An eco-friendly dyeing of woolen yarn by Terminalia chebula extract with evaluations of kinetic and adsorption characteristics

In the present study Terminalia chebula was used as an eco-friendly natural colorant for sustainable textile coloration of woolen yarn with primary emphasis on thermodynamic and kinetic adsorption aspects of dyeing processes. Polyphenols and ellagitannins are the main coloring components of the dye extract. Assessment of the effect of pH on dye adsorption showed an increase in adsorption capacity with decreasing pH. Effect of temperature on dye adsorption showed 80 °C as optimum temperature for wool dyeing with T. chebula dye extract. Two kinetic equations, namely pseudo first-order and pseudo second-order equations, were employed to investigate the adsorption rates. Pseudo second-order model provided the best fit (R2 = 0.9908) to the experimental data. The equilibrium adsorption data were fitted by Freundlich and Langmuir isotherm models. The adsorption behavior accorded well (R2 = 0.9937) with Langmuir isotherm model. Variety of eco-friendly and sustainable shades were developed in combination with small amount of metallic mordants and assessed in terms of colorimetric (CIEL∗a∗b∗ and K/S) properties measured using spectrophotometer under D65 illuminant (10° standard observer). The fastness properties of dyed woolen yarn against light, washing, dry and wet rubbing were also evaluated

Dyeing studies and fastness properties of brown naphtoquinone colorant extracted from Juglans regia L on natural protein fiber using different metal salt mordants

In this study, wool fibers are dyed with a natural colorant extracted from walnut bark in presence and absence of mordants. The effect of aluminum sulfate, ferrous sulfate, and stannous chloride mordants on colorimetric and fastness properties of wool fibers was investigated. Juglone was identified as the main coloring component in walnut bark extract by UV visible and FTIR spectroscopic techniques. The results showed that pretreatment with metallic mordants substantially improved the colorimetric and fastness properties of wool fibers dyed with walnut bark extract. Ferrous sulfate and stannous chloride mordanted wool fibers shows best results than potassium aluminum sulfate mordanted and unmordanted wool fibers. This is ascribed due to strong chelating power of ferrous sulfate and stannous chloride mordants

Assessment of Colorimetric and Fastness Properties of Prangos Ferulacea (Jashir) Dyed Wool Yarns in Conjunction with Mixed Metal Mordant Combinations via Reflectance Spectroscopy

Prangos ferulacea (Jashir) plant possesses various phytoconstituents such as coumarins, flavonoids, alkaloids, umbelliferon, and monoterpenes and has been used in traditional medicine. The presence of flavonoids in aerial parts of Prangos ferulacea necessities further examination of using them as a source of natural colorants for developing natural and beautiful shades on wool yarns. This will add one more new effective natural dye source and ease the dependency of the present-day textile industry on synthetic colorants. Simple adsorption of aqueous dye extract on the wool followed by evaluation of buildup properties using 28 different binary metal combinations as mordants were studied in this study. The dyeing was performed by exhaust dyeing method and dyed samples were analyzed through reflectance spectroscopy and analyzed in terms of color strength, CIEL*a*b*, and CIEL*c*ho values. Color characteristics were evaluated on a spectrophotometer under D65 illuminant and 10° standard observer. FT-IR and SEM analyses were performed to characterize P. ferulacea dyed wool yarns. The results showed that overall 29 different shades having very good to excellent fastness properties were produced by the use of different metallic salt combinations in natural dyeing of wool yarns using aerial parts of P. ferulacea as a source of natural dye

Biomordanting Potential of Acacia nilotica (Babul) in Conjunction with Kerria lacca and Rheum emodi Natural Dyes

This study was undertaken to propose an alternative use of Acacia nilotica bark extract as a potential source of biomordant for the development of ecofriendly shades of varying hue and tone in conjunction with Kerria lacca (Lac) and Rheum emodi (Himalayan rhubarb) natural dyes. The colorimetric analysis of K. lacca and R. emodi natural dyes were evaluated onto the woolen yarn samples adopting pre-mordanting technique using 1.0–5.0% (o.w.f.) A. nilotica as biomordant. The hue of color developed was found to be in yellow-red coordinate of color space diagram with hues shifted toward red region for K. lacca and toward yellow region for R. emodi dyed samples. The color strength (K/S) values were found to increase with increase in the concentration of biomordant and were found highest for 5.0% (o.w.f.) A. nilotica mordanted samples. Color fastness with respect to light exposure, washing, rubbing for the developed shades ranged between good to very good ratings of 4–5 on grey scale, confirming the possibility of using A. nilotica bark extract as a potential source of biomordant for enhancing the colorimetric and fastness characteristics of dyed woolen yarn samples

Terminalia arjuna Dyed Woolen Yarn - Effect of Binary and Ternary Metal Salt Combinations: A Greener Route for Production of Ecofriendly Textiles

Terminalia arjuna (Roxb.) Wight and Arn. (family: Combretaceae) is a large evergreen cardioactive plant drug available throughout India. The bark of T. arjuna is medicinally used as a tonic and is chemically characterized by the presence of tannins and related compounds with 20.0–24.0% tannin content. This research study investigates the use of barks of T. arjuna for the extraction of color components to develop natural and beautiful shades on wool with different hues and tones using binary and ternary metal salt combinations (aluminum potassium sulfate, ferrous sulfate, and stannous chloride). The dyeing was carried by exhaustion method and dyed samples were analyzed using a reflective spectrophotometer in terms of CIELAB (L*, a*, and b*) and color strength (K/S) values. Wash and light fastnesses were investigated according to (International Organization for Standardization)ISO standards. pH has marked effect on the K/S values of dyed woolen yarn. The results showed that overall 54 different shades having good to very good fastness properties were produced by control dyeing (un-mordanted) and the use of different metallic salt combinations in dyeing of wool using T. arjuna bark extract as a source of natural dye

