12,403 research outputs found
Chirality distribution and transition energies of carbon nanotubes
From resonant Raman scattering on isolated nanotubes we obtained the optical
transition energies, the radial breathing mode frequency and Raman intensity of
both metallic and semiconducting tubes. We unambiguously assigned the chiral
index (n_1,n_2) of approximately 50 nanotubes based solely on a third-neighbor
tight-binding Kataura plot and find omega_RBM=214.4cm^-1nm/d+18.7cm^-1. In
contrast to luminescence experiments we observe all chiralities including
zig-zag tubes. The Raman intensities have a systematic chiral-angle dependence
confirming recent ab-initio calculations.Comment: 4 pages, to be published in Phys. Rev. Let
Structure and formation energy of carbon nanotube caps
We present a detailed study of the geometry, structure and energetics of
carbon nanotube caps. We show that the structure of a cap uniquely determines
the chirality of the nanotube that can be attached to it. The structure of the
cap is specified in a geometrical way by defining the position of six pentagons
on a hexagonal lattice. Moving one (or more) pentagons systematically creates
caps for other nanotube chiralities. For the example of the (10,0) tube we
study the formation energy of different nanotube caps using ab-initio
calculations. The caps with isolated pentagons have an average formation energy
0.29+/-0.01eV/atom. A pair of adjacent pentagons requires a much larger
formation energy of 1.5eV. We show that the formation energy of adjacent
pentagon pairs explains the diameter distribution in small-diameter nanotube
samples grown by chemical vapor deposition.Comment: 8 pages, 8 figures (gray scale only due to space); submitted to Phys.
Rev.
Wide-range optical studies on various single-walled carbon nanotubes: the origin of the low-energy gap
We present wide-range (3 meV - 6 eV) optical studies on freestanding
transparent carbon nanotube films, made from nanotubes with different diameter
distributions. In the far-infrared region, we found a low-energy gap in all
samples investigated. By a detailed analysis we determined the average
diameters of both the semiconducting and metallic species from the near
infrared/visible features of the spectra. Having thus established the
dependence of the gap value on the mean diameter, we find that the frequency of
the low energy gap is increasing with increasing curvature. Our results
strongly support the explanation of the low-frequency feature as arising from a
curvature-induced gap instead of effective medium effects. Comparing our
results with other theoretical and experimental low-energy gap values, we find
that optical measurements yield a systematically lower gap than tunneling
spectroscopy and DFT calculations, the difference increasing with decreasing
diameter. This difference can be assigned to electron-hole interactions.Comment: 9 pages, 8 figures, to be published in Physical Review B,
supplemental material attached v2: Figures 1, 7 and 8 replaced, minor changes
to text; v3: Figures 3, 4 and 5 replaced, minor changes to tex
Theory of double-resonant Raman spectra in graphene: intensity and line shape of defect-induced and two-phonon bands
We calculate the double resonant (DR) Raman spectrum of graphene, and
determine the lines associated to both phonon-defect processes, and two-phonons
ones. Phonon and electronic dispersions reproduce calculations based on density
functional theory corrected with GW. Electron-light, -phonon, and -defect
scattering matrix elements and the electronic linewidth are explicitly
calculated. Defect-induced processes are simulated by considering different
kind of idealized defects. For an excitation energy of eV, the
agreement with measurements is very good and calculations reproduce: the
relative intensities among phonon-defect or among two-phonon lines; the
measured small widths of the D, , 2D and lines; the line shapes; the
presence of small intensity lines in the 1800, 2000 cm range. We
determine how the spectra depend on the excitation energy, on the light
polarization, on the electronic linewidth, on the kind of defects and on their
concentration. According to the present findings, the intensity ratio between
the and 2D lines can be used to determine experimentally the electronic
linewidth. The intensity ratio between the and lines depends on the
kind of model defect, suggesting that this ratio could possibly be used to
identify the kind of defects present in actual samples. Charged impurities
outside the graphene plane provide an almost undetectable contribution to the
Raman signal
The phonon dispersion of graphite by inelastic x-ray scattering
We present the full in-plane phonon dispersion of graphite obtained from
inelastic x-ray scattering, including the optical and acoustic branches, as
well as the mid-frequency range between the and points in the Brillouin
zone, where experimental data have been unavailable so far. The existence of a
Kohn anomaly at the point is further supported. We fit a fifth-nearest
neighbour force-constants model to the experimental data, making improved
force-constants calculations of the phonon dispersion in both graphite and
carbon nanotubes available.Comment: 7 pages; submitted to Phys. Rev.
