339 research outputs found
Lowering and raising operators for the free Meixner class of orthogonal polynomials
We compare some properties of the lowering and raising operators for the
classical and free classes of Meixner polynomials on the real line
Small innovative business development experience
The article deals with the study of the experience and impact of establishing micro, small and medium-sized businesses, including innovative enterprises, in developed countries of Europe, the USA, and Russia, their development dynamics, as well as tools ensuring government regulation of their effective functioning.
In Russia, the right to establish small innovative enterprises was granted by Federal Law No. 217-FZ dated August 2, 2009. The article provides quantitative statistics of the accounting of small innovative enterprises operating in the scientific and educational sector of Russiaβs economy and the economic indicators of their activities, obtained based on monitoring results. The article also analyzes the US legislation in the innovation field.
The research allowed us to come to the following key conclusions: Micro, small, and medium-sized businesses play an important role in the European and American economies, being the most important source of innovation and new jobs.
In Russia, further development of a mechanism for commercialization of intellectual results requires improvement in terms of harmonization with international rules. The foreign legislative experience with respect to micro, small and medium-sized businesses is of particular interest for the improvement of the regulatory framework that would ensure the effective operation of small innovative enterprises in Russia.peer-reviewe
Formation of Verbal Forms of Imperative in the Livvik and Lyudik Dialects of Karelian Language
The question of the formation of imperative forms in the dialects of the Karelian language is considered. Attention is paid to two dialects: Livvik and Lyudik. The results of a comparative analysis of affirmative and negative forms of the imperative in the mentioned adverbs are presented. Particular attention is paid to the indicators of the imperative, their origin, features of use in a comparative aspect. The novelty of research is that at present the literary form of the Lyudik dialect of the Karelian language is still not fully formed, and today the Lyudik dialect is poorly represented in the educational space: systematic and systematic teaching due to the influence of objective and subjective factors is not conducted. It is noted that the Livvik dialect, on the contrary, is