Effect of Binary and Ternary Combination of Metal Salt on Colorimetric and Fastness Characteristics of Acacia Nilotica Dyed Woolen Yarn

Acacia nilotica an important medicinal plant of topical and sub-tropical regions belonging to family Fabaceae of genus Acacia is a source of many active phytochemicals (secondary metabolites) have been explored to study their useful utilization in different fields. The versatile utility of this plant as a source of timber, a source of fodder, tannin, and gum, and fuel has prompted researchers to deepen investigations for full utilization of this plant. To exploit its use as a colorant for textiles, this research study investigates for the first time pre-mordanting of wool with binary and ternary metal salt combinations using aluminum potassium sulfate, ferrous sulfate, and stannous chloride mordants in order to develop natural and beautiful shades on wool with different hue and tone. The dyeing was carried by exhaustion method and dyed samples were analyzed using a reflective spectrophotometer in terms of CIELab and CIELch (L*, a*, b*, c*, and h°) and K/S values. Wash and light fastnesses were investigated according to ISO standards. Wool samples pre-mordanted with ferrous sulfate-stannous chloride (neutral medium) displayed the highest color strength value of 11.22 followed by ferrous sulfate-alum and alum-stannous chloride combinations. Statistical analysis of color parameters confirms the synergetic role of individual metal salts in different combinations. The results showed that 36 different shades having good to very good fastness properties were produced by the use of different metallic salt combinations in the natural dyeing of wool using A. nilotica bark extract as dye

Simultaneous shade development, antibacterial, and antifungal functionalization of wool using Punica granatum L. Peel extract as a source of textile dye

In this work, we investigated the use of pomegranate peel extract as an effective functional dye for producing beautiful natural shades on wool and to impart durable antimicrobial properties. Wool is treated with various metal salt mordants in the presence of pomegranate dye under optimum natural dyeing conditions. The structural changes of wool are characterized by SEM and FT-IR techniques. The properties of color strength, color fastness to light, washing, rubbing, and durability of antimicrobial activity to washing are investigated. The experimental results indicate that there is small color variation among shades obtained under identical dyeing conditions. Furthermore, it was found that metal salt mordants improved dyeing depth, fastness properties, and effectively enhanced the durability of antimicrobial activity up to several washing cycles

Study the effect of ammonia post-treatment on color characteristics of annatto-dyed textile substrate using reflectance spectrophotometery

This research is aimed to study the influence of ammonia after-treatment on color behavior in wool yarns dyed with annatto extract. The dyeing was carried out using 15% (o. w. f.) dye concentration in presence of stannous chloride as a mordant and then treated with different percentages of ammonia solution. At the same time, color strength, CIE-Lab values and fastness properties of all dyed woolen yarns were also assessed. It was concluded that, in all cases after treatment with ammonia caused a decrease in lightness (L*) values, there was less lightness in the red hue of the wool yarns with the increase of ammonia percentage in solution. The K/S value of annatto dyed wool was found to increase after treated with ammonia. In addition, it was also observed that dyed wool yarns after post-treatment with ammonia did not return to their original color on acidification

Antibacterial Functionalization and Simultaneous Coloration of Wool Fiber with the Application of Plant-Based Dyes

High susceptibility of wool toward bacterial growth owing to proteinous nature and moisture retention ability leads to need for antibacterial functionalization of wool to cure the resulting deterioration. Antibacterial colored wool was designed via application of Terminalia chebula, Alkanna tinctoria, and Tagetes erecta natural dyes. Characteristics in terms of color and antibacterial activity were compared to correlate coloring compound’s effect on characteristics of dyes and, both T. chebula and A. tinctoria dyes inferred themselves actively resisting bacterial growth while T. erecta was not efficient against bacterial strains. Colorful shades of good color and fastness properties were obtained from selected natural dyes on woolen yarn. Results show Bacillus subtilis and Staphylococcus aureus (gram positive) were highly resisted by the effect of T. chebula and A. tinctoria dyes, and T. chebula among them proved best in terms of both color characteristics and antibacterial potential

First Application of Mix Metallic Salt Mordant Combinations to Develop Newer Shades on Wool with Bixa orellana Natural Dye Using Reflectance Spectroscopy

Annatto colorants derived from Bixa orellana L. seeds have been extensively used in a wide range of food commodities such as dairy products, flour confectionery, fish, soft drinks, meat products, snack foods, and dry mixes. To exploit its use as a colorant for textiles, this research study investigates for the first time pre-mordanting of wool with bi and tri metal salt combinations using aluminum potassium sulfate, ferrous sulfate, and stannous chloride mordants in order to develop natural and beautiful shades on wool with variation in hue and tone. The dyeing was carried by exhaustion method and dyed samples were analyzed using a Reflective Spectrophotometer in terms of CIELAB (L*, a*and b*) and K/S values and washing and light fastnesses were investigated according to I.S.O. standard recommendations. In the dyeing experiments, wool samples pre-mordanted with Fe + Sn displayed highest color strength followed by Fe + Al and Al + Sn combinations. The results showed that overall 36 different shades having good to very good fastness properties were produced by the use of different metallic salt combinations in the natural dyeing of wool using annatto dye