6 research outputs found
1,2-Di-2-quinolylethene
The title compound, C20H14N2, comprises two crystallographically independent centrosymmetric molecules (A and B) with different conformations due to the disorder of molecule B. The whole of molecule B is disordered over two sets of positions, corresponding to a 180° rotation of the molecule, with a site-occupancy ratio of 0.780 (6):0.220 (6). The minor component of the disordered part in B has the same configuration as molecule A, but the major component is different. The dihedral angle between the planes of molecule A and molecule B (major component) is 63.22 (3)°. The crystal structure is stabilized by intermolecular C—H⋯π interactions
2-(7-Hydroxy-2-naphthyloxy)-N-(6-methyl-2-pyridyl)acetamide
In the title compound, C18H16N2O3, the dihedral angle between the naphthalene ring system and the pyridyl ring is 18.1 (8)°. The molecules are interconnected via C—H⋯O and O—H⋯O hydrogen bonds. Inversion-related molecules are linked by O—H⋯O hydrogen bonds into cyclic centrosymmetric R
2
2(22) dimers. Intramolecular N—H⋯O hydrogen bonding produces an S(5) ring motif. The crystal structure is further stabilized by weak C—H—π interactions
N-[6-(Dibromomethyl)-2-pyridyl]-2,2-dimethylpropionamide
In the molecular structure of the title compound, C11H14Br2N2O, the dimethylpropionamide substituent is twisted slightly with respect to the pyridine ring, the interplanar angle being 12.3 (2)°. The dibromomethyl group is orientated in such a way that the two Br atoms are tilted away from the pyridine ring. In the crystal structure, molecules are associated into supramolecular chains by weak C—H⋯O interactions. The crystal is further stabilized by weak N—H⋯Br and C—H⋯N interactions