actively taught in educational institutions of the Republic of Karelia, the grammatical structure of this dialect is quite well studied and tested in the educational process. Based on the fact that the Livvik and Lyudik dialects are most closely related to each other, the material analyzed can also be used in the preparation of textbooks, which are urgently needed by people of the Lyudik dialect
REGULATION OF WORKING MOBILITY AS A FACTOR OF REGION INVESTMENT ATTRACTIVENESS (ULYANOVSK REGION FOR EXAMPLE)
In the article analyzed existing migration flows in Ulyanovsk region. Using cluster analysis recieved groups of region districts with same migration activities. Found out reasons that have influence on migration process. Analyzed influence of migration to labor market development and given recommends to reducing migration
REGULATION OF WORKING MOBILITY AS A FACTOR OF REGION INVESTMENT ATTRACTIVENESS (ULYANOVSK REGION FOR EXAMPLE)
In the article analyzed existing migration flows in Ulyanovsk region. Using cluster analysis recieved groups of region districts with same migration activities. Found out reasons that have influence on migration process. Analyzed influence of migration to labor market development and given recommends to reducing migration
Π‘ΠΎΠ²ΠΌΠ΅ΡΠ΅Π½Π½ΡΠΉ ΠΏΡΠΎΡΠ΅ΡΡ ΡΠΈΠ½ΡΠ΅Π·Π° ΡΠΈΠΊΠ»ΠΎΠ³Π΅ΠΊΡΠΈΠ»ΡΠΈΠΊΠ»ΠΎΠ³Π΅ΠΊΡΠ°Π½ΠΊΠ°ΡΠ±ΠΎΠΊΡΠΈΠ»Π°ΡΠ° ΠΈΠ· ΡΠΈΠΊΠ»ΠΎΠ³Π΅ΠΊΡΠ°Π½ΠΎΠ»Π° ΠΈ CO, ΠΊΠ°ΡΠ°Π»ΠΈΠ·ΠΈΡΡΠ΅ΠΌΡΠΉ ΡΠΈΡΡΠ΅ΠΌΠΎΠΉ Pd(OAc)2βPPh3βΠΏ-ΡΠΎΠ»ΡΠΎΠ»ΡΡΠ»ΡΡΠΎΠΊΠΈΡΠ»ΠΎΡΠ°
Objectives. To study the possibility of combining acid-catalytic cyclohexanol dehydration and alkoxycarbonylation of the formed cyclohexene with cyclohexanol and carbon(II) oxide in a single reactor in order to achieve high yields of the target cyclohexyl cyclohexanecarboxylate product under mild conditions using the Pd(OAc)2βPPh3βp-toluenesulfonic acid catalytic system.Methods. The combined process took place in a toluene medium in a periodic steel reactor designed to operate at elevated pressure, equipped with a glass insert, a magnetic stirrer, and a sampler, as well as gas input and discharge devices. The reaction mass with the components of the catalytic system was placed in a glass reactor inside a steel autoclave. The reaction mass samples obtained during the combined process were analyzed by gasβliquid chromatography with a flame ionization detector.Results. The possibility of combining cyclohexanol dehydration catalyzed by p-toluenesulfonic acid monohydrate and formed cyclohexene alkoxycarbonylation with cyclohexanol and CO during catalysis by the Pd(OAc)2βPPh3βp-toluenesulfonic