Synthesis and properties of lipoamino acid/fatty acid mixtures. Influence of the amphiphilic structure.

The acylation of amino acids by acid chlorides with from 8 to 12 carbon atoms, in alkaline aqueous medium following Shotten-Baumann reaction, results in sodium salts of Nα-acylamino acids and fatty acids mixture. These lastest are present in proportion from 40 to 60%. These compositions represent mixtures of amphiphilic anionic surfactants. They contribute together to the properties of the formulation. Measurements of the surface-active properties of these formulations, such as critical micelle concentration (CMC), surface tension at the CMC (TS), foaming capacity (FC) and foaming stability (FS), show that surfactant mixtures with the longest chain have the most desirable properties. They are comparable to commercial petroleum-based surfactants. Thus, the CMC, TS and CM values of the formulation obtained starting from leucine and dodecanoyl chloride (310 mg/L, 30.1 mN/m and 200%, respectively) are similar, even better than, sodium dodecylsulfate (290 mg/L, 39.1 mN/m and 230%, respectively

G.A. Cohen and the Logic of Egalitarian Congruence

In this article, I argue that G. A. Cohen’s defense of the feminist slogan, “The personal is political”, his argument against Rawls’s restriction of principles of justice to the basic structure of society, depends for its intelligibility on the ability to distinguish—with reasonable but perhaps not perfect precision—between those situations in which what Nancy Rosenblum has called “the logic of congruence” is validly invoked and those in which it is not. More importantly, I suggest that the philosophical shape of Cohen’s critique makes it difficult for him to supply the required criterion, and that the methodological “intuitionism” he claims to be committed to is at odds with his larger argument against Rawls concerning the subject of justice