Sorption Properties of Clay and Pectin-Containing Hydrogels

As is known, polymeric polyelectrolyte hydrogels are superabsorbents that are capable of absorbing moisture in amounts many times greater than their own mass. Numerous studies have shown that besides water absorption and retention, they can also be effectively used as sorbents to purify water from heavy metals. In many works, attempts are made to improve the sorption properties of polyelectrolyte hydrogels by creating polymer composites based on them. Organic/inorganic composite materials frequently exhibited desired hybrid performance superior to their individual components and cost-efficient characteristics. The composites derived from natural polysaccharides and inorganic clay minerals are of special interest by virtue of their unique commercial and environmental advantages, which means that the design and development of environmentally friendly superabsorbents, introducing natural ingredients, have long been necessary. In this paper, we consider polymer hydrogels based on a copolymer of acrylic acid and acrylamide filled with pectin and bentonite. The aim of this study is to investigate the influence of chemical conditions on hydrogels and their composites, kinetic, and absorption behavior toward metal ions in the presence of the chelating agent. In this chapter, an investigation of the kinetic patterns of swelling, deswelling, and sorption of the hydrogels and their composites will be presented

Study of the Compatibility of Polyvinyl Chloride and Polyhydroxybutyrate in a Mixture of Organic Solvents

В статье исследована совместимость поливинилхлорида (ПВХ) и полигидроксибутирата (ПГБ) в смеси органических растворителей при различном соотношении полимеров. Были выполнены расчеты для прогнозирования совместности полимеров, выполнена экспериментальная оценка совместимости путем исследования условий и времени гелирования полимерных растворов, изучено влияние соотношения ПВХ и ПГБ на динамическую вязкость и на электропроводность полимерных растворов, а также были получены ИК‑спектр и графики прочности и удлинения полимерных пленок на основе ПВХ и ПГБ при прокалывании. Результаты исследования совместимости полимеров могут быть использованы для выбора оптимального соотношения полимеров при получении ПВХ/ПГБ пленок методом литья или ПВХ/ПГБ нановолокон методом электроформованияThe article investigates the compatibility of polyvinyl chloride (PVC) and polyhydroxybutyrate (PHB) in a mixture of organic solvents at different ratios of polymers. Computations were performed to predict the compatibility of polymers, an experimental assessment of compatibility was performed by studying the conditions and time of gelation of polymer solutions, the effect of the ratio of PVC and PHB on the dynamic viscosity and electrical conductivity of polymer solutions was studied, and the IR spectrum and graphs of the strength and elongation of polymer films were obtained. based on PVC and PHB when pierced. The results of the study of polymer compatibility can be used to select the optimal ratio of polymers in the production of PVC/PHB films by casting or PVC/PHB nanofibers by electrospinnin

Influence of Thermal Treatment and Acetic Acid Concentration on the Electroactive Properties of Chitosan/PVA-Based Micro- and Nanofibers

This study presents, for the first time, a comprehensive investigation of the influence of pre- and post-fabrication parameters for the electroactive properties of electrospun chitosan/PVA-based micro- and nanofibers. Chitosan/PVA fibers were fabricated using electrospinning, characterized, and tested as electroactive materials. Solutions with different acetic acid contents (50, 60, 70, and 80 v/v%) were used, and the rheological properties of the solutions were analyzed. Characterization techniques, such as rheology, conductivity, optical microscopy, a thermogravimetric analysis, differential scanning calorimetry, a tensile test, and FT-IR spectroscopy, were utilized. Fiber mats from the various solutions were thermally treated, and their electroactive behavior was examined under a constant electric potential (10 V) at different pHs (2–13). The results showed that fibers electrospun from 80% acetic acid had a lower electroactive response and dissolved quickly. However, thermal treatment improved the stability and electroactive response of all fiber samples, particularly the ones spun with 80% acetic acid, which exhibited a significant increase in speed displacement from 0 cm−1 (non-thermally treated) to 1.372 cm−1 (thermally treated) at a pH of 3. This study sheds light on the influence of pre- and post-fabrication parameters on the electroactive properties of chitosan/PVA fibers, offering valuable insights for the development of electroactive materials in various applications

