Dual-Band Selective Circular Dichroism in Mid-Infrared Chiral Metasurfaces

Most chiral metamaterials and meta surfaces are designed to operate in a single wavelength band and with a certain circular dichroism (CD) value. Here, mid-infrared chiral meta surface absorbers with selective CD in dual-wavelength bands are designed and demonstrated. The dual-band CD selectivity and tunability in the chiral meta surface absorbers are enabled by the unique design of a unit cell with two coupled rectangular bars. It is shown that the sign of CD in each wavelength band can be independently controlled and flipped by simply adjusting the geometric parameters, the width and the length, of the vertical rectangular bars. The mechanism of the dual-band CD selection in the chiral meta surface absorber is further revealed by studying the electric field and magnetic field distributions of the antibonding and bonding modes supported in the coupled bars under circularly polarized incident light. Furthermore, the chiral resonance wavelength can be continuously increased by scaling up the geometric parameters of the meta surface unit cell. The demonstrated results will contribute to the advance of future mid-infrared applications such as chiral molecular sensing, thermophotovoltaics, and optical communication

Strong Circular Dichroism in Chiral Plasmonic Metasurfaces Optimized by Micro-Genetic Algorithm

Strong circular dichroism in absorption in the near-infrared wavelength range is realized by designing binary-pattern chiral plasmonic metasurfaces via the micro-genetic algorithm optimization method. The influence of geometric parameter modifications in the binary-pattern nanostructures on the circular dichroism performance is studied. The strong circular dichroism in absorption is attributed to the simultaneous excitation and field interference of the resonant modes with relative phase delay under linearly polarized incident light. This work provides a universal design method toward the on-demand properties of chiral metasurfaces, which paves the way for future applications in chemical and biological sensing, chiral imaging and spectroscopy

Muon spin rotation study of the magnetic penetration depth in the intercalated graphite superconductor CaC6

We report temperature- and magnetic field-dependent bulk muon spin rotation measurements in a c-axis oriented superconductor CaC6 in the mixed state. Using both a simple second moment analysis and the more precise analytical Ginzburg-Landau model, we obtained a field independent in-plane magnetic penetration depth {\lambda}ab (0) = 72(3) nm. The temperature dependencies of the normalized muon spin relaxation rate and of the normalized superfluid density result to be identical, and both are well represented by the clean limit BCS model with 2\Delta/kB Tc = 3.6(1), suggesting that CaC6 is a fully gapped BCS superconductor in the clean limit regime.Comment: Accepted for publication in PR

Plasmon-Phonon Coupling between Mid-Infrared Chiral Metasurfaces and Molecular Vibrations

Plasmon-phonon coupling between metamaterials and molecular vibrations provides a new path for studying mid-infrared light-matter interactions and molecular detection. So far, the coupling between the plasmonic resonances of metamaterials and the phonon vibrational modes of molecules has been realized under linearly polarized light. Here, mid-infrared chiral plasmonic metasurfaces with high circular dichroism (CD) in absorption over 0.65 in the frequency range of 50 to 60 THz are demonstrated to strongly interact with the phonon vibrational resonance of polymethyl methacrylate (PMMA) molecules at 52 THz, under both left-handed and right-handed circularly polarized (LCP and RCP) light. The mode splitting features in the absorption spectra of the coupled metasurface-PMMA systems under both circular polarizations are studied in PMMA layers with different thicknesses. The relation between the mode splitting gap and the PMMA thickness is also revealed. The demonstrated results can be applied in areas of chiral molecular sensing, thermal emission, and thermal energy harvesting

Near-Infrared Chiral Plasmonic Metasurface Absorbers

Chirality plays an essential role in the fields of biology, medicine and physics. However, natural materials exhibit very weak chiroptical response. In this paper, near-infrared chiral plasmonic metasurface absorbers are demonstrated to selectively absorb either the left-handed or right-handed circularly polarized light for achieving large circular dichroism (CD) across the wavelength range from 1.3 µm to 1.8 µm. It is shown that the maximum chiral absorption can reach to 0.87 and that the maximum CD in absorption is around 0.70. The current chiral metasurface design is able to achieve strong chiroptical response, which also leads to high thermal CD for the local temperature increase. The high-contrast reflective chiral images are also realized with the designed metasurface absorbers. The demonstrated chiral metasurface absorbers can be applied in many areas, such as optical filters, thermal energy harvesting, optical communication, and chiral imaging

On the correct formula for the lifetime broadened superconducting density of states