acid system in a single reactor was demonstrated. Under mild conditions (temperature 110Β°C; CO pressure 2.1 MPa), the target product yield reached 64.8% in 5 h. However, the combined process is complicated by the formation of a cyclohexanecarboxylic acid by-product formed as a result of the cyclohexyl cyclohexanecarboxylate hydrolysis and the cyclohexene hydroxycarbonylation.Conclusions. The reactions of intramolecular acid-catalytic cyclohexanol dehydration and formed cyclohexene alkoxycarbonylation catalyzed by the Pd(OAc)2βPPh3βp-toluenesulfonic acid system can be combined in a single reactor. p-Toluenesulfonic acid can simultaneously act as a catalyst for the cyclohexanol dehydration and a co-catalyst of the palladiumβphosphine system of cyclohexene alkoxycarbonylation. The involvement of cyclohexene, representing a product of reversible cyclohexanol dehydration, in the alkoxycarbonylation reaction is a factor in shifting the dehydration reaction equilibrium towards the formation of cyclohexene. Cyclohexanecarboxylic acid is a by-product of the proposed combined process. A factor in the reduction of target product yield is water formed as a result of cyclohexanol dehydration due to the involvement of the latter in the hydrolysis reaction and the course of the cyclohexene hydroxycarbonylation.Π¦Π΅Π»ΠΈ. ΠΠ·ΡΡΠ΅Π½ΠΈΠ΅ Π²ΠΎΠ·ΠΌΠΎΠΆΠ½ΠΎΡΡΠΈ ΡΠΎΠ²ΠΌΠ΅ΡΠ΅Π½ΠΈΡ Π² ΠΎΠ΄Π½ΠΎΠΌ ΡΠ΅Π°ΠΊΡΠΎΡΠ΅ ΡΠ΅Π°ΠΊΡΠΈΠΉ ΠΊΠΈΡΠ»ΠΎΡΠ½ΠΎΠΊΠ°ΡΠ°Π»ΠΈΡΠΈΡΠ΅ΡΠΊΠΎΠΉ Π΄Π΅Π³ΠΈΠ΄ΡΠ°ΡΠ°ΡΠΈΠΈ ΡΠΈΠΊΠ»ΠΎΠ³Π΅ΠΊΡΠ°Π½ΠΎΠ»Π° ΠΈ Π°Π»ΠΊΠΎΠΊΡΠΈΠΊΠ°ΡΠ±ΠΎΠ½ΠΈΠ»ΠΈΡΠΎΠ²Π°Π½ΠΈΡ ΠΎΠ±ΡΠ°Π·ΡΡΡΠ΅Π³ΠΎΡΡ ΡΠΈΠΊΠ»ΠΎΠ³Π΅ΠΊΡΠ΅Π½Π° ΡΠΈΠΊΠ»ΠΎΠ³Π΅ΠΊΡΠ°Π½ΠΎΠ»ΠΎΠΌ ΠΈ ΠΎΠΊΡΠΈΠ΄ΠΎΠΌ ΡΠ³Π»Π΅ΡΠΎΠ΄Π° (II). Π£ΡΡΠ°Π½ΠΎΠ²Π»Π΅Π½ΠΈΠ΅ Π²ΠΎΠ·ΠΌΠΎΠΆΠ½ΠΎΡΡΠΈ Π΄ΠΎΡΡΠΈΠΆΠ΅Π½ΠΈΡ Π²ΡΡΠΎΠΊΠΈΡ
Π²ΡΡ
ΠΎΠ΄ΠΎΠ² ΡΠ΅Π»Π΅Π²ΠΎΠ³ΠΎ ΠΏΡΠΎΠ΄ΡΠΊΡΠ° β ΡΠΈΠΊΠ»ΠΎΠ³Π΅ΠΊΡΠΈΠ»ΡΠΈΠΊΠ»ΠΎΠ³Π΅ΠΊΡΠ°Π½ΠΊΠ°ΡΠ±ΠΎΠΊΡΠΈΠ»Π°ΡΠ° β Π² ΠΌΡΠ³ΠΊΠΈΡ
ΡΡΠ»ΠΎΠ²ΠΈΡΡ
ΠΏΡΠΈ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π΅ ΡΠΈΡΡΠ΅ΠΌΠΎΠΉ Pd(OAc)2βPPh3βΠΏ-ΡΠΎΠ»ΡΠΎΠ»ΡΡΠ»ΡΡΠΎΠΊΠΈΡΠ»ΠΎΡΠ°.ΠΠ΅ΡΠΎΠ΄Ρ. Π‘ΠΎΠ²ΠΌΠ΅ΡΠ΅Π½Π½ΡΠΉ ΠΏΡΠΎΡΠ΅ΡΡ ΠΈΠ·ΡΡΠ°Π»ΡΡ Π² ΡΡΠ΅Π΄Π΅ ΡΠΎΠ»ΡΠΎΠ»Π° Π² ΠΏΠ΅ΡΠΈΠΎΠ΄ΠΈΡΠ΅ΡΠΊΠΎΠΌ ΡΡΠ°Π»ΡΠ½ΠΎΠΌ ΡΠ΅Π°ΠΊΡΠΎΡΠ΅, ΡΠ°ΡΡΡΠΈΡΠ°Π½Π½ΠΎΠΌ Π½Π° ΡΠ°Π±ΠΎΡΡ ΠΏΡΠΈ ΠΏΠΎΠ²ΡΡΠ΅Π½Π½ΠΎΠΌ Π΄Π°Π²Π»Π΅Π½ΠΈΠΈ, ΡΠ½Π°Π±ΠΆΠ΅Π½Π½ΠΎΠΌ ΡΡΠ΅ΠΊΠ»ΡΠ½Π½ΠΎΠΉ Π²ΡΡΠ°Π²ΠΊΠΎΠΉ, ΠΌΠ°Π³Π½ΠΈΡΠ½ΠΎΠΉ ΠΌΠ΅ΡΠ°Π»ΠΊΠΎΠΉ, ΠΏΡΠΎΠ±ΠΎΠΎΡΠ±ΠΎΡΠ½ΠΈΠΊΠΎΠΌ, ΡΡΡΡΠΎΠΉΡΡΠ²Π°ΠΌΠΈ Π²Π²ΠΎΠ΄Π° ΠΈ ΡΠ±ΡΠΎΡΠ° Π³Π°Π·ΠΎΠ². Π Π΅Π°ΠΊΡΠΈΠΎΠ½Π½Π°Ρ ΠΌΠ°ΡΡΠ° Ρ ΠΊΠΎΠΌΠΏΠΎΠ½Π΅Π½ΡΠ°ΠΌΠΈ ΠΊΠ°ΡΠ°Π»ΠΈΡΠΈΡΠ΅ΡΠΊΠΎΠΉ ΡΠΈΡΡΠ΅ΠΌΡ ΠΏΠΎΠΌΠ΅ΡΠ°Π»Π°ΡΡ Π² ΡΡΠ΅ΠΊΠ»ΡΠ½Π½ΡΠΉ ΡΠ΅Π°ΠΊΡΠΎΡ Π²Π½ΡΡΡΠΈ ΡΡΠ°Π»ΡΠ½ΠΎΠ³ΠΎ Π°Π²ΡΠΎΠΊΠ»Π°Π²Π°. ΠΡΠ±ΠΈΡΠ°Π΅ΠΌΡΠ΅ Π² Ρ