The Mechanical Properties of PVC Nanofiber Mats Obtained by Electrospinning

This paper investigates the mechanical properties of oriented polyvinyl chloride (PVC) nanofiber mats, which, were obtained by electrospinning a PVC solution. PVC was dissolved in a solvent mixture of tetrahydrofuran/dimethylformamide. Electrospinning parameters used in our work were, voltage 20 kV; flow rate 0.5 mL/h; the distance between the syringe tip and collector was 15 cm. The rotating speed of the drum collector was varied from 500 to 2500 rpm with a range of 500 rpm. Nanofiber mats were characterized by scanning electron microscope, thermogravimetric analysis, differential scanning calorimetry methods. The mechanical properties of PVC nanofiber mats, such as tensile strength, Young’s modulus, thermal degradation, and glass transition temperature were also analyzed. It was shown that, by increasing the collector’s rotation speed from 0 (flat plate collector) to 2500 rpm (drum collector), the average diameter of PVC nanofibers decreased from 313 ± 52 to 229 ± 47 nm. At the same time, it was observed that the mechanical properties of the resulting nanofiber mats were improved: tensile strength increased from 2.2 ± 0.2 MPa to 9.1 ± 0.3 MPa, Young’s modulus from 53 ± 14 to 308 ± 19 MPa. Thermogravimetric analysis measurements showed that there was no difference in the process of thermal degradation of nanofiber mats and PVC powders. On the other hand, the glass transition temperature of nanofiber mats and powders did show different values, such values were 77.5 °C and 83.2 °C, respectively

A Review on Electrospun PVC Nanofibers: Fabrication, Properties, and Application

Polyvinyl chloride (PVC) is a widely used polymer, not only in industry, but also in our daily life. PVC is a material that can be applied in many different fields, such as building and construction, health care, and electronics. In recent decades, the success of electrospinning technology to fabricate nanofibers has expanded the applicability of polymers. PVC nanofibers have been successfully manufactured by electrospinning. By changing the initial electrospinning parameters, it is possible to obtain PVC nanofibers with diameters ranging from a few hundreds of nanometers to several micrometers. PVC nanofibers have many advantages, such as high porosity, high mechanical strength, large surface area, waterproof, and no toxicity. PVC nanofibers have been found to be very useful in many fields with a wide variety of applications such as air filtration systems, water treatment, oil spill treatment, batteries technology, protective clothing, corrosion resistance, and many others. This paper reviews the fabricating method, properties, applications, and prospects of PVC nanofibers

A Review on Chitosan and Cellulose Hydrogels for Wound Dressings

Wound management remains a challenging issue around the world, although a lot of wound dressing materials have been produced for the treatment of chronic and acute wounds. Wound healing is a highly dynamic and complex regulatory process that involves four principal integrated phases, including hemostasis, inflammation, proliferation, and remodeling. Chronic non-healing wounds are wounds that heal significantly more slowly, fail to progress to all the phases of the normal wound healing process, and are usually stalled at the inflammatory phase. These wounds cause a lot of challenges to patients, such as severe emotional and physical stress and generate a considerable financial burden on patients and the general public healthcare system. It has been reported that about 1–2% of the global population suffers from chronic non-healing wounds during their lifetime in developed nations. Traditional wound dressings are dry, and therefore cannot provide moist environment for wound healing and do not possess antibacterial properties. Wound dressings that are currently used consist of bandages, films, foams, patches and hydrogels. Currently, hydrogels are gaining much attention as a result of their water-holding capacity, providing a moist wound-healing milieu. Chitosan is a biopolymer that has gained a lot of attention recently in the pharmaceutical industry due to its unique chemical and antibacterial nature. However, with its poor mechanical properties, chitosan is incorporated with other biopolymers, such as the cellulose of desirable biocompatibility, at the same time having the improved mechanical and physical properties of the hydrogels. This review focuses on the study of biopolymers, such as cellulose and chitosan hydrogels, for wound treatment