A model for orientation effects in electron‐transfer reactions

A method for solving the single‐particle Schrödinger equation with an oblate spheroidal potential of finite depth is presented. The wave functions are then used to calculate the matrix element T_BA which appears in theories of nonadiabatic electron transfer. The results illustrate the effects of mutual orientation and separation of the two centers on TBA. Trends in these results are discussed in terms of geometrical and nodal structure effects. Analytical expressions related to T_BA for states of spherical wells are presented and used to analyze the nodal structure effects for T_BA for the spheroidal wells

Solidification processing of alloys using an applied electric field

A method is provided for obtaining an alloy having an ordered microstructure which comprises the steps of heating the central portion of the alloy under uniform temperature so that it enters a liquid phase while the outer portions remain solid, applying a constant electric current through the alloy during the heating step, and solidifying the liquid central portion of the alloy by subjecting it to a temperature-gradient zone so that cooling occurs in a directional manner and at a given rate of speed while maintaining the application of the constant electric current through the alloy. The method of the present invention produces an alloy having superior characteristics such as reduced segregation. After subsequent precipitation by heat-treatment, the alloys produced by the present invention will have excellent strength and high-temperature resistance

Development of a Transition Between an Energy-Absorbing Concrete Barrier and a Rigid Concrete Butress

From 2010 to 2015, MwRSF researchers developed the RESTORE barrier, which is a restorable MASH TL-4 median barrier with a steel and concrete rail supported by elastomer posts and steel skids. The research effort reported herein describes the initial development of a transition from the RESTORE barrier to a rigid TL-4 concrete buttress. The previously-developed RESTORE barrier LS-DYNA model was validated against three full-scale vehicle crash tests. Several design concepts were generated through a series of brainstorming efforts. The primary transition concept consisted of a pin and loop connection between the RESTORE barrier and rigid concrete buttress, which was designed and evaluated with LS-DYNA computer simulation. Vehicle and system behavior were investigated using MASH test designation nos. 4-20, 4-21, and 4-22. Six horizontal gusset plates and drop-down pin allowed for limited deflection and rotation at the transition joint, but provided shear continuity between the two systems. A rounded-edge cover plate mitigated vehicle snag on the transition joint hardware. Eleven impact points were evaluated with each vehicle model to determine critical impact points for use in a future full-scale crash testing program. All occupant risk measures and vehicle stability were within MASH limits. Further design modifications are recommended to limit stresses in the transition joint hardware and to reduce excessive occupant compartment deformation that occurred when the small car impacted the concrete buttress end

Development of a Transition Between an Energy-Absorbing Concrete Barrier and a Rigid Concrete Butress

From 2010 to 2015, MwRSF researchers developed the RESTORE barrier, which is a restorable MASH TL-4 median barrier with a steel and concrete rail supported by elastomer posts and steel skids. The research effort reported herein describes the initial development of a transition from the RESTORE barrier to a rigid TL-4 concrete buttress. The previously-developed RESTORE barrier LS-DYNA model was validated against three full-scale vehicle crash tests. Several design concepts were generated through a series of brainstorming efforts. The primary transition concept consisted of a pin and loop connection between the RESTORE barrier and rigid concrete buttress, which was designed and evaluated with LS-DYNA computer simulation. Vehicle and system behavior were investigated using MASH test designation nos. 4-20, 4-21, and 4-22. Six horizontal gusset plates and drop-down pin allowed for limited deflection and rotation at the transition joint, but provided shear continuity between the two systems. A rounded-edge cover plate mitigated vehicle snag on the transition joint hardware. Eleven impact points were evaluated with each vehicle model to determine critical impact points for use in a future full-scale crash testing program. All occupant risk measures and vehicle stability were within MASH limits. Further design modifications are recommended to limit stresses in the transition joint hardware and to reduce excessive occupant compartment deformation that occurred when the small car impacted the concrete buttress end

MASH TL-4 Design and Evaluation of A Restorable Energy-Absorbing Concrete Barrier

A new, high-containment longitudinal barrier was designed to reduce the accelerations imparted to passenger vehicles during impacts and to be restorable and reusable. Elastomer support posts were designed to translate laterally and absorb energy when impacted and restore to their initial position after impact events. A hybrid concrete beam and steel tube combination rail was optimized to minimize weight, provide sufficient structural capacity, maintain a height to contain and redirect single-unit trucks, and to prevent passenger vehicles from snagging on the posts. Three full-scale vehicle crash tests were conducted according to Manual for Assessing Safety Hardware (MASH) Test Level (TL-4) safety performance requirements on a 240-ft long barrier with nominal height of 38⅝ in. In test SFH-1, a 5,021-lb pickup truck was redirected with minimal damage to the barrier. The peak lateral acceleration was reduced 47 percent as compared to similar impacts on rigid barriers. In test SFH-2, a 2,406-lb small car was redirected by the barrier, and the peak lateral acceleration was reduced 21 percent as compared to similar impacts on rigid barriers. In test SFH-3, a 21,746-lb single-unit truck was successfully contained and redirected, resulting in only minor damage to the concrete rail. Therefore, the barrier met all MASH TL-4 safety performance criteria. Recommendations about the performance, future design refinements, and installation requirements of the barrier were provided