ΠΎΠ΄Π΅ ΡΠΎΠ²ΠΌΠ΅ΡΠ΅Π½Π½ΠΎΠ³ΠΎ ΠΏΡΠΎΡΠ΅ΡΡΠ° ΠΏΡΠΎΠ±Ρ ΡΠ΅Π°ΠΊΡΠΈΠΎΠ½Π½ΠΎΠΉ ΠΌΠ°ΡΡΡ Π°Π½Π°Π»ΠΈΠ·ΠΈΡΠΎΠ²Π°Π»ΠΈ ΠΌΠ΅ΡΠΎΠ΄ΠΎΠΌ Π³Π°Π·ΠΎ-ΠΆΠΈΠ΄ΠΊΠΎΡΡΠ½ΠΎΠΉ Ρ
ΡΠΎΠΌΠ°ΡΠΎΠ³ΡΠ°ΡΠΈΠΈ Ρ ΠΏΠ»Π°ΠΌΠ΅Π½Π½ΠΎ-ΠΈΠΎΠ½ΠΈΠ·Π°ΡΠΈΠΎΠ½Π½ΡΠΌ Π΄Π΅ΡΠ΅ΠΊΡΠΎΡΠΎΠΌ.Π Π΅Π·ΡΠ»ΡΡΠ°ΡΡ. ΠΠΎΠΊΠ°Π·Π°Π½Π° Π²ΠΎΠ·ΠΌΠΎΠΆΠ½ΠΎΡΡΡ ΡΠΎΠ²ΠΌΠ΅ΡΠ΅Π½ΠΈΡ Π² ΠΎΠ΄Π½ΠΎΠΌ ΡΠ΅Π°ΠΊΡΠΎΡΠ΅ Π΄Π΅Π³ΠΈΠ΄ΡΠ°ΡΠ°ΡΠΈΠΈ ΡΠΈΠΊΠ»ΠΎΠ³Π΅ΠΊΡΠ°Π½ΠΎΠ»Π°, ΠΊΠ°ΡΠ°Π»ΠΈΠ·ΠΈΡΡΠ΅ΠΌΠΎΠΉ ΠΌΠΎΠ½ΠΎΠ³ΠΈΠ΄ΡΠ°ΡΠΎΠΌ ΠΏ-ΡΠΎΠ»ΡΠΎΠ»ΡΡΠ»ΡΡΠΎΠΊΠΈΡΠ»ΠΎΡΡ, ΠΈ Π°Π»ΠΊΠΎΠΊΡΠΈΠΊΠ°ΡΠ±ΠΎΠ½ΠΈΠ»ΠΈΡΠΎΠ²Π°Π½ΠΈΡ ΠΎΠ±ΡΠ°Π·ΡΡΡΠ΅Π³ΠΎΡΡ ΡΠΈΠΊΠ»ΠΎΠ³Π΅ΠΊΡΠ΅Π½Π° ΡΠΈΠΊΠ»ΠΎΠ³Π΅ΠΊΡΠ°Π½ΠΎΠ»ΠΎΠΌ ΠΈ Π‘Π ΠΏΡΠΈ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π΅ ΡΠΈΡΡΠ΅ΠΌΠΎΠΉ Pd(OAc)2βPPh3βΠΏ-ΡΠΎΠ»ΡΠΎΠ»ΡΡΠ»ΡΡΠΎΠΊΠΈΡΠ»ΠΎΡΠ°. Π ΠΌΡΠ³ΠΊΠΈΡ
ΡΡΠ»ΠΎΠ²ΠΈΡΡ
(ΡΠ΅ΠΌΠΏΠ΅ΡΠ°ΡΡΡΠ° 110 Β°Π‘, Π΄Π°Π²Π»Π΅Π½ΠΈΠ΅ Π‘Π 2.1 ΠΠΠ°) Π²ΡΡ
ΠΎΠ΄ ΡΠ΅Π»Π΅Π²ΠΎΠ³ΠΎ ΠΏΡΠΎΠ΄ΡΠΊΡΠ° Π΄ΠΎΡΡΠΈΠ³Π°Π» 64.8% Π·Π° 5 Ρ. Π£ΡΡΠ°Π½ΠΎΠ²Π»Π΅Π½ΠΎ, ΡΡΠΎ ΡΠΎΠ²ΠΌΠ΅ΡΠ΅Π½Π½ΡΠΉ ΠΏΡΠΎΡΠ΅ΡΡ ΠΎΡΠ»ΠΎΠΆΠ½ΡΠ΅ΡΡΡ ΠΎΠ±ΡΠ°Π·ΠΎΠ²Π°Π½ΠΈΠ΅ΠΌ ΠΏΠΎΠ±ΠΎΡΠ½ΠΎΠ³ΠΎ ΠΏΡΠΎΠ΄ΡΠΊΡΠ° β ΡΠΈΠΊΠ»ΠΎΠ³Π΅ΠΊΡΠ°Π½ΠΊΠ°ΡΠ±ΠΎΠ½ΠΎΠ²ΠΎΠΉ ΠΊΠΈΡΠ»ΠΎΡΡ β Π² ΡΠ΅Π·ΡΠ»ΡΡΠ°ΡΠ΅ Π³ΠΈΠ΄ΡΠΎΠ»ΠΈΠ·Π° ΡΠΈΠΊΠ»ΠΎΠ³Π΅ΠΊΡΠΈΠ»ΠΎΠ²ΠΎΠ³ΠΎ ΡΡΠΈΡΠ° ΡΠΈΠΊΠ»ΠΎΠ³Π΅ΠΊΡΠ°Π½ΠΊΠ°ΡΠ±ΠΎΠ½ΠΎΠ²ΠΎΠΉ ΠΊΠΈΡΠ»ΠΎΡΡ ΠΈ Π³ΠΈΠ΄ΡΠΎΠΊΡΠΈΠΊΠ°ΡΠ±ΠΎΠ½ΠΈΠ»ΠΈΡΠΎΠ²Π°Π½ΠΈΡ ΡΠΈΠΊΠ»ΠΎΠ³Π΅ΠΊΡΠ΅Π½Π°
Methodology for Estimating the Expected Cost of Engineering and Technology Innovation
The article proposes a methodology for estimating the expected cost of technical and technological innovations. The evaluation is performed in the pre-design phase of the innovation (project initiation phase). It relies on the method of analogy and is implemented based on the principle of βso was - so will be.β At the same time, the available analogues provide objective information about βhow it was.β Extending this data into the future to estimate the cost of design relies on probabilistic interpretation of the available uncertainty. Uncertainty removal is accomplished using the principle of maximum entropy. This ensures the most complete consideration of the available objective information and minimizes speculation in assessing the cost of designing innovative objects. In general, the methodology proposed in the article allows obtaining objective estimates of the expected cost of designing technical and technological innovations in the standard information situation for the initiation stage of the project
Benefits Analysis of Wind-Optimal Operations For Trans-Atlantic Flights
