Scaling in the crossover from random to correlated growth

In systems where deposition rates are high compared to diffusion, desorption and other mechanisms that generate correlations, a crossover from random to correlated growth of surface roughness is expected at a characteristic time t_0. This crossover is analyzed in lattice models via scaling arguments, with support from simulation results presented here and in other authors works. We argue that the amplitudes of the saturation roughness and of the saturation time scale as {t_0}^{1/2} and t_0, respectively. For models with lateral aggregation, which typically are in the Kardar-Parisi-Zhang (KPZ) class, we show that t_0 ~ 1/p, where p is the probability of the correlated aggregation mechanism to take place. However, t_0 ~ 1/p^2 is obtained in solid-on-solid models with single particle deposition attempts. This group includes models in various universality classes, with numerical examples being provided in the Edwards-Wilkinson (EW), KPZ and Villain-Lai-Das Sarma (nonlinear molecular-beam epitaxy) classes. Most applications are for two-component models in which random deposition, with probability 1-p, competes with a correlated aggregation process with probability p. However, our approach can be extended to other systems with the same crossover, such as the generalized restricted solid-on-solid model with maximum height difference S, for large S. Moreover, the scaling approach applies to all dimensions. In the particular case of one-dimensional KPZ processes with this crossover, we show that t_0 ~ nu^{-1} and nu ~ lambda^{2/3}, where nu and lambda are the coefficients of the linear and nonlinear terms of the associated KPZ equations. The applicability of previous results on models in the EW and KPZ classes is discussed.Comment: 14 pages + 5 figures, minor changes, version accepted in Phys. Rev.

Phase transitions and crossovers in reaction-diffusion models with catalyst deactivation

The activity of catalytic materials is reduced during operation by several mechanisms, one of them being poisoning of catalytic sites by chemisorbed impurities or products. Here we study the effects of poisoning in two reaction-diffusion models in one-dimensional lattices with randomly distributed catalytic sites. Unimolecular and bimolecular single-species reactions are considered, without reactant input during the operation. The models show transitions between a phase with continuous decay of reactant concentration and a phase with asymptotic non-zero reactant concentration and complete poisoning of the catalyst. The transition boundary depends on the initial reactant and catalyst concentrations and on the poisoning probability. The critical system behaves as in the two-species annihilation reaction, with reactant concentration decaying as t^{-1/4} and the catalytic sites playing the role of the second species. In the unimolecular reaction, a significant crossover to the asymptotic scaling is observed even when one of those parameters is 10% far from criticality. Consequently, an effective power-law decay of concentration may persist up to long times and lead to an apparent change in the reaction kinetics. In the bimolecular single-species reaction, the critical scaling is followed by a two-dimensional rapid decay, thus two crossovers are found.Comment: 8 pages, 7 figure

Non-Local Product Rules for Percolation

Despite original claims of a first-order transition in the product rule model proposed by Achlioptas et al. [Science 323, 1453 (2009)], recent studies indicate that this percolation model, in fact, displays a continuous transition. The distinctive scaling properties of the model at criticality, however, strongly suggest that it should belong to a different universality class than ordinary percolation. Here we introduce a generalization of the product rule that reveals the effect of non-locality on the critical behavior of the percolation process. Precisely, pairs of unoccupied bonds are chosen according to a probability that decays as a power-law of their Manhattan distance, and only that bond connecting clusters whose product of their sizes is the smallest, becomes occupied. Interestingly, our results for two-dimensional lattices at criticality shows that the power-law exponent of the product rule has a significant influence on the finite-size scaling exponents for the spanning cluster, the conducting backbone, and the cutting bonds of the system. In all three cases, we observe a continuous variation from ordinary to (non-local) explosive percolation exponents.Comment: 5 pages, 4 figure

How dense can one pack spheres of arbitrary size distribution?

We present the first systematic algorithm to estimate the maximum packing density of spheres when the grain sizes are drawn from an arbitrary size distribution. With an Apollonian filling rule, we implement our technique for disks in 2d and spheres in 3d. As expected, the densest packing is achieved with power-law size distributions. We also test the method on homogeneous and on empirical real distributions, and we propose a scheme to obtain experimentally accessible distributions of grain sizes with low porosity. Our method should be helpful in the development of ultra-strong ceramics and high performance concrete.Comment: 5 pages, 5 figure

Quantum Evolution of Inhomogeneities in Curved Space

We obtain the renormalized equations of motion for matter and semi-classical gravity in an inhomogeneous space-time. We use the functional Schrodinger picture and a simple Gaussian approximation to analyze the time evolution of the $\lambda\phi^4$ model, and we establish the renormalizability of this non-perturbative approximation. We also show that the energy-momentum tensor in this approximation is finite once we consider the usual mass and coupling constant renormalizations, without the need of further geometrical counter-terms.Comment: 22 page

Experimental determination of the non-extensive entropic parameter qq

We show how to extract the $q$ parameter from experimental data, considering an inhomogeneous magnetic system composed by many Maxwell-Boltzmann homogeneous parts, which after integration over the whole system recover the Tsallis non-extensivity. Analyzing the cluster distribution of La$_{0.7}$Sr$_{0.3}$MnO$_{3}$ manganite, obtained through scanning tunnelling spectroscopy, we measure the $q$ parameter and predict the bulk magnetization with good accuracy. The connection between the Griffiths phase and non-extensivity is also considered. We conclude that the entropic parameter embodies information about the dynamics, the key role to describe complex systems.Comment: Submitted to Phys. Rev. Let