Processing double refractory gold-arsenic-bearing concentrates by direct reductive melting

Iron arsenides may be the key to extraction of gold from existing refractory ores such as that at Bakyrchik, Kazakhstan, an ore body containing an estimated £8.5 billion reserve of gold. Gold is not extractable without significant ecological contamination from the associate arsenopyrite mineralisation. A new method for gold recovery from refractory gold-arsenic-bearing materials, based on direct reductive melting (DRM) of the concentrate has been developed, which locks As into relatively benign iron arsenide phases, whilst gold is extracted into lead alloy. The method has been filed as a patent with the Patent Office of the Republic of Kazakhstan.Islamic Development Bank - Cambridge International Scholarship Programm

Deep carbon cycle through five reactions

What are the key reactions driving the global carbon cycle in Earth, the only known habitable planet in the solar system? And how do chemical reactions govern the transformation and movement of carbon? The special collection “Earth in five reactions - A deep carbon perspective” features review articles synthesizing knowledge and findings on the role of carbon- related reactions in Earth's dynamics and evolution. These integrative studies identify gaps in our current understanding and establish new frontiers to motivate and guide future research in deep carbon science. The collection also includes original experimental and theoretical investigations of carbon-bearing phases and the impact of chemical and polymorphic reactions on Earth's deep carbon cycle.Sloan Foundatio

Metamorphic temperature investigation of coexisting calcite and dolomite marble––examples from Nikani Ghar marble and Nowshera Formation, Peshawar Basin, Pakistan

Using marble samples from the Nikani Ghar marble and Nowshera Formation from Northern Pakistan the determination of the temperature of metamorphism was undertaken with the help of calcite-dolomite solvus geothermometer. Two types of marbles, that is, calcite-dolomite marble and quartz-bearing calcite-dolomite marble were selected. Petrographic and scanning electron microscope analysis of dolomite samples indicated different grain sizes. X-ray diffraction technique indicated the calcites MgCO₃ content up to 7.93 mol.%. Nikani Ghar marble samples have shown lower contents of MgCO₃ as compared to samples from Nowshera Formation. The calcite-dolomite-quartz marble has also showed relatively lower MgCO₃ content and hence rather low temperature (~500 °C). The temperature reached during peak metamorphism of the investigated marble occurrence, based on calcitedolomite solvus was 628 °C. Metamorphic temperatures derived from the present study were shown as a linear graph and values were in good agreement with the published literature.The authors acknowledge the financial support extended by the Higher Education Commission (HEC), Pakistan and National Academy of Sciences (USA), project ID 131, under the PAK-USA S & T Cooperation Program, Award (No. 0521315). The authors are grateful to the HEC, Pakistan for their support in the form of “International Research Support Initiative Program (IRSIP)” to conduct a part of research at Department of Earth Sciences, University of Cambridge, United 996 Muhammad Fahad, Yaseen Iqbal, Mohammad Riaz, Rick Ubic and Simon A. T. Redfern Kingdom. The financial support extended by the Directorate of S & T, KP regarding minerals upgradation is also acknowledged

Ternary hypervalent silicon hydrides via lithium at high pressure

Hydrogen is rarely observed as ligand in hypervalent species, however, we find that high-pressure hydrogenation may stabilise hypervalent hydrogen-rich materials. Focussing on ternary silicon hydrides via lithium doping, we find anions composed of hypervalent silicon with H ligands formed under high pressure. Our results reveal two new hypervalent anions: layered-SiH−5 and tricapped triangular prismatic SiH2−. These differ from octahedral SiH2− described in earlier studies. In addition, there are further hydrogen-rich structures, Li3SiH10 and Li2SiH6+δ, which may be stabilised at high pressure. Our work provides pointers to future investigations on hydrogen rich materials

The coordination and distribution of B in foraminiferal calcite

The isotopic ratio and concentration of B in foraminiferal calcite appear to reflect the pH and bicarbonate concentration of seawater. The use of B as a chemical proxy tracer has the potential to transform our understanding of the global carbon cycle, and ocean acidification processes. However, discrepancies between the theory underpinning the B proxies, and mineralogical observations of B coordination in biomineral carbonates call the basis of these proxies into question. Here, we use synchrotron X-ray spectromicroscopy to show that B is hosted solely as trigonal BO3 in the calcite test of Amphistegina lessonii, and that B concentration exhibits banding at the micron length scale. In contrast to previous results, our observation of trigonal B agrees with the predictions of the theoretical mechanism behind B palaeoproxies. These data strengthen the use of B for producing palaeo-pH records. The observation of systematic B heterogeneity, however, highlights the complexity of foraminiferal biomineralisation, implying that B incorporation is modulated by biological or crystal growth processes.We would like to acknowledge David Nicol, Iris Buisman and Martin Walker for invaluable technical assistance, and James Bryson for his help with synchrotron data collection. Wewould like to thank Jean DeMouthe (California Academy of Sciences) and Mike Rumsey (Natural History Museum, London) for provision of B-containing minerals for use as reference materials. This work was funded by ERC (grant 2010-ADG-267931 to HE), NERC, Jesus College (Cambridge)and the US Department of Energy (via ALS).This is the final published version. It first appeared at http://www.sciencedirect.com/science/article/pii/S0012821X15000849

