31,518 research outputs found
The Quantum Algebraic Structure of the Twisted XXZ Chain
We consider the Quantum Inverse Scattering Method with a new R-matrix
depending on two parameters and . We find that the underlying algebraic
structure is the two-parameter deformed algebra enlarged by
introducing an element belonging to the centre. The corresponding Hamiltonian
describes the spin-1/2 XXZ model with twisted periodic boundary conditions.Comment: LateX file, 9 pages, Minor changes (including authors` names in the
hep-th heading
On duality of the noncommutative extension of the Maxwell-Chern-Simons model
We study issues of duality in 3D field theory models over a canonical
noncommutative spacetime and obtain the noncommutative extension of the
Self-Dual model induced by the Seiberg-Witten map. We apply the dual projection
technique to uncover some properties of the noncommutative Maxwell-Chern-Simons
theory up to first-order in the noncommutative parameter. A duality between
this theory and a model similar to the ordinary self-dual model is
estabilished. The correspondence of the basic fields is obtained and the
equivalence of algebras and equations of motion are directly verified. We also
comment on previous results in this subject.Comment: Revtex, 9 pages, accepted for publication PL
Liquid mixtures involving fluorinated alcohols: The equation of state (p, r, T, x) of (Ethanol + Trifluoroethanol) Experimental and Simulation
Liquid mixtures involving fluorinated alcohols:
The equation of state (p, r, T, x) of (Ethanol + Trifluoroethanol)
Experimental and Simulation
Pedro Duartea, Djêide Rodriguesa, Marcelo Silvaa, Pedro Morgadoa,
Luís Martinsa,b and Eduardo J. M. Filipea*
aCentro de Química Estrutural, Instituto Superior Técnico, 1049-001 Lisboa, Portugal
bCentro de Química de Évora, Universidade de Évora, 7000-671 Évora, Portugal
Fluorinated alcohols are substances with unique properties and high technological value in the pharmaceutical and chemical industries. Trifluoroethanol (TFE), in particular, displays a number of unusual properties as a solvent. For example, it dissolves nylon at room temperature and is effectively used as solvent in bioengineering. The presence of the three fluorines atoms gives the alcohol a high ionization constant, strong hydrogen bonding capability and stability at high temperatures.
In the pharmaceutical industry, TFE finds use as the major raw material for the production of inhalation anesthetics. Mixtures of TFE and water (known as Fluorinols®) are used as working fluids for Rankine cycle heat engines for terrestrial and space applications, as a result of a unique combination of physical and thermodynamic properties such as high thermal efficiency and excellent turbine expansion characteristics.
Environmentally, TFE is a CFC substitute with an acceptable short lifetime and with small ozone depletion potential. Additionally, TFE is known to induce conformational changes in proteins and it is used as a co-solvent to analyze structural features of partially folded states.
The (ethanol + TFE) system displays an interesting and peculiar behaviour, combining a negative azeotrope with high positive excess volumes.
In this work, liquid mixtures of (ethanol + TFE) were investigated. The densities of the mixtures were measured as a function of composition between 278K and 338K and at pressures up to 700 bar. The corresponding excess volumes as a function of temperature and pressure, the isothermal compressibilities and thermal expansivities were calculated from the experimental results. The mixtures are highly non-ideal with excess volumes ranging from 0.8 - 1.0 cm3mol-1.
Finally, molecular dynamic simulations were performed to model and interpret the experimental results. The Trappe force field was used to simulate the (TFE + ethanol) mixtures and calculate the corresponding excess volumes. The simulation results are able to reproduce the correct sign and order of magnitude of the experimental VE without fitting to the experimental data. Furthermore, the simulations suggest the presence of a particular type of hydrogen bridge between ethanol and TFE, that can help to rationalize the experimental results
Anisotropic Cosmological Constant and the CMB Quadrupole Anomaly
There are evidences that the cosmic microwave background (CMB) large-angle
anomalies imply a departure from statistical isotropy and hence from the
standard cosmological model. We propose a LCDM model extension whose dark
energy component preserves its nondynamical character but wield anisotropic
vacuum pressure. Exact solutions for the cosmological scale factors are
presented, upper bounds for the deformation parameter are evaluated and its
value is estimated considering the elliptical universe proposal to solve the
quadrupole anomaly. This model can be constructed from a Bianchi I cosmology
with cosmological constant from two different ways: i) a straightforward
anisotropic modification of the vacuum pressure consistently with
energy-momentum conservation; ii) a Poisson structure deformation between
canonical momenta such that the dynamics remain invariant under scale factors
rescalings.Comment: 8 pages, 2 columns, 1 figure. v2: figure improved, added comments on
higher eccentricity powers and references. v3: typos corrected, version to
appear in PR
Avaliação de extratores de zinco em solos da Amazônia.
A Fertbio 2002 reuniu a XXV Reunião Brasileira de Fertilidade do Solo e Nutrição de Plantas, a IX Reunião Brasileira sobre Micorrizas, o VII Simpósio Brasileiro de Microbiologia do Solo e a Reunião Brasileira de Biologia do Solo, sob o tema: "Agricultura: bases ecológicas para o desenvolvimento social e econômico sustentado
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