Enhancement of the thermal expansion of organic charge transfer salts by strong electronic correlations

Organic charge transfer salts exhibit thermal expansion anomalies similar to those found in other strongly correlated electron systems. The thermal expansion can be anisotropic and have a non-monotonic temperature dependence. We show how these anomalies can arise from electronic effects and be significantly enhanced, particularly at temperatures below 100 K, by strong electronic correlations. For the relevant Hubbard model the thermal expansion is related to the dependence of the entropy on the parameters ($t$, $t'$, and $U$) in the Hamiltonian or the temperature dependence of bond orders and double occupancy. The latter are calculated on finite lattices with the Finite Temperature Lanczos Method. Although many features seen in experimental data, in both the metallic and Mott insulating phase, are described qualitatively, the calculated magnitude of the thermal expansion is smaller than that observed experimentally.Comment: 9 pages, 6 figure

Derivation of the probability distribution function for the local density of states of a disordered quantum wire via the replica trick and supersymmetry

We consider the statistical properties of the local density of states of a one-dimensional Dirac equation in the presence of various types of disorder with Gaussian white-noise distribution. It is shown how either the replica trick or supersymmetry can be used to calculate exactly all the moments of the local density of states. Careful attention is paid to how the results change if the local density of states is averaged over atomic length scales. For both the replica trick and supersymmetry the problem is reduced to finding the ground state of a zero-dimensional Hamiltonian which is written solely in terms of a pair of coupled ``spins'' which are elements of u(1,1). This ground state is explicitly found for the particular case of the Dirac equation corresponding to an infinite metallic quantum wire with a single conduction channel. The calculated moments of the local density of states agree with those found previously by Al'tshuler and Prigodin [Sov. Phys. JETP 68 (1989) 198] using a technique based on recursion relations for Feynman diagrams.Comment: 39 pages, 1 figur

Quantum frustration in organic Mott insulators: from spin liquids to unconventional superconductors

We review the interplay of frustration and strong electronic correlations in quasi-two-dimensional organic charge transfer salts, such as k-(BEDT-TTF)_2X and Et_nMe_{4-n}Pn[Pd(dmit)2]2. These two forces drive a range of exotic phases including spin liquids, valence bond crystals, pseudogapped metals, and unconventional superconductivity. Of particular interest is that in several materials there is a direct transition as a function of pressure from a spin liquid Mott insulating state to a superconducting state. Experiments on these materials raise a number of profound questions about the quantum behaviour of frustrated systems, particularly the intimate connection between spin liquids and superconductivity. Insights into these questions have come from a wide range of theoretical techniques including first principles electronic structure, quantum many-body theory and quantum field theory. In this review we introduce the basic ideas of the field by discussing a simple frustrated Heisenberg model with four spins. We then describe the key experimental results, emphasizing that for two materials, k-(BEDT-TTF)_2Cu_2(CN)_3 and EtMe_3Sb[Pd(dmit)_2]_2, there is strong evidence for a spin liquid ground state, and for EtMe_3P[Pd(dmit)_2]_2, a valence bond solid ground state. We review theoretical attempts to explain these phenomena, arguing that this can be captured by a Hubbard model on the anisotropic triangular lattice at half filling, and that resonating valence bond wavefunctions can capture most of the essential physics. We review evidence that this model can have a spin liquid ground state for a range of parameters that are realistic for the relevant materials. We conclude by summarising the progress made thus far and identifying some of the key questions still to be answered.Comment: Major rewrite. New material added and many typos corrected. 67 pages, 41 figures. Thanks to those who commented on the previous versio

Comment on the Coupling of Zero Sound to the J=1−J=1^- Modes of 3^3He-B

Features in the zero sound attenuation near the pair-breaking edge in superfluid $^3$He-B have been observed in large magnetic fields. Schopohl and Tewordt [{\sl J. Low Temp. Phys.} {\bf 57}, 601 (1984)] claim that the $J=1^-, M=\pm 1$ order-parameter collective modes couple to zero sound as a result of the distortion of the equilibrium order parameter by a magnetic field; they identify the new features with these modes. However, we show that, when the effect of gap distortion on the collective modes is properly taken into account, the collective mode equations of Schopohl and Tewordt yield no direct coupling of zero sound to the $J=1^-$ modes. Thus, the identification of the absorption features reported by Ling, Saunders and Dobbs [{\sl Phys. Rev. Lett.} {\bf 59}, 461 (1987)] near the pair-breaking edge with the $J=1^-$ modes is not clearly established.Comment: 6 pages (Tex with jnl.tex

Symmetry of the superconducting order parameter in frustrated systems determined by the spatial anisotropy of spin correlations

We study the resonating valence bond (RVB) theory of the Hubbard-Heisenberg model on the half-filled anisotropic triangular lattice. Varying the frustration changes the wavevector of maximum spin correlation in the Mott insulating phase. This, in turn, changes the symmetry of the superconducting state, that occurs at the boundary of the Mott insulating phase. We propose that this physics is realised in several families of quasi-two-dimensional organic superconductors.Comment: To appear in Phys. Rev. Lett. - 5 pages, 4 fig

Interplay of frustration, magnetism, charge ordering, and covalency in a model of Na0.5CoO2

We investigate an effective Hamiltonian for Na0.5CoO2 that includes the electrostatic potential due to the ordered Na ions and strong electronic correlations. This model displays a subtle interplay between metallic and insulating phases and between charge and magnetic order. For realistic parameters, the model predicts an insulating phase with similarities to a covalent insulator. We show that this interpretation gives a consistent explanation of experiments on Na0.5CoO2, including the small degree of charge ordering, the small charge gap, the large moment, and the optical conductivity.Comment: 5 pages, 4 figures. Text revised making more emphasis on model properties. Figures compacte

Quantum entanglement and fixed-point bifurcations

How does the classical phase space structure for a composite system relate to the entanglement characteristics of the corresponding quantum system? We demonstrate how the entanglement in nonlinear bipartite systems can be associated with a fixed point bifurcation in the classical dynamics. Using the example of coupled giant spins we show that when a fixed point undergoes a supercritical pitchfork bifurcation, the corresponding quantum state - the ground state - achieves its maximum amount of entanglement near the critical point. We conjecture that this will be a generic feature of systems whose classical limit exhibits such a bifurcation.Comment: v2: Structure of the paper changed for clarity, reduced length, now 9 pages with 6 figure