Dust Deposition to the Bermuda Region: A Comparison of Estimates Using Seasonally-resolved Measurements of Aluminum in Water-column, Aerosol, and Rain Samples

Dust deposition is a major source of bioactive trace elements to the surface ocean, yet this flux remains difficult to constrain. Previously, time-averaged dust flux has been estimated using surface ocean dissolved aluminum (DAl) concentrations, assumed values for aerosol aluminum solubility (%AlS), and the residence time of DAl in the surface mixed layer (SML). We apply this method to estimate dust deposition in the Bermuda Atlantic Time-series Study (BATS) region using water-column DAl data from cruises in 2019, which is compared with direct flux estimates from contemporaneous measurements of aluminum in aerosols and rain collected on Bermuda. Seasonal DAl inventories over the upper 200 m (our observed maximum SML depth) yield flux estimates that follow the expected seasonality of dust deposition in Bermuda, with ranges of 9.9-13 g/m2/y and 4.7-6.1 g/m2/y, using %AlS values derived from aerosol leaches using ultrapure water and 25% acetic acid, respectively. These values are ~5-10 times higher than our estimates based on aluminum in aerosols and rain, which average ~1.18 g/m2/y over our 318 day sampling period and are in accord with previous estimates of dust deposition at Bermuda. This discrepancy may reflect uncertainties in aerosol deposition velocity (assumed 1 cm/s), lateral advection of DAl in the region (assumed negligible), and, most likely, the residence time of DAl in the upper water column (assumed 5 years). The two different estimates can be brought into agreement if the residence time of DAl in the upper 200 m is increased to ~49 years or ~23 years, for %AlS values estimated by leaching aerosols with ultrapure water or 25% acetic acid, respectively. Such residence times for DAl in the upper 200 m are greater than a recent estimate for the North Atlantic based on thorium supply but appear compatible with values extracted from a recent data-assimilation modeling study.https://digitalcommons.odu.edu/gradposters2023_sciences/1000/thumbnail.jp

Submarine Magmatic-Hydrothermal Systems at the Monowai Volcanic Centre, Kermadec Arc

Authors listed on this Accepted Manuscript vary slightly from those listed on the Version of Record. Harold L. Gibson is an additional author on the published version.The Monowai volcanic centre (MVC) is located at the mid-point along the ~2530 km long Tonga-Kermadec arc system, is probably the most hydrothermally active submarine volcanic system globally. The MVC is comprised of a large elongate caldera (Monowai caldera, 7.9 x 5.7 km; 35 km²; depth to caldera floor is 1590 m), which has formed within an older caldera some 84 km² in area. To the south of the nested caldera system is a large composite volcano, Monowai cone, which rises to within ~ 100 m of the sea surface and has been volcanically active for at least several decades. Despite the large size, mafic volcanic rocks dominate the MVC; basalts are the most common rock type recovered; less common are basaltic andesites and andesites. Hydrothermal plume mapping during the 2004 NZAPLUME III cruise showed at least three major hydrothermal systems associated with the caldera and cone. Monowai cone has hydrothermal venting from the summit. This summit plume is gas-rich and acidic; plume samples show a pH shift of -2.00 pH units, δ³He up to 358 ‰, H₂S concentrations up to 32 μM and CH₄ concentrations up to 900 nM. The summit plume is also metal-rich with elevated total dissolvable Fe (TDFe up to 4200 nM), TDMn (up to 412 nM), and TDFe/TDMn (up to 20.4). Monowai caldera has a major hydrothermal vent system with plumes extending from ~ 1000 to 1400 m depth. The caldera plume has lower values for TDFe, although ranges to higher TDMn concentrations than the summit plume, and is relatively gas-poor (no H₂S detected, pH shift of -0.06 pH units, CH₄ concentrations up to 26 nM). Hydrothermal vents have been observed associated with prominent basaltic andesite ridges (Mussel Ridge) proximal to the southwest wall of the caldera (1025 – 1171 m depth). However, the composition of the hydrothermal plumes in the caldera are different to the vents, indicating that the source of the caldera plumes is at greater depth and is more metal-rich and therefore likely higher temperature. Minor plumes detected as light scattering anomalies down the northern flank of Monowai caldera most likely represent resuspension of volcanic debris. Particulate samples from both the cone sites and the caldera site are enriched in Al, Ti, Ca, Mg, Si, and S, with the cone summit plume especially enriched in K, As, W and Cu, Pb, Zn. The elevated Ti and Al suggest acidic water-rock reactions and intense high-sulfidation alteration of the host volcanic rocks. Observations from submersible dives with Pisces V in 2005 and the remotely operated vehicle ROPOS in 2007 of Mussel Ridge indicate numerous low temperature vents (< 60°C), with a large biomass of vent-associated fauna, in particular large accumulations of the mussel Bathymodiolus sp. and the tubeworm Lamellibrachia sp. We interpret the Monowai volcanic centre as possessing a robust high-sulfidation magmatic-hydrothermal system, with significant differences in the style and composition of venting at the cone and caldera sites. At Monowai cone, the large shifts in pH, elevated TDFe and TDFe/TDMn, and H₂S-, CH₄- and ³He-rich nature of the plume fluids coupled with elevated Ti, P, V, S and Al in the particulates indicates significant magmatic volatile ± metal contributions to the hydrothermal system and aggressive acidic water-rock interaction. By contrast, Monowai caldera has low TDFe/TDMn in hydrothermal plumes; however, end-member vent fluid compositions, combined with presence of alunite, sulfide minerals and native sulfur in samples from Mussel Ridge suggest recent acid volatile-rich venting and active Fe-sulfide formation in the subsurface, and the potential for the presence of significant SMS mineralization