We argue that the well known Dynes formula [Dynes R C {\it et al.} 1978 {\it Phys. Rev. Lett.} {\bf 41} 1509] for the superconducting quasiparticle density of states, which tries to incorporate the lifetime broadening in an approximate way, cannot be justified microscopically for conventional superconductors. Instead, we propose a new simple formula in which the energy gap has a finite imaginary part $-\Delta_2$ and the quasiparticle energy is real. We prove that in the quasiparticle approximation 2$\Delta_2$ gives the quasiparticle decay rate at the gap edge for conventional superconductors. This conclusion does not depend on the nature of interactions that cause the quasiparticle decay. The new formula is tested on the case of a strong coupling superconductor Pb$_{0.9}$Bi$_{0.1}$ and an excellent agreement with theoretical predictions is obtained. While both the Dynes formula and the one proposed in this work give good fits and fit parameters for Pb$_{0.9}$Bi$_{0.1}$, only the latter formula can be justified microscopically.Comment: 6 pages, 4 figure

STM studies of CoxNbSe2 and MnxNbSe2

Cobalt and Manganese intercalated NbSe(2) single crystals have been synthesized and characterized by DC magnetization and scanning tunnelling microscopy (STM) at low temperatures. We observed a pronounced peak effect in magnetization for both Co and Mn intercalated samples that we further investigated by low temperature STM. A structural phase transition of the vortex lattice (VL) has been observed for applied magnetic fields corresponding to the peak in magnetization

Effect of magnetic impurities on the vortex lattice properties in NbSe2 single crystals

We report a pronounced peak effect in the magnetization of CoxNbSe2 single crystals with critical temperatures T-c ranging between 7.1 and 5.0 K, and MnxNbSe2 single crystals with critical temperatures down to 3.4 K. We correlate the peak effect in magnetization with the structure of the vortex lattice across the peak-effect region using scanning-tunneling microscopy. Magnetization measurements show that the amplitude of the peak effect in the case of CoxNbSe2 exhibits a nonmonotonic behavior as a function of the Co content, reaching a maximum for concentration of Co of about 0.4 at. % (corresponding to a T-c of 5.7 K) and after that gradually decreasing in amplitude with the increase in the Co content. The normalized value of the peak position H-p/H-c2 has weak dependence on Co concentration. In the case of MnxNbSe2 the features of the peak effect as a function of the Mn content are different and they can be understood in terms of strong pinning

Intrinsic Photoconductivity of Few-layered ZrS2 Phototransistors via Multiterminal Measurements

We report intrinsic photoconductivity studies on one of the least examinedlayered compounds, ZrS2.Few-atomic layer ZrS2 field-effect transistorswere fabricated on the Si/SiO2 substrate and photoconductivity measurements were performed using both two- and four-terminal configurationsunder the illumination of 532 nm laser source. We measured photocurrentas a function of the incident optical power at several source-drain (bias)voltages. We observe a significantly large photoconductivity when measured in the multiterminal (four-terminal) configuration compared to thatin the two-terminal configuration. For an incident optical power of 90nW, the estimated photosensitivity and the external quantum efficiency(EQE) measured in two-terminal configuration are 0.5 A/W and 120%,respectively, under a bias voltage of 650 mV. Under the same conditions,the four-terminal measurements result in much higher values for both thephotoresponsivity (R) and EQE to 6 A/W and 1400%, respectively. Thissignificant improvement in photoresponsivity and EQE in the four-terminal configuration may have been influenced by the reduction of contactresistance at the metal-semiconductor interface, which greatly impacts thecarrier mobility of low conducting materials. This suggests that photoconductivity measurements performed through the two-terminal configurationin previous studies on ZrS2 and other 2D materials have severely underestimated the true intrinsic properties of transition metal dichalcogenides andtheir remarkable potential for optoelectronic applications

Cerebrospinal fluid biomarkers in human genetic transmissible spongiform encephalopathies

The 14-3-3 protein test has been shown to support the clinical diagnosis of sporadic Creutzfeldt-Jakob disease (CJD) when associated with an adequate clinical context, and a high differential potential for the diagnosis of sporadic CJD has been attributed to other cerebrospinal fluid (CSF) proteins such as tau protein, S100b and neuron specific enolase (NSE). So far there has been only limited information available about biochemical markers in genetic transmissible spongiform encephalopathies (gTSE), although they represent 10–15% of human TSEs. In this study, we analyzed CSF of 174 patients with gTSEs for 14-3-3 (n = 166), tau protein (n = 78), S100b (n = 46) and NSE (n = 50). Levels of brain-derived proteins in CSF varied in different forms of gTSE. Biomarkers were found positive in the majority of gCJD (81%) and insert gTSE (69%), while they were negative in most cases of fatal familial insomnia (13%) and Gerstmann-Sträussler-Scheinker syndrome (10%). Disease duration and codon 129 genotype influence the findings in a different way than in sporadic CJD