Dissolution Rates of Allophane, Fe-Allophane, and Hisingerite and Implications for Aqueous Alteration on Mars and in Potential Returned Martian Samples

Recent measurements from Mars document X-ray amorphous/nano-crystalline materials in multiple locations across the planet. However, despite their prevalence, little is known about these materials or what their presence implies for the history of Mars. The amorphous component of the martian soil in Gale Crater has an X-ray diffraction pattern that can be partially fit with allophane (approximately Al2O3•(SiO2)1.3-2•(H2O)2.5-3), as well as low-temperature water release consistent with allophane. The chemical data from Gale Crater suggest that other silicate phases similar to allophane, such as Fe-substituted allophane (here, approximately (Fe2O3)0.01(Al2O3)0.99(SiO2)2•3H2O) and hisingerite (approximately Fe3+2Si2O5(OH)4•(H2O)), may also be present. In order to investigate the properties of these poorly crystalline components of the martian soil, we synthesized allophane, Fe-substituted allophane, and hisingerite; characterized the synthetic materials by infrared spectroscopy, electron microscopy, X-ray diffraction, and evolved gas analysis; and performed dissolution experiments at acidic, near-neutral, and alkaline conditions in order to determine dissolution kinetics and alteration phases for these poorly crystalline materials. Our analyses demonstrate that allophane, Fe-allophane, and hisingerite are appropriate analogs for silicate phases in the martian amorphous soil component. These poorly crystalline materials dissolve rapidly at all experimental pH conditions, indicating that similar materials on Mars must have had limited interaction with liquid water since their formation. For allophane, logrdiss = -11.05 – 0.088 × pH; for Fe-allophane, logrdiss = -11.09 – 0.091 × pH; and for hisingerite, logrdiss = -11.49 – 0.032 × pH. Additionally, incipient phyllosilicate phases form in hisingerite and allophane under high pH conditions, but are much more sparse at low pH, which, combined with the enrichment of Fe expected from weathering, may be a useful tool for examining returned samples of martian soils for evidence of past aqueous alteration

Hadron Helicity Violation in Exclusive Processes: Quantitative Calculations in Leading Order QCD

We study a new mechanism for hadronic helicity flip in high energy hard exclusive reactions. The mechanism proceeds in the limit of perfect chiral symmetry, namely without any need to flip a quark helicity. The fundamental feature of the new mechanism is the breaking of rotational symmetry of the hard collision by a scattering plane in processes involving independent quark scattering. We show that in the impulse approximation there is no evidence for of the helicity violating process as the energy or momentum transfer $Q^2$ is increased over the region 1 GeV^2 < Q^2 < 100 GeV^2. In the asymptotic region Q^2> 1000 GeV^2, a saddle point approximation with doubly logarithmic accuracy yields suppression by a fraction of power of Q^2. ``Chirally--odd" exclusive wave functions which carry non--zero orbital angular momentum and yet are leading order in the high energy limit, play an important role.Comment: uuencoded LaTeX file (21 pages) and PostScript figure

The Virgo Alignment Puzzle in Propagation of Radiation on Cosmological Scales

We reconsider analysis of data on the cosmic microwave background on the largest angular scales. Temperature multipoles of any order factor naturally into a direct product of axial quantities and cosets. Striking coincidences exist among the axes associated with the dipole, quadrupole, and octupole CMB moments. These axes also coincide well with two other axes independently determined from polarizations at radio and optical frequencies propagating on cosmological scales. The five coincident axes indicate physical correlation and anisotropic properties of the cosmic medium not predicted by the conventional Big Bang scenario. We consider various mechanisms, including foreground corrections, as candidates for the observed correlations. We also consider whether the propagation anomalies may be a signal of ``dark energy'' in the form of a condensed background field. Perhaps {\it light propagation} will prove to be an effective way to look for the effects of {\it dark energy}.Comment: 24 pages, 4 figures, minor changes, no change in result or conclusions. to appear in IJMP

Systematic Analysis Method for Color Transparency Experiments

We introduce a data analysis procedure for color transparency experiments which is considerably less model dependent than the transparency ratio method. The new method is based on fitting the shape of the A dependence of the nuclear cross section at fixed momentum transfer to determine the effective attenuation cross section for hadrons propagating through the nucleus. The procedure does not require assumptions about the hard scattering rate inside the nuclear medium. Instead, the hard scattering rate is deduced directly from the data. The only theoretical input necessary is in modelling the attenuation due to the nuclear medium, for which we use a simple exponential law. We apply this procedure to the Brookhaven experiment of Carroll et al and find that it clearly shows color transparency: the effective attenuation cross section in events with momentum transfer $Q^2$ is approximately $40\ mb\ (2.2\ GeV^2/Q^2)$. The fit to the data also supports the idea that the hard scattering inside the nuclear medium is closer to perturbative QCD predictions than is the scattering of isolated protons in free space. We also discuss the application of our approach to electroproduction experiments.Comment: 11 pages, 11 figures (figures not included, available upon request), report # KU-HEP-92-2

Evidence for Adsorption of Chlorine Species on Iron(III) (hydr)oxides in the Sheepbed Mudstone, Gale Crater, Mars

Chlorine is a widespread element on Mars present in dust, soils and rocks, including the Sheepbed mudstone at Yellowknife Bay, Gale crater. Combined elemental and volatile analyses of two drilled samples, Cumberland and John Klein, indicated that chloride (Cl-) and perchlorate (ClO4 -) are likely present in the mudstone. The nature of chlorine species in Sheepbed mudstone is still not well constrained. It has been proposed that both are present as amorphous or crystalline salts physically mixed with mudstone minerals. We alternatively hypothesize that adsorbed perchlorate and chloride exist in the mudstone and adsorption could occur, in particular, on Fe(III) (hydr)oxide phases as supported by laboratory observations on terrestrial materials. Mineralogical and compositional analyses of the drilled Cumberland mudstone sample revealed the presence of ~30 wt% of a Fe-rich X-ray amorphous phase. Ferrihydrite has been proposed as a component of the Fe-rich X-ray amorphous material. The objectives of this work were to determine adsorption of perchlorate and chloride on ferrihydrite and to enable data comparison by characterizing adsorbed chloride and perchlorate with thermal and evolved gas analysis run under operating conditions similar to the SAM instrument onboard the Curiosity rover

Advancements and Application of Microsecond Synchrotron X-ray Footprinting at the Advanced Light Source

The method of synchrotron X-ray protein footprinting (XF-MS) is used to determine protein conformational changes, folding, protein-protein and protein-ligand interactions, providing information which is often difficult to obtain using X-ray crystallography and other common structural biology methods [1–3]. The technique uses comparative in situ labeling of solvent-accessible side chains by highly reactive hydroxyl radicals (•OH) in buffered aqueous solution under different assay conditions. In regions where a protein is folded or binds a partner, these •OH susceptible sites are inaccessible to solvent, and therefore protected from labeling. The •OH are generated by the ionization of water using high-flux-density X-rays. High-flux density is a key factor for XF-MS labeling because obtaining an adequate steady-state concentration of hydroxyl radical within a short irradiation time is necessary to minimize radiation-induced secondary damage and also to overcome various scavenging reactions that reduce the yield of labeled side chains

Exclusive Hadronic Processes and Color Transparency

We review the current status of high energy exclusive processes and color transparency.Comment: 17 pages, 8 figures, based on talk given at International Symposium on Nuclear Physics, Mumbai, Dec 18-22, 200

Anisotropy in the Distribution of Galactic Radio Polarizations

Radiation traversing the observable universe provides powerful ways to probe anisotropy of electromagnetic propagation. A controversial recent study claimed a signal of dipole character. Here we test a new and independent data set of 361 points under the null proposal of {\it statistical independence} of linear polarization alignments relative to galaxy axes, versus angular positions. The null hypothesis is tested via maximum likelihood analysis of best fits among numerous independent types of factored distributions. We also examine single-number correlations which are parameter free, invariant under coordinate transformations, and distributed very robustly. The statistics are shown explicitly not to depend on the uneven distribution of sources on the sky. We find that the null proposal is not supported at the level of less than 5% to less than 0.1% by several independent statistics. The signal of correlation violates parity, that is, symmetry under spatial inversion, and requires a statistic which transforms properly. The data indicate an axis of correlation, on the basis of likelihood determined to be $[{\rm R.A.}=(0^{\rm h},9^{\rm m}) \pm (1^{\rm h},0^{\rm m})$, ${\rm Decl.} = -1^o\pm 15^o]$.Comment: 10 pages, Late