2,385 research outputs found
Spin signatures of exchange-coupled triplet pairs formed by singlet fission
We study the effect of an exchange interaction on the magnetic-field-dependent photoluminescence in singlet fission materials. We show that, for strongly interacting triplet exciton pairs (intertriplet exchange interaction greater than the intratriplet spin-dipolar interaction), quantum beating and magnetic-field effects vanish apart from at specific magnetic fields where singlet and quintet levels are mixed by a level anticrossing. We characterize these effects and show that the absence of a magnetic-field effect or zero-field quantum beats does not necessarily mean that fission is inoperative. These results call for a reconsideration of the observations that are considered hallmarks of singlet fission and demonstrate how the spin coherence and exchange coupling of interacting triplet pairs can be measured through magneto-photoluminescence experiments.Engineering and Physical Sciences Research Council (Grant ID: EP/G060738/1)This is the author accepted manuscript. The final version is available from the American Physical Society via http://dx.doi.org/10.1103/PhysRevB.94.04520
Probabilistic Perception Revision in AgentSpeak(L)
Agent programming is mostly a symbolic discipline and, as such, draws little benefits from probabilistic areas as machine learning and graphical models. However, the greatest objective of agent research is the achievement of autonomy in dynamical and complex environments — a goal that implies embracing uncertainty and therefore the entailed representations, algorithms and techniques. This paper proposes an innovative and conflict free two layer approach to agent programming that uses already established methods and tools from both symbolic and probabilistic artificial intelligence. Moreover, this method is illustrated by means of a widely used agent programming example, GOLDMINERS
Fresnel zone plate telescopes for X-ray imaging II: numerical simulations with parallel and diverging beams
We present the results of simulations of shadows cast by a zone plate
telescope which may have one to four pairs of zone plates. From the shadows we
reconstruct the images under various circumstances. We discuss physical basis
of the resolution of the telescope and demonstrate this by our simulations. We
allow the source to be at a finite distance (diverging beam) as well as at an
infinite distance (parallel beam) and show that the resolution is worsened when
the source is nearby. By reconstructing the zone plates in a way that both the
zone plates subtend the same solid angles at the source, we obtain back high
resolution even for sources at a finite distance. We present simulated results
for the observation of the galactic center and show that the sources of varying
intensities may be reconstructed with accuracy. Results of these simulations
would be of immense use in interpreting the X-ray images from recently launched
CORONAS-PHOTON satellite.Comment: 17 pages, 36 figures, Published in Experimental Astronom
Electroluminescence from Organometallic Lead Halide Perovskite-Conjugated Polymer Diodes
Organometallic lead perovskite-based solar cells can be converted to light-emitting diodes by engineering the current density. Diodes are fabricated with adjacent perovskite and conjugated polymer layers using orthogonal solvents. Under forward bias, these devices show simultaneous emission from both the luminescent conjugated polymer and the perovskite, providing direct information on electron and hole recombination as a function of device architecture and bias voltage.We gratefully acknowledge funding from the Engineering and Physical Sciences Research Council (EPSRC). A.K. acknowledges NRF-Singapore for a scholarship.This is the final version of the article. It first appeared from Wiley via http://dx.doi.org/10.1002/aelm.20150000
Impact of exciton delocalization on exciton-vibration interactions in organic semiconductors
Organic semiconductors exhibit properties of individual molecules and
extended crystals simultaneously. The strongly bound excitons they host are
typically described in the molecular limit, but excitons can delocalize over
many molecules, raising the question of how important the extended crystalline
nature is. Using accurate Green's function based methods for the electronic
structure and non-perturbative finite difference methods for exciton-vibration
coupling, we describe exciton interactions with molecular and crystal degrees
of freedom concurrently. We find that the degree of exciton delocalization
controls these interactions, with thermally activated crystal phonons
predominantly coupling to delocalized states, and molecular quantum
fluctuations predominantly coupling to localized states. Based on this picture,
we quantitatively predict and interpret the temperature and pressure dependence
of excitonic peaks in the acene series of organic semiconductors, which we
confirm experimentally, and we develop a simple experimental protocol for
probing exciton delocalization. Overall, we provide a unified picture of
exciton delocalization and vibrational effects in organic semiconductors,
reconciling the complementary views of finite molecular clusters and periodic
molecular solids
Comparison of glucose tolerance in renal transplant recipients and hemodialysis patients
BACKGROUND: Impaired glucose tolerance is a risk factor for atherosclerosis in hemodialysis patients and renal transplant recipients. METHODS: To check the relationship of impaired glucose tolerance with the other atherosclerotic risk factors, fasting blood sugar and the standard two hour glucose tolerance test, serum tryglyceride, serum cholesterol, cyclosporine through level (in renal tranpslant recipients) and hemoglobin A1C were measured in 55 stable renal transplant recipients, 55 hemodialysis patients and 55 healthy controls with similar demographic characteristics. Patients with diabetes mellitus and propranolol consumers were excluded. The mean age and female to male ratio were 39 +/- 7 years and 23/22, respectively. RESULTS: Four of the renal transplant recipients and twelve of the hemodialysis patients had impaired glucose tolerance. Significant linear correlation was observed with body mass index and IGT only in hemodialysis patients (r = 0.4, p = 0.05). Glucose tolerance also had a significant correlation with triglyceride levels (217.2 +/- 55 mg/dl in hemodialysis patients vs. 214.3 +/- 13 mg/dl in renal transplant recipients and 100.2 +/- 18 mg/dl in control groups, p = 0.001). The glucose tolerance had significant relationship with higher serum cholesterol levels only in the renal transplant recipients (269.7 +/- 54 in renal transplant recipients vs. 199.2 +/- 36.6 mg/dl in hemodialysis and 190.5 +/- 34 mg/dl in control groups, p = 0.0001). In the renal transplant recipients, a linear correlation was observed with glucose tolerance and both the serum cyclosporine level (r = 0.9, p = 0.001) and the hemoglobin A1C concentration (6.2 +/- 0.9 g/dl). The later correlation was also observed in the hemodialysis patients (6.4 +/- 0.7 g/dl; r = 67, p = 0.001). CONCLUSIONS: We conclude that although fasting blood sugar is normal in non-diabetic renal transplant and hemodialysis patients, impaired glucose tolerance could be associated with the other atherosclerotic risk factors
Instruments of RT-2 Experiment onboard CORONAS-PHOTON and their test and evaluation III: Coded Aperture Mask and Fresnel Zone Plates in RT-2/CZT Payload
Imaging in hard X-rays of any astrophysical source with high angular
resolution is a challenging job. Shadow-casting technique is one of the most
viable options for imaging in hard X-rays. We have used two different types of
shadow-casters, namely, Coded Aperture Mask (CAM) and Fresnel Zone Plate (FZP)
pair and two types of pixellated solid-state detectors, namely, CZT and CMOS in
RT-2/CZT payload, the hard X-ray imaging instrument onboard the CORONAS-PHOTON
satellite. In this paper, we present the results of simulations with different
combinations of coders (CAM & FZP) and detectors that are employed in the
RT-2/CZT payload. We discuss the possibility of detecting transient Solar
flares with good angular resolution for various combinations. Simulated results
are compared with laboratory experiments to verify the consistency of the
designed configuration.Comment: 27 pages, 16 figures, Accepted for publication in Experimental
Astronomy (in press
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