Tectonic/volcanic Segmentation and Controls on Hydrothermal Venting Along Earth\u27s Fastest Seafloor Spreading System, EPR 27°–32°S

We have collected 12 kHz SeaBeam bathymetry and 120 kHz DSL-120 side-scan sonar and bathymetry data to determine the tectonic and volcanic segmentation along the fastest spreading (∼150 km/Myr) part of the global mid-ocean ridge system, the southern East Pacific Rise between the Easter and Juan Fernandez microplates. This area is presently reorganizing by large-scale dueling rift propagation and possible protomicroplate tectonics. Fracture patterns observed in the side-scan data define structural segmentation scales along these ridge segments. These sometimes, but not always, correlate with linear volcanic systems defining segmentation in the SeaBeam data. Some of the subsegments behave cohesively, with in-phase tectonic activity, while fundamental discontinuities occur between other subsegments. We also collected hydrothermal plume data using sensors mounted on the DSL-120 instrument package, as well as CTDO tow-yos, to determine detailed structural and volcanic controls on the hydrothermal vent pattern observed along 600 km of the Pacific-Nazca axis. Here we report the first rigorous correlation between coregistered hydrothermal plume and high-resolution marine geophysical data on similar scales and over multisegment distances. Major plume concentrations were usually found where axial inflation was relatively high and fracture density was relatively low. These correlations suggest that hydrothermal venting is most active where the apparent magmatic budget is greatest, resulting in recent eruptions that have paved over the neovolcanic zone. Areas of voluminous acoustically dark young lava flows produced from recent fissure eruptions correlate with many of the major hydrothermal vent areas. Increased crustal permeability, as gauged by increased fracture density, does not enhance hydrothermal venting in this area. Axial summit troughs and graben are rare, probably because of frequent volcanic resurfacing in this superfast spreading environment, and are not good predictors of hydrothermal activity here. Many of the hydrothermal areas are found in inflated areas near the ends of segments, suggesting that abundant magma is being supplied to these areas

Tectonic/volcanic Segmentation and Controls on Hydrothermal Venting Along Earth\u27s Fastest Seafloor Spreading System, EPR 27°–32°S

We have collected 12 kHz SeaBeam bathymetry and 120 kHz DSL-120 side-scan sonar and bathymetry data to determine the tectonic and volcanic segmentation along the fastest spreading (∼150 km/Myr) part of the global mid-ocean ridge system, the southern East Pacific Rise between the Easter and Juan Fernandez microplates. This area is presently reorganizing by large-scale dueling rift propagation and possible protomicroplate tectonics. Fracture patterns observed in the side-scan data define structural segmentation scales along these ridge segments. These sometimes, but not always, correlate with linear volcanic systems defining segmentation in the SeaBeam data. Some of the subsegments behave cohesively, with in-phase tectonic activity, while fundamental discontinuities occur between other subsegments. We also collected hydrothermal plume data using sensors mounted on the DSL-120 instrument package, as well as CTDO tow-yos, to determine detailed structural and volcanic controls on the hydrothermal vent pattern observed along 600 km of the Pacific-Nazca axis. Here we report the first rigorous correlation between coregistered hydrothermal plume and high-resolution marine geophysical data on similar scales and over multisegment distances. Major plume concentrations were usually found where axial inflation was relatively high and fracture density was relatively low. These correlations suggest that hydrothermal venting is most active where the apparent magmatic budget is greatest, resulting in recent eruptions that have paved over the neovolcanic zone. Areas of voluminous acoustically dark young lava flows produced from recent fissure eruptions correlate with many of the major hydrothermal vent areas. Increased crustal permeability, as gauged by increased fracture density, does not enhance hydrothermal venting in this area. Axial summit troughs and graben are rare, probably because of frequent volcanic resurfacing in this superfast spreading environment, and are not good predictors of hydrothermal activity here. Many of the hydrothermal areas are found in inflated areas near the ends of segments, suggesting that abundant magma is being supplied to these areas