, based on the Hartree approximation for the
extended Hubbard models with both on-site and intersite Coulomb interactions.
It is found that charge ordered states of stripe-type are stabilized for the
relevant values of Coulomb energies, while the spatial pattern of the stripes
sensitively depends on the anisotropy of the models. By comparing the results
of calculations with the experimental facts, where the effects of quantum
fluctuation is incorporated by mapping the stripe-type charge ordered states to
the S=1/2 Heisenberg Hamiltonians, the actual charge patterns in the insulating
phases of -(ET)_2MM'(SCN)_4 and -(ET)_2I_3 are deduced.
Furthermore, to obtain a unified view among the , and
-(ET)_2X families, the stability of the charge ordered state in
competition with the dimeric antiferromagnetic state viewed as the Mott
insulating state, which is typically realized in -type compounds, and
with the paramagnetic metallic state, is also pursued by extracting essential
parameters.Comment: 35 pages, 27 figures, submitted to J. Phys. Soc. Jp