North Atlantic Tracks are trans-Atlantic routes across the busiest oceanic airspace in the world. This study analyzes and compares current flight-plan routes to wind-optimal routes for trans-Atlantic flights in terms of aircraft fuel burn, emissions and the associated climate impact. The historical flight track data recorded by EUROCONTROL's Central Flow Management Unit is merged with data from FAA's Enhanced Traffic Management System to provide an accurate flight movement database containing the highest available flight path resolution in both systems. The combined database is adopted for airspace simulation integrated with aircraft fuel burn and emissions models, contrail models, simplified climate response models, and a common climate metric to assess the climate impact of flight routes within the Organized Track System (OTS). The fuel burn and emissions for the tracks in the OTS are compared with the corresponding quantities for the wind-optimized routes to evaluate the potential environmental benefits of flying wind-optimal routes in North Atlantic Airspace. The potential fuel savings and reduction in emissions depend on existing inefficiencies in current flight plans, atmospheric conditions and location of the city-pairs. The potential benefits are scaled by comparing them with actual flight tests that have been conducted since 2010 between a few city-pairs in the transatlantic and trans-pacific region to improve fuel consumption and reduce the environmental impact of aviation
Model and Method of Calendar Planning of Logistic Processes of Enterprises of Agricultural Complex
A model and method for the formation of optimal calendar plans for the organization of logisticsΒ processes for the functioning of enterprises of the agro-industrial complex have been developed.Β The model is based on the presentation of the procedure for the formation of an optimal calendarΒ plan in the form of a discrete programming problem. The optimization method is based on theΒ procedure of branches and boundaries. The proposed model and method are the basis for creatingΒ specific methods for the formation of optimal calendar plans for the organization of logisticalΒ processes of the functioning of the agro industrial complex
Effect of Silicon Content on Carbide Precipitation and Low-Temperature Toughness of Pressure Vessel Steels
Cr β Mn β Mo β Ni pressure vessel steels containing 0.54 and 1.55% Si are studied. Metallographic and fractographic analyses of the steels after tempering at 650 and 700Β°C are performed. The impact toughness at β 30Β°C and the hardness of the steels are determined. The mass fraction of the carbide phase in the steels is computed with the help of the J-MatPro 4.0 software
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