Exciton binding energies in carbon nanotubes from two-photon photoluminescence
One- and two-photon luminescence excitation spectroscopy showed a series of
distinct excitonic states in single-walled carbon nanotubes. The energy
splitting between one- and two-photon-active exciton states of different
wavefunction symmetry is the fingerprint of excitonic interactions in carbon
nanotubes. We determine exciton binding energies of 0.3-0.4 eV for different
nanotubes with diameters between 0.7 and 0.9 nm. Our results, which are
supported by ab-initio calculations of the linear and non-linear optical
spectra, prove that the elementary optical excitations of carbon nanotubes are
strongly Coulomb-correlated, quasi-one dimensionally confined electron-hole
pairs, stable even at room temperature. This alters our microscopic
understanding of both the electronic structure and the Coulomb interactions in
carbon nanotubes, and has direct impact on the optical and transport properties
of novel nanotube devices.Comment: 5 pages, 4 figure
The strength of the radial-breathing mode in single-walled carbon nanotubes
We show by ab initio calculations that the electron-phonon coupling matrix
element M of the radial breathing mode in single-walled carbon nanotubes
depends strongly on tube chirality. For nanotubes of the same diameter the
coupling strength |M|^2 is up to one order of magnitude stronger for zig-zag
than for armchair tubes. For (n,m) tubes M depends on the value of (n-m) mod 3,
which allows to discriminate semiconducting nano tubes with similar diameter by
their Raman scattering intensity. We show measured resonance Raman profiles of
the radial breathing mode which support our theoretical predictions
HI ``Tails'' from Cometary Globules in IC1396
IC 1396 is a relatively nearby (750 pc), large (>2 deg), HII region ionized
by a single O6.5V star and containing bright-rimmed cometary globules. We have
made the first arcmin resolution images of atomic hydrogen toward IC 1396, and
have found remarkable ``tail''-like structures associated with some of the
globules and extending up to 6.5 pc radially away from the central ionizing
star. These HI ``tails'' may be material which has been ablated from the
globule through ionization and/or photodissociation and then accelerated away
from the globule by the stellar wind, but which has since drifted into the
``shadow'' of the globules.
This report presents the first results of the Galactic Plane Survey Project
recently begun by the Dominion Radio Astrophysical Observatory.Comment: 11 pages, 5 postscript figures, uses aaspp4.sty macros, submitted in
uuencoded gzipped tar format, accepted for publication in Astrophysical
Journal Letters, colour figures available at
http://www.drao.nrc.ca/~schieven/news_sep95/ic1396.htm
Soft Null Hypotheses: A Case Study of Image Enhancement Detection in Brain Lesions
This work is motivated by a study of a population of multiple sclerosis (MS)
patients using dynamic contrast-enhanced magnetic resonance imaging (DCE-MRI)
to identify active brain lesions. At each visit, a contrast agent is
administered intravenously to a subject and a series of images is acquired to
reveal the location and activity of MS lesions within the brain. Our goal is to
identify and quantify lesion enhancement location at the subject level and
lesion enhancement patterns at the population level. With this example, we aim
to address the difficult problem of transforming a qualitative scientific null
hypothesis, such as "this voxel does not enhance", to a well-defined and
numerically testable null hypothesis based on existing data. We call the
procedure "soft null hypothesis" testing as opposed to the standard "hard null
hypothesis" testing. This problem is fundamentally different from: 1) testing
when a quantitative null hypothesis is given; 2) clustering using a mixture
distribution; or 3) identifying a reasonable threshold with a parametric null
assumption. We analyze a total of 20 subjects scanned at 63 visits (~30Gb), the
largest population of such clinical brain images
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