4 research outputs found
Superconductivity in single crystals of a quasi-one dimensional infinite chain cuprate SrCaCuO at 90 K
Although there is no complete theory of high temperature superconductivity,
the importance of CuO planes in cuprate superconductors is confirmed from
both theory and experiments. Strong Coulomb repulsion between electrons on the
CuO plane makes the resultant electron system highly correlated and a
difficult problem to solve since exact solutions of many-body Hamiltonian in
two dimensions do not exist. If however, superconductivity can arise in
structures having chains rather than planes and having a high critical
temperature, then the high temperature superconductivity problem could become
more tractable since exact solutions in one dimension do exist. In this paper,
we report the observation of bulk superconductivity in single crystals of a
cuprate SrCaCuO at very high critical temperature, T, of
90 K whose structure reveals the presence of infinite double chains of
Cu-O-Cu-O instead of CuO planes, thus, ensuring quasi-one dimensional
superconductivity. Bulk superconducting behaviour was observed in \textit{dc}
magnetisation, \textit{ac} susceptibility as well as resistance measurements.
The observation of bulk superconductivity in SrCaCuO having
chains of Cu-O-Cu-O rather than planes of CuO at a high T of 90 K is
expected to profoundly impact our understanding of high temperature
superconductivity.Comment: 15 pages, 4 figure
A study on assessment of hydrocarbon potential of the lignite deposits of Saurashtra basin, Gujarat (Western India)
Abstract In the present investigation, Bhavnagar lignites of the Saurashtra basin (Gujarat) have been studied to assess their hydrocarbon generating potential. The samples of upper as well as lower lignite seams have been studied through microscopy and subjected to various chemical analyses viz. proximate analysis, ultimate analysis and Rock-Eval Pyrolysis. These lignites have high moisture and low to moderate ash yield but are characterized by high volatile matter. Petrographically they comprise predominantly of huminite group maceral while liptinite and inertinite groups occur in subordinated amount. Huminite is chiefly composed of detrohuminite and telohuminite. The T max (av. 416.23 °C) and huminite reflectivity (0.28%–0.30%) indicate a low degree of maturity for these lignites which is also substantiated by the T max versus hydrogen index plot. The organic matter is subjugated by kerogen Type-III with a potential to expel hydrocarbon on liquefaction. Study further reveals that the fixed hydrocarbon is several folds higher than the free hydrocarbons. Being high in reactive maceral content, a high ‘conversion’ and good ‘oil yield’ values for these lignites were observed. Thus, the empirically derived values match well with those obtained through the experimental values of Rock-Eval Pyrolysis and validate their hydrocarbon generating potential