Mineralogical and geochemical characteristics of triassic lithium-rich K-Bentonite deposits in Xiejiacao section, South China

Widespread alteration in the Early–Middle Triassic volcanic ash of the Xiejiacao section, south China, has resulted in significant occurrences of lithium-rich K-bentonite deposits with economic potential. Detailed mineralogical and geochemical investigations of Li-rich K-bentonite deposits from the Xiejiacao section of Guangan city, South China, are presented here. The X-ray diffraction (XRD) data and major element chemistry indicates that the Li-rich K-bentonite deposits contain quartz, clay minerals, feldspar, calcite and dolomite, and the clay minerals are dominated by illite and ordered (R3) illite/smectite (I/S). The concentrations of major and trace elements in Li-rich K-bentonite deposits altered from volcanic ashes are most likely derived from felsic magmas, associated with intense volcanic arc activity. The composition of the clay components suggests that the Li-rich K-bentonite deposits are probably altered from the smectite during diagenesis, whereas smectite is mainly formed by submarine alterations of volcanic materials and subsequently the I/S derived from the volcanogenic smectite illitization. Moreover, accurate determination of the structure in I/S reveals that the temperatures reached by the sedimentary series are around 180 °C with a burial depth of ~6000 m. The widely distributed lithium-rich clay deposits strongly indicate widespread eruptions of volcanic ashes in the Early–Middle Triassic, which released huge amounts of volcanic ash. Lithium fixed in the illite and I/S is considered to have leached from the volcanogenic products by a mixed fluid source (i.e., meteoric, porewater and hydrothermal fluids). These Li-rich clay minerals in the marine basin contain economically extractable levels of metal and are a promising new target for lithium exploration.</jats:p

The distribution and coordination of trace elements in Krithe ostracods and their implications for paleothermometry

The Mg and Sr content of ostracod valves have been used to reconstruct past temperature and salinity, and their stable isotopes have been used to reveal aspects of marine, lake and estuary hydrology. However, significant uncertainties surround the ostracod calcification processes, the incorporation mechanisms of trace elements, and the sensitivity of proxy tracers to complex confounding factors. The valves of most ostracods are composed of micron-scale crystal grains embedded in an organic matrix. The fine-scale geochemistry of these structures, and the nature of the influence of biological mineralisation processes on valve chemistry remain poorly constrained. We have performed sub-micron resolution X-ray microscopy of a marine Krithe ostracod valve, and determined the chemical coordination of Mg, and the distribution of Mg, Na and S throughout the crystal-organic valve structure. These trace elements display systematic sub-micron-scale compositional variations within the mineral grains and iner-granular matrix of the valve ultrastructure. These patterns imply that Krithe biomineralisation processes significantly modulate trace element incorporation at the sub-micron scale. Thus Krithe chemical composition is likely to be decoupled to some extent from the water in which they calcified. Most importantly, Mg K-edge Near- Edge X-Ray Absorption Fine Structure (NEXAFS) spectra, and the coincidence of high-Mg regions with S-rich organic layers reveal that Mg is not primarily hosted in the calcite structure in the valve. Our results highlight the need to understand the processes that drive this fine-scale chemical heterogeneity and their influence on connections between the external environment and valve geochemistry, if ostracods are to be used as sources of paleoenvironmental proxies

Carbon network evolution from dimers to sheets in superconducting ytrrium dicarbide under pressure

Carbon-bearing compounds display intriguing structural diversity, due to variations in hybrid bonding of carbon. Here, first- principles calculations and unbiased structure searches on yttrium dicarbide at pressure reveal four new structures with varying carbon polymerisation ， in addition to the experimentally-obsersed high- temperature low-pressure I4/mmm dimer phase. At low pressures, a metallic C2/m phase (four-member single chain carbide) is stable, which transforms into a Pnma phase (single chain carbide) upon increasing pressure, with further transformation to an Immm structure (double chain carbide) at 54 GPa and then to a P6/mmm phase (sheet carbide) at 267 GPa. Yttrium dicarbide is structurally diverse, with carbon bonded as dimers (at lowest pressure), four- member single chains, infinite single chains, double chains and eventually sheet structures on compression. Electron-phonon coupling calculations indicate that the high-pressure phases are superconducting. Our results aid the understanding and design of new superconductors and illuminate pressure-induced carbon polymerisation in carbides.NERC (NE/P012167/1) EPSRC (EP/P022596/1