Development of a Transition Between an Energy-Absorbing Concrete Barrier and a Rigid Concrete Butress

From 2010 to 2015, MwRSF researchers developed the RESTORE barrier, which is a restorable MASH TL-4 median barrier with a steel and concrete rail supported by elastomer posts and steel skids. The research effort reported herein describes the initial development of a transition from the RESTORE barrier to a rigid TL-4 concrete buttress. The previously-developed RESTORE barrier LS-DYNA model was validated against three full-scale vehicle crash tests. Several design concepts were generated through a series of brainstorming efforts. The primary transition concept consisted of a pin and loop connection between the RESTORE barrier and rigid concrete buttress, which was designed and evaluated with LS-DYNA computer simulation. Vehicle and system behavior were investigated using MASH test designation nos. 4-20, 4-21, and 4-22. Six horizontal gusset plates and drop-down pin allowed for limited deflection and rotation at the transition joint, but provided shear continuity between the two systems. A rounded-edge cover plate mitigated vehicle snag on the transition joint hardware. Eleven impact points were evaluated with each vehicle model to determine critical impact points for use in a future full-scale crash testing program. All occupant risk measures and vehicle stability were within MASH limits. Further design modifications are recommended to limit stresses in the transition joint hardware and to reduce excessive occupant compartment deformation that occurred when the small car impacted the concrete buttress end

Continued Development of a Non-Proprietary, High-Tension, Cable End Terminal System

A non-proprietary, cable guardrail system is currently under development for the Midwest States Pooled Fund Program. A cable guardrail end terminal was necessary to accompany the cable guardrail system. The objective of this research project was to develop design recommendations for the cable end terminal. Bogie testing that was previously completed on a design concept indicated delayed cable release, which was an undesired performance that led to vehicle instabilities. Several design changes were recommended for better end terminal performance and to reflect the changes made to the cable median barrier. An LS-DYNA model of the modified cable end terminal was developed. Simulations of 0- and 15-degree impacts on the end of the cable anchor bracket with a bogie model indicated that the cables would release easily and not induce vehicle instabilities. This behavior still needs to be verified through bogie and full-scale crash testing. Simulations of a 25-degree reverse impact between post nos. 2 and 3 with small car models indicated that cables did not release easily and may interlock around the car resulting in excessive vehicle decelerations or instabilities. Simulations of various line post designs found that the MWP and weakened MWP have lower forces and energies during impact than the S3x5.7 posts used in previous three-cable end terminals. This finding would suggest improved performance with respect to vehicle override and instability. However, vehicle simulations with multiple line posts impacted were inconclusive. Further design modifications, evaluation, and testing are recommended

Continued Development of a Non-Proprietary, High-Tension, Cable End Terminal System

A non-proprietary, cable guardrail system is currently under development for the Midwest States Pooled Fund Program. A cable guardrail end terminal was necessary to accompany the cable guardrail system. The objective of this research project was to develop design recommendations for the cable end terminal. Bogie testing that was previously completed on a design concept indicated delayed cable release, which was an undesired performance that led to vehicle instabilities. Several design changes were recommended for better end terminal performance and to reflect the changes made to the cable median barrier. An LS-DYNA model of the modified cable end terminal was developed. Simulations of 0- and 15-degree impacts on the end of the cable anchor bracket with a bogie model indicated that the cables would release easily and not induce vehicle instabilities. This behavior still needs to be verified through bogie and full-scale crash testing. Simulations of a 25-degree reverse impact between post nos. 2 and 3 with small car models indicated that cables did not release easily and may interlock around the car resulting in excessive vehicle decelerations or instabilities. Simulations of various line post designs found that the MWP and weakened MWP have lower forces and energies during impact than the S3x5.7 posts used in previous three-cable end terminals. This finding would suggest improved performance with respect to vehicle override and instability. However, vehicle simulations with multiple line posts impacted were inconclusive. Further design modifications, evaluation, and testing are recommended

Combined macro- and micro-rheometer for use with Langmuir monolayers

A Langmuir monolayer trough that is equipped for simultaneous microrheology and standard rheology measurements has been constructed. The central elements are the trough itself with a full range of optical tools accessing the air-water interface from below the trough and a portable knife-edge torsion pendulum that can access the interface from above. The ability to simultaneously measure the mechanical response of Langmuir monolayers on very different lengths scales is an important step in for our understanding of the mechanical response of such systems