Design, construction, and testing of an accurate low-cost humidistat for laboratory-scale applications

Stable and precise control of humidity is imperative for a wide variety of experiments. However, commercially available humidistats (devices that maintain a constant humidity) are often prohibitively expensive. Here, we present a simple yet effective humidistat for laboratory-scale applications that can be easily and affordably (<€250) constructed based on an Arduino Uno as microcontroller, a set of proportional miniature solenoid valves, a gas washing bottle, and a humidity sensor. The microcontroller implements a PID controller that regulates the ratio of a dry and humid airflow. The design and implementation of the device, including a custom driver circuit for the solenoids, are described in detail, and the firmware is freely available online. Finally, we demonstrate its proper operation and performance through step response and long-term stability tests, which shows settling times of approx. 30 s and an attainable relative humidity range of 10–95

Design and validation of a low-cost open-source impedance based quartz crystal microbalance for electrochemical research

The quartz crystal microbalance (QCM) measurement technique is utilized in a broad variety of scientific fields and applications, where surface and interfacial processes are relevant. However, the costs of purchasing QCMs is typically high, which has limited its employment in education as well as by scientists in developing countries. In this article, we present an open-source QCM, built on the OpenQCM project, and using an impedance-based measurement technique (QCM-I), which can be built for <200 euro. Our QCM allows for simultaneous monitoring of the frequency change and dissipation, such that both soft and rigid materials can be characterized. In addition, our QCM measurements can be combined with simultaneous electrochemical measurement techniques (EQCM-I). We demonstrate the validity of our system by characterizing the electrodeposition of a rigid metallic film (Cu) and by the electropolymerization of aniline. Finally, we discuss potential improvements to our system

Swelling of Poly(methyl acrylate) Brushes in Acetone Vapor

Sensor platforms can benefit from the incorporation of polymer brushes since brushes can concentrate the analyte near the sensor surface. Brushes that absorb acetone vapor are of particular interest since acetone is an important marker for biological processes. We present a simple procedure to synthesize acetone-responsive poly(methyl acrylate) brushes. Using spectroscopic ellipsometry, we show that these brushes respond within seconds and swell by more than 30% when exposed to acetone vapor. Moreover, quartz crystal microbalance measurements demonstrate that the brushes can be exploited to increase the acetone detection sensitivity of sensors by more than a factor 6. Surprisingly, we find that the swelling ratio of the brushes in acetone vapor is independent of the grafting density and the degree of polymerization of the polymers in the brush. This is qualitatively different from swelling of the same brushes in liquid environments, where the swelling ratio decreases for increasing grafting densities. Yet, it indicates that the brushes are robust and reproducible candidates for implementation in vapor sensor systems