Low-temperature SCR of NO with NH 3 over noble metal promoted Fe-ZSM-5 catalysts

We have reported previously the excellent performance of Fe-exchanged ZSM-5 for selective catalytic reduction (SCR) of NO with ammonia at high temperatures (300–400 °C). In this work, we found that the reaction temperature could be decreased to 200–300 °C when a small amount of noble metal (Pt, Rh, or Pd) was added to the Fe-ZSM-5. The SCR activity follows the order Pt/Fe-ZSM-5 > Rh/Fe-ZSM-5 > Pd/Fe-ZSM-5 at 250 °C. On the Pt promoted Fe-ZSM-5, 90% NO conversion was obtained at 250 °C at GHSV  = 1.1 ×  10 5  h −1 . Moreover, the noble metal improved the resistance to H 2 O and SO 2 . The presence of H 2 O and SO 2 decreased the SCR performance only very slightly.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/44250/1/10562_2004_Article_3462.pd

Interstellar Probe: Humanity's exploration of the Galaxy Begins

During the course of its evolution, our Sun and its protective magnetic bubble have plowed through dramatically different interstellar environments throughout the galaxy. The vast range of conditions of interstellar plasma, gas, dust and high-energy cosmic rays on this “solar journey” have helped shape the solar system that we live in. Today, our protective bubble, or Heliosphere, is likely about to enter a completely new regime of interstellar space that will, yet again, change the entire heliospheric interaction and how it shields us from the interstellar environment. Interstellar Probe is a mission concept to explore the mechanisms shaping our heliosphere and represents the first step beyond our home, into the interstellar cloud to understand the evolutionary journey of our Sun, Heliosphere and Solar System. The idea of an Interstellar Probe dates back to the 1960's, when also the ideas of a probe to the Sun and its poles were formed. An international team of scientists and a team of engineers at the Johns Hopkins University Applied Physics Laboratory (APL) are funded by NASA to study pragmatic mission concepts that would make a launch in the 2030's a reality. The ground breaking science enabled by such a mission spans not only the discipline of Solar and Space Physics, but also Planetary Sciences and Astrophysics. Detailed analyses including the upcoming SLS Block 2 and powerful stages demonstrate that asymptotic speeds around 7 Astronomical Units (au) per Year are already possible with a Jupiter Gravity Assist. Here, we give an overview of the science discoveries that await along the journey, including the physics of the heliospheric boundary and interstellar medium, the potential for exploration of Kuiper Belt Objects, the circum-solar dust disk and the extra-galactic background light. The scientific rationale, investigations and implementation of an Interstellar Probe are discussed including also example payload, trajectory design and operations

Management of lymphedema of the male genitalia

Polysubstituted cyclopentadienyl and indenyl complexes of ruthenium were synthesized and investigated to elucidate their potential cytotoxic activities. In particular, substituted (indenyl)ruthenium complexes inhibited the proliferation of a panel of human adherent cancer cells with comparable activity to reference agent cisplatin. One of the active compounds exerted a concentration dependent inhibition of cell cycle at G1–S transiton as evidenced